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Produce health proteins throughout bio-barriers via hexa-histidine material units for remedy: an incident in cornael neovascularization product.
In accord with the experimental observations, at high salt concentrations, the model predicts loss of chemical equilibrium between the endcaps and cylindrical part of the wormlike micelles, which implies transition to self-assemblies of other, e.g. branched, morphology or the onset of crystallization and phase separation.
Excellent agreement was achieved between the theoretical model and experimental data for wormlike micelles from anionic and cationic surfactants at various concentrations of salt and temperatures. In accord with the experimental observations, at high salt concentrations, the model predicts loss of chemical equilibrium between the endcaps and cylindrical part of the wormlike micelles, which implies transition to self-assemblies of other, e.g. branched, morphology or the onset of crystallization and phase separation.
The wettability of complex fluids on surfaces usually depends on the adsorption of solutes to any of the constituting interfaces. Controlling such interfacial processes by varying the composition of a phase enables the design of smart responsive systems. Our goal is to demonstrate that 3D Confocal Raman Microscopy (CRM) can reveal the mechanistic details of such processes by allowing to simultaneously monitor the contact angle variation and redistribution of the chemical species involved.

Motivated by the enhanced oil recovery process of low salinity water flooding, we studied the response of picolitre oil drops on mineral substrates upon varying the ambient brine salinity. The substrates were pre-coated with thin layers of deuterated-stearic acid (surfactant) that display salinity-dependent stability.

3D CRM imaging using a recently proposed faster 'ai' (algorithm-improved) mode reveals that the surfactant layer is stable at high salinities, leading to preferential oil wetting. Upon reducing learn more , this layer decomposes and the investigated surfaces of mica and - somewhat less pronounced - silica become more water wet. Eventually, the surfactant is found to partly dissolve in the oil and partly precipitate at the oil-water interface. We anticipate that ai-3D-CRM will prove useful to holistically study similar systems displaying reactive wetting.
3D CRM imaging using a recently proposed faster 'ai' (algorithm-improved) mode reveals that the surfactant layer is stable at high salinities, leading to preferential oil wetting. Upon reducing the ambient brine salinity, this layer decomposes and the investigated surfaces of mica and - somewhat less pronounced - silica become more water wet. Eventually, the surfactant is found to partly dissolve in the oil and partly precipitate at the oil-water interface. We anticipate that ai-3D-CRM will prove useful to holistically study similar systems displaying reactive wetting.Antibiotic pollution has been a serious global public health concern in recent years, photodynamic inactivation is one of the most promising and innovative methods for antibacterial applications that avoids antibiotic abuse and minimizes risks of antibiotic resistance. #link# However, limited by the weak interaction between the photosensitizers and Gram-negative bacteria, the effect of photodynamic inactivation cannot be fully exerted. Herein, photosensitizer chlorin e6-loaded polyethyleneimine-based micelle was constructed. The synergy of electrostatic and hydrophobic interactions between the nanoparticles and the bacterial surface promoted the anchoring of nanoparticles onto the bacteria, resulting in enhanced photoinactivation activities on Gram-negative bacteria. As expected, an eminent antibacterial effect was also observed on the Gram-positive bacteria Staphylococcus aureus. The cellular uptake results showed that photosensitizer was firmly anchored to the bacterial cell surface of Escherichia coli or Staphylococcus aureus by the introduction of branched polyethylenimine-containing nanoparticles. The light-triggered generation of reactive oxygen species, mainly singlet oxygen, from the membrane-bound nanoparticles caused irreversible damage to the bacterial outer membrane, achieving enhanced bactericidal efficiency than free photosensitizer. The study would provide an efficient and promising antimicrobial alternative to prevent overuse of antibiotics and have enormous potential for human healthcare and the environment remediation.Many uses of emulsion droplets require precise control over droplet size and shape. Here we report a 'shape-memorable' micro-droplet formulation stabilized by a polyethylene glycol (PEG)-modified protein -surfactant, the droplets are stable against coalescence for months and can maintain non-spherical shapes for hours, depending on the surface coverage of PEGylated protein. Monodisperse droplets with aspect ratios ranging from 1.0 to 3.4 were controllably synthesized with a flow-focusing microfluidic device. Mechanical properties of the interfacial protein network were explored to elucidate the mechanism behind the droplet shape conservation phenomenon. Characterization of the protein film revealed that the presence of a PEG layer at interfaces alters the mechanical responses of the protein film, resulting in interfacial networks with improved strength. Taking advantage of the prolonged stabilization of non-spherical droplets, we demonstrate functionalization of the droplet interface with accessible biotins. The stabilization of micro-droplet shape with surface-active proteins that also serve as an anchor for integrating functional moieties, provides a tailorable interface for diverse biomimetic applications.A novel hierarchical solution-processed fractional structured molybdenum oxide (MoO3) catalyst is fabricated from tricarbonyltris (propionitrile) molybdenum and used as the counter electrode of all-solid-state fiber-shaped dye-sensitized solar cells (S-FDSSC). The Tafel plot results and electrical impedance spectroscopy suggest that the use of the fractional structured MoO3 catalyst enhances the efficiency of the reduction of I3- to 3I- at the counter electrode/electrolyte interface. Because of the improvements of the short-current circuit and fill factor, the power conversion efficiency of the MoO3-modified S-FDSSC improves by 60% compared with that of the reference S-FDSSC. In addition, because of the robust fractional structure of MoO3, the MoO3-modified S-FDSSC maintains 90% and 95% of efficiency after 350-fold bending and the incident light angle dependency test, respectively. At 65% humidity and at 65 °C, the power conversion efficiency of the MoO3-modified device decreases by less then 20% after 350 h of storage, while that of the reference device drops by more than 70%.
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