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The low-dimensional, highly anisotropic geometries, and superior mechanical properties of one-dimensional (1D) nanomaterials allow the exquisite strain engineering with a broad tunability inaccessible to bulk or thin-film materials. Such capability enables unprecedented possibilities for probing intriguing physics and materials science in the 1D limit. Among the techniques for introducing controlled strains in 1D materials, nanoimprinting with embossed substrates attracts increased attention due to its capability to parallelly form nanomaterials into wrinkled structures with controlled periodicities, amplitudes, orientations at large scale with nanoscale resolutions. Here, we systematically investigated the strain-engineered anisotropic optical properties in Te nanowires through introducing a controlled strain field using a resist-free thermally assisted nanoimprinting process. The magnitude of induced strains can be tuned by adjusting the imprinting pressure, the nanowire diameter, and the patterns on the substrates. The observed Raman spectra from the chiral-chain lattice of 1D Te reveal the strong lattice vibration response under the strain. Our results suggest the potential of 1D Te as a promising candidate for flexible electronics, deformable optoelectronics, and wearable sensors. The experimental platform can also enable the exquisite mechanical control in other nanomaterials using substrate-induced, on-demand, and controlled strains.Aqueous hybrid supercapacitors are attracting increasing attention due to their potential low cost, high safety and eco-friendliness. However, the narrow operating potential window of aqueous electrolyte and the lack of suitable negative electrode materials seriously hinder its future applications. Here, we explore high concentrated lithium acetate with high ionic conductivity of 65.5 mS cm-1 as a green "water-in-salt" electrolyte, providing wide voltage window up to 2.8 V. It facilitates the reversible function of niobium tungsten oxide, Nb18W16O93, that otherwise only operations in organic electrolytes previously. The Nb18W16O93 with lithium-ion intercalation pseudocapacitive behavior exhibits excellent rate performance, high areal capacity, and ultra-long cycling stability. An aqueous lithium-ion hybrid capacitor is developed by using Nb18W16O93 as negative electrode combined with graphene as positive electrode in lithium acetate-based "water-in-salt" electrolyte, delivering a high energy density of 41.9 W kg-1, high power density of 20,000 W kg-1 and unexceptionable stability of 50,000 cycles.A controllable approach that combines surface plasmon resonance and two-dimensional (2D) graphene/MoS2 heterojunction has not been implemented despite its potential for efficient photoelectrochemical (PEC) water splitting. In this study, plasmonic Ag-decorated 2D MoS2 nanosheets were vertically grown on graphene substrates in a practical large-scale manner through metalorganic chemical vapor deposition of MoS2 and thermal evaporation of Ag. The plasmonic Ag-decorated MoS2 nanosheets on graphene yielded up to 10 times higher photo-to-dark current ratio than MoS2 nanosheets on indium tin oxide. The significantly enhanced PEC activity could be attributed to the synergetic effects of SPR and favorable graphene/2D MoS2 heterojunction. Plasmonic Ag nanoparticles not only increased visible-light and near-infrared absorption of 2D MoS2, but also induced highly amplified local electric field intensity in 2D MoS2. In addition, the vertically aligned 2D MoS2 on graphene acted as a desirable heterostructure for efficient separation and transportation of photo-generated carriers. This study provides a promising path for exploiting the full potential of 2D MoS2 for practical large-scale and efficient PEC water-splitting applications.Developing a flexible, lightweight and effective electromagnetic (EM) absorber remains challenging despite being on increasing demand as more wearable devices and portable electronics are commercialized. Herein, we report a flexible and lightweight hybrid paper by a facile vacuum-filtration-induced self-assembly process, in which cotton-derived carbon fibers serve as flexible skeletons, compactly surrounded by other microwave-attenuating components (reduced graphene oxide and Fe3O4@C nanowires). Owing to its unique architecture and synergy of the three components, the as-prepared hybrid paper exhibits flexible and lightweight features as well as superb microwave absorption performance. Maximum absorption intensity with reflection loss as low as - 63 dB can be achieved, and its broadest frequency absorption bandwidth of 5.8 GHz almost covers the entire Ku band. Such a hybrid paper is promising to cope with ever-increasing EM interference. The work also paves the way to develop low-cost and flexible EM wave absorber from biomass through a facile method.The discovery of laser-induced graphene (LIG) from polymers in 2014 has aroused much attention in recent years. A broad range of applications, including batteries, catalysis, sterilization, and separation, have been explored. The advantages of LIG technology over conventional graphene synthesis methods are conspicuous, which include designable patterning, environmental friendliness, tunable compositions, and controllable morphologies. In addition, LIG possesses high porosity, great flexibility, and mechanical robustness, and excellent electric and thermal conductivity. selleck chemical The patternable and printable manufacturing process and the advantageous properties of LIG illuminate a new pathway for developing miniaturized graphene devices. Its use in sensing applications has grown swiftly from a single detection component to an integrated smart detection system. In this minireview, we start with the introduction of synthetic efforts related to the fabrication of LIG sensors. Then, we highlight the achievement of LIG sensors for the detection of a diversity of stimuli with a focus on the design principle and working mechanism. Future development of the techniques toward in situ and smart detection of multiple stimuli in widespread applications will be discussed.
Read More: https://www.selleckchem.com/products/U0126.html
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