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Phthalate acid esters (PAEs) are environmentally ubiquitous and have aroused a worldwide concern due to their threats to environment and human health. Di-n-butyl phthalate (DBP) is one of the most frequently observed PAEs in the environment. In this study, a novel bacterium identified as Pseudomonas sp. YJB6 that isolated from PAEs-contaminated soil was determined to have strong DBP-degrading activity. A complete degradation of DBP in 200 mg/L was achieved within 3 days when YJB6 was cultivated at 31.4 °C with an initial inoculation size of 0.6 (OD600) in basic mineral salts liquid medium (MSM), pH 7.6. The degradation curves of DBP (50-2000 mg/L) fitted well the first-order kinetics model, with a half-life (t1/2) ranging from 0.86 to 1.88 d. The main degradation intermediates were identified as butyl-ethyl phthalate (BEP), mono-butyl phthalate (MBP), phthalic acid (PA) and benzoic acid (BA), indicating a new complex and complete biodegradation pathway presented by YJB6. DBP might be metabolized through de-esterification, β-oxidation, and hydrolysis, followed by entering the Krebs cycle of YJB6 as a final step. Strain YJB6 was successfully immobilized with sodium alginate (SA), polyvinyl alcohol (PVA), and SA-PVA. The immobilization significantly improved the stability and adaptability of the cells thus resulting in high volumetric DBP-degrading rates compared to that of the freely suspended cells. In addition, these immobilized cells can be reused for many cycles with well conserved in DBP-degrading activity. The ideal DBP degrading ability of the free and immobilized YJB6 cells suggests that strain YJB6, especially the SA-PVA+ YJB6 promises great potential to remove hazardous PAEs.L-cysteine is used to improve efficiency in anaerobic biological systems as an oxygen scavenger, electron shuttle and substrate source. The performance of MEC by addition of L-cysteine was investigated during start-up and operation phases, respectively. Results showed that the maximum current density of 6.36 ± 0.14 A/m2, hydrogen yield of 1.08 ± 0.05 m3/m3 and energy efficiency of 130% were achieved with L-cysteine adding during operation phase. By contrast, the addition of L-cysteine during the start-up phase reduced the energy efficiency by more than 30%. The microbial community analysis revealed that a higher microbial community richness and diversity were achieved, the enrichment of Sulfuricurvum, Sulfurospirillum, Desulfovibrio and other electroactive microorganisms indicated their relative abundance could be regulated by L-cysteine during start-up phase when L-cysteine was added. This study provided an alternative method to enhanced hydrogen production and a better understanding of the mechanism of L-cysteine action in MEC performance.In this study, the quantitative and qualitative compositions of microplastics (MPs) deposited from the atmosphere in the coastal zone were analysed. Moreover, links between MP deposition and meteorological factors (air humidity, wind speed, precipitation height, and air mass trajectories) were investigated. MP deposition samples were collected in the southern Baltic area in 2017 and 2018 for 286 days in total. The morphological features of MPs (shape and size) were analysed using a digital microscope. Qualitative analysis was performed using micro-attenuated total reflectance Fourier-transform infrared spectroscopy (μATR FT-IR). The size of the deposited MPs ranged from 5 μm to 5000 μm, and smaller size classes ( less then 720 μm) were predominant (70%). Fibres were of the dominant type (60%). Films and fragments constituted 26% and 14% of the total MPs, respectively, while 55% of the MPs found in the study were polymers often used in textiles, packaging materials, and fishing gear (polyesters and polypropylene). The atmospheric MP deposition ranged from 0 m-2·d-1 to 30 m-2·d-1 (average 10 ± 8 m-2·d-1; median 8 m-2·d-1). Based on the air mass trajectory cluster analysis, MPs deposited in Gdynia mainly originated from local sources ( less then 100 km). Furthermore, higher MP deposition occurred when the inflowing air masses were terrestrial, and lower deposition occurred when they were marine. On average, during wet periods twice the amount of MPs was deposited in comparison with dry periods. During dry periods deposition increased with increasing wind speed and was intensified by high relative humidity.Brazil is an important player in the global agribusiness markets, in which grain and beef make up the majority of exports. Barriers to access more valuable sustainable markets emerge from the lack of adequate compliance in supply chains. Here is depicted a mobile application based on cloud/edge computing for the livestock supply chain to circumvent that limitation. The application, called BovChain, is a peer-to-peer (P2P) network connecting landowners and slaughterhouses. The objective of the application is twofold. Firstly, it maximizes sustainable business by reducing transaction costs and by strengthening ties between state-authorized stakeholders. Secondly, it creates metadata useful for digital certification by exploiting CMOS and GPS sensor technologies embedded in low-cost smartphones. Successful declarative transactions in the digital space are recorded as metadata, and the corresponding big data might be valuable for the certification of livestock origin and traceability for sustainability compliance in 'glocal' beef markets.North China suffers from severe haze pollution and has received widespread attentions since the winter of 2012. CA-074 Me nmr In addition to human activities, climate variability also plays an important role, particularly in the interannual-decadal variations in the number of haze days in North China (HDNC). Many previous studies separately explored numerous preceding climate drivers, including Arctic sea ice, Eurasia snow and soil moisture, sea surface temperature in Pacific and Atlantic and forcing of Tibetan Plateau, but lacked assessment and analysis of the joint effects. In this study, we reviewed their impacts on HDNC and associated physical mechanisms. Beyond that, the synergetic effects were newly revealed by the observations and numerical experiments with fixed emissions. The preceding signals explained approximately 66% of the interannual-decadal variations in HDNC by exciting teleconnection patterns in winter and influencing the local dispersion conditions in North China. Furthermore, some future research directions were identified, such as the subseasonal variations in HDNC, subseasonal-seasonal prediction of haze by numerical climate models, and changing relationships between HDNC and climate conditions.
Read More: https://www.selleckchem.com/products/ca-074-methyl-ester.html
     
 
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