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However, we found that the incorporation of urban ecosystem services in urban planning is low, but at the same time, it is in a promising development related to the application of innovative actions such as nature-based solutions and in support of the new global urban agenda. Investigating the spatiotemporal dynamics of contaminants in surface water is crucial to better understand how introduced chemicals are interacting with and potentially influencing aquatic organisms and environments. Within the Chesapeake Bay Watershed, United States, there are concerns about the potential role of contaminant exposure on fish health. Evidence suggests that exposure to contaminants in surface water is causing immunosuppression and intersex in freshwater fish species. Despite these concerns, there is a paucity of information regarding the complex dynamics of contaminant occurrence and co-occurrence in surface water across both space and time. To address these concerns, we applied a Bayesian hierarchical joint-contaminant model to describe the occurrence and co-occurrence patterns of 28 contaminants and total estrogenicity across six river sites and over three years. We found that seasonal occurrence patterns varied by contaminant, with the highest occurrence probabilities during the spring and summer months. Additionally, we found that the proportion of agricultural landcover in the immediate catchment, as well as stream discharge, did not have a significant effect on the occurrence probabilities of most compounds. Four pesticides (atrazine, metolachlor, fipronil and simazine) co-occurred across sites after accounting for environmental covariates. These results provide baseline information on the contaminant occurrence patterns of several classes of compounds within the Chesapeake Bay Watershed. Understanding the spatiotemporal dynamics of contaminants in surface water is the first step in investigating the effects of contaminant exposure on fisheries and aquatic environments. Crop growth conditions are being altered by ongoing climate change and the agronomic management practices should be adjusted accordingly and timely. In Chinese Maize Belt, climate change impacts are always compounded by agronomic management and the regional differences have yet to be well understood. How local farmers adapt to climate change is a big challenge and related adaptive strategies are urgently required. Based on detailed field experiments performed for >15 years, we applied the CERES-Maize model to disentangle the impacts of individual climate variables, quantify the contributions of three low-cost measures (cultivar, sowing date, and planting density) to yield variations, and design effective adaptation options in each zone. We found the patterns and impacts of climate change varied among the cultivated areas yield increased by 0.39% per year in Northeast China (NEC) and 0.78% in the northwestern arid area (NWA) but decreased by 1.13% in the North China Plain (NCP). The results highlighted the conto develop sustainable intensification options and improve yield and stability with fewer economic-environmental costs by optimizing G × E × M interactions in the future. FRAX486 concentration The use of colloidal silver-containing products as dietary supplements, immune boosters and surface disinfectants has increased in recent years which has elevated the potential for human exposure to silver nanoparticles and ions. Product mislabeling and long-term use of these products may put consumers at risk for adverse health outcomes including argyria. This study assessed several physical and chemical characteristics of five commercial products as well as their cytotoxicity using a rat intestinal epithelial cell (IEC-6) model. Concentrations of silver were determined for both the soluble and particulate fractions of the products. Primary particle size distribution and elemental composition were determined by transmission electron microscopy (TEM) and energy-dispersive X-ray spectroscopy (EDS), respectively. Hydrodynamic diameters were measured using nanoparticle tracking analysis (NTA) and dynamic light scattering (DLS). The effect of gastrointestinal (GI) simulation on the colloidal silver products was determined using two systems. First, physical and chemical changes of the silver nanoparticles in these products was assessed after exposure to Synthetic Stomach Fluid (SSF) resulting in particle agglomeration, and the appearance of AgCl on the surfaces and between particles. IEC-6 cells were exposed for 24 h to dilutions of the products and assessed for cell viability. The products were also treated with a three-stage simulated GI system (stomach and intestinal fluids) prior to exposure of the IEC-6 cells to the isolated silver nanoparticles. Cell viability was affected by each of the consumer products. Based on the silver nitrate and commercial silver nanoparticle dose response, the cytotoxicity for each of the colloidal silver products was attributed to the particulate silver, soluble silver or non‑silver matrix constituents. Published by Elsevier B.V.Accumulations of large woody debris can worsen scour at a bridge pier and thereby lead to structural damage. Accumulations can also increase the flood risk in adjacent areas. These consequences can cause disruption to local communities and even pose a risk to human life. Current methodologies acknowledge the existence of these effects of debris but do not provide a practical method, usable by engineers and practitioners, to assess the potential for debris accumulation at a bridge structure based on readily available data. This work aims to address this practical need by proposing a methodology based on direct and indirect observations. Using this methodology, a desk-based analysis can be performed to assess whether a bridge is prone to the formation of debris accumulations. Direct observations may include information from inspection reports, satellite imagery and tree removal works, while indirect observations may use information related to the geographical location of the bridge such as on other structures that share the watercourse or the presence of forested areas in its proximity. This methodology has been applied to local authority-owned bridges in Devon, UK. Results show that a large number of the structures (100 out of over 3000 bridges) are liable to debris accumulations. Direct observations served as primary evidence for over 80% of the bridges liable to debris accumulations. For many cases, direct observations existed to corroborate indirect observations suggesting that indirect observations can also be relied upon. The proposed methodology has also been applied to the prioritisation of bridge inspections for scour assessment. Results showed that many of the bridges prone to debris accumulations would need to be prioritised for scour inspections over other bridges in the aftermath of floods due to their significantly higher risk to scour in the presence of debris.
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