Notes

Novel lithium-nitrogen materials in background and also demands.
Erythrodiol (3β-olean-12-ene-3, 28-diol) (C30H50O2) 1 is a nanosized oleanane-type fused 6-6-6-6-6 pentacyclic triterpeneoid extractable from the dried leaves of olive (Olea europia). One step reduction of oleanolic acid extracted from Lantana camara also yields the same compound. The triterpenoid has one secondary -OH group attached at C3 of the "A" ring and one primary -OH group at C28 present at the junction of the "D" and "E" rings. Here, we report the spontaneous self-assembly of erythrodiol in different neat organic liquids and aqueous-organic liquid mixtures. The nanosized dihydroxy triterpenoid having an oleanane-type lipophilic rigid skeleton self-assembled in liquids, yielding nanosized fibrils, microsized flowers, and grass-like architectures via formation of densely assembled fibrils and petals or 2D sheets. The microstructures of the self-assemblies have been characterized by different techniques like optical microscopy, electron microscopy, atomic force microscopy, FTIR, and wide angle X-ray diffraction studies. The porous self-assemblies having a large surface area obtained from 1 were capable of adsorbing toxic fluorophores like rhodamine-B, rhodamine-6G, methylene blue, and crystal violet (CV). Moreover, removal of the aforementioned toxic pigments has also been demonstrated from their aqueous solutions by using UV-visible spectrophotometry and epifluorescence microscopy.In the steam-assisted-gravity-drainage (SAGD) process, heat energy is transferred from the steam chamber to the farther cold reservoir by conduction and convection mechanisms, so as to reduce the oil viscosity. In previous research works, although it was proved that convection is an indispensable part of the heat-transfer process, there is still a controversy about the formation mechanism of heat convection. In this study, an analytical mathematic model was proposed to explore the convective heat transfer in SAGD operation. Typically, this model integrates three heat convection forms that are generated by pressure difference, gravity, and thermal expansion of connate water,. Subsequently, the simulation results are compared with field data to evaluate the accuracy of the new model, and they are reasonably consistent with UTF field data. The results indicate that convective heat transfer plays a predominant role in the immediate vicinity of the steam chamber interface. Furthermore, this paper derives a mathematic model of oil production to explore the effect of heat convection on oil production under different operation conditions. The results demonstrate that heat convection has an adverse impact on oil production, but it is inevitable. This study also displays that some parameters, such as the lateral spreading rate, the thermal diffusivity, the viscosity coefficient, and the curvature of oil relative permeability curve, can significantly affect the oil production rate. Based on this study, the effect of convection mechanism on the heat-transfer process and oil production will be further clarified, and the parameters in the SAGD process can be optimized, so as to effectively enhance and predict oil production.Large dielectric constants and small remanent polarization of the relaxor-ferroelectric (RFE) polymers are favored for energy-harvesting applications. Here, the energy harvesting of RFE thin films of vinylidene fluoride (VDF)-based terpolymers were re-evaluated. VDF-based terpolymers with trifluoroethylene (TrFE) and chlorofluoroethylene (CFE), CFE terpolymer, and those with TrFE and chlorotrifluoroethylene were used. Thermally annealed CFE terpolymer exhibited an energy density of 8.3 J cm-3 and an energy efficiency of 82% at a field of 280 MV m-1. The high-energy efficiency was related to the narrow bipolar hysteresis of displacement (D)-electric field (E) of the CFE terpolymer film. This narrow D-E hysteresis was a sum of the unipolar hysteresis directed toward the positive electric field region and that toward the negative electric field region, which suggested antiferroelectric-like behavior.Of several samples of polyvinyl pyrrolidone (PVP) used to coat and stabilize freshly manufactured aqueous dispersions of silver nanoparticles, one batch gave anomalous results the dispersion maintained continued stability, even on extensive dilution. Our efforts to understand this desirable feature concluded that the generally used spectral method of PVP purity verification, Fourier transform infrared (FTIR) spectroscopy, was incapable of answering our inquiry. This led to the employment of several other methods, including X-ray photoelectron and nuclear magnetic resonance spectroscopies, which ultimately revealed several possible reasons for the dilution stability, including incomplete PVP hydrolysis during manufacture and the presence of hydroperoxide contaminants. It led, as well, to explanations for the shortcomings of FTIR spectroscopy as a verification method for PVP purity.In this paper, we present the formation of reversible covalently cross-linked networks in ethylene propylene rubber with grafted anthracene groups (EPM-g-AN) based on the principles of photoinduced anthracene dimerization. First, an industrial-grade EPM rubber grafted with maleic anhydride functional groups (EPM-g-MA) was modified with 9-anthracenemethanol. By irradiating EPM-g-AN with UV light (365 nm), the anthracene moieties dimerize via [4 + 4]cycloaddition, forming a covalent network. BAY 2666605 The network cleavage proceeds at high temperatures (>170 °C), even if with considerable (chemical) degradation. Furthermore, one of the degradation routes has been identified by 1H NMR to occur via the ester bond cleavage releasing 9-anthracenemethanol. Nevertheless, the reversibility of cross-linking has been achieved by performing the reverse reaction in decalin. The UV-vis spectroscopy clearly shows that the de-cross-linking process in these conditions is due to the anthracene dimer cleavage. Although the recovery in mechanical properties upon recycling is yet to be optimized, the disclosed results pave the way toward the use of anthracene chemistry in thermally reversible networks with possible industrial perspective applications.
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