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The results show that NiCo/Co4S3@C hybrid material is a potential electromagnetic wave absorber.Transition metal doped carbon materials are recognized as promising sensing platforms for glucose detection. Herein, a simple strategy involving crystallinity, nanostructure engineering, and pyrolysis was developed for constructing well-defined Ni nanoparticle embedded on nanoporous carbon nanorods (Ni/NCNs). A three-dimensional nickel-based metal-organic framework (Ni-MOF) was used as both a self-sacrificing template and precursor. Due to the synergistic effects between the uniformly dispersed Ni nanoparticles and the nanoporous carbon matrix, the as-prepared Ni/NCNs exhibited remarkable electrochemical activity. The fabricated Ni/NCNs glucose sensor showed excellent electrocatalytic performance with ultra-low limit of detection, wide linear detection ranges, fast response times (within 1.6 s), superior stability, and anti-interference characteristics. Moreover, the Ni/NCNs sensing platform was successfully applied to analyze glucose concentrations in human blood samples. These results showed that Ni/NCNs hold potential applications in developing enzyme-free glucose sensors."Two-for-one" strategy is an effective method to construct two kinds of materials from a single precursor owing to the simplicity of fabricating procedure and reduction of manufacturing cost. However, such a strategy has seldom been utilized to produce both battery-type and capacitive electrodes of a hybrid supercapacitor (HSC) device. Here, we adopt the "two-for-one" strategy to fabricate three-dimensional (3D) porous iron-doped (Fe-doped) Co3O4 and nitrogen-doped (N-doped) carbon via a single bimetallic metal-organic framework, FeCo-ZIF-67. Fe-doped amounts and carbonization temperature are used to adjust their individual electrochemical behaviors. The optimal 3D porous Fe-doped Co3O4 and N-doped carbon possess a high capacitance of 767.9 and 277C g-1 at 1 A g-1, respectively. Charge storage mechanism of Fe-doped Co3O4 is further investigated via analysis of capacitive and diffusion-controlled contribution. A Fe-doped Co3O4//N-doped carbon HSC device achieves desirable specific energy (37 Wh kg-1) and power (750 Wkg-1), and satisfied cycling stability (90% retention after 4000 cycles). A light-emitting diode (LED) is successfully light by the HSC device, suggesting its potential application in the field of green energy conversion and storage devices.With the increasing demand for miniaturization and portable energy storage system, it is an urgent necessary that developing high volumetric energy density supercapacitors with small volumes. Herein, an integrated self-supporting CoZnNiS@CNTs/rGO composite film electrode with the thickness of about 6 μm was designed. In the unique structure, porous CNTs/rGO film is served as conductive substrate to support the CoZn-MOFs derived vertically oriented two-dimensional CoZnNiS nanoarrays. The self-supporting film endows the electrode a high volumetric mass density of 1.28 g cm-3 and superior electron-ion transport channel, which displays a maximum specific capacitance of 1349.2 F g-1 as well as high volumetric capacity of 1727.0 F cm-3 at 1 A g-1. Sitagliptin inhibitor Besides, a porous film of pure carbon materials (carbon spheres integrated graphene) was designed and used as the negative electrode in supercapacitor. When assembled a hybrid supercapacitor based on the above two self-supporting electrodes, the device delivers up an ultra-high volumetric/gravimetric energy density of 65.2 W h L-1 (60.4 W h kg-1) at a power density of 1308 W L-1 (1200 W kg-1). Moreover, the asymmetric supercapacitor also displays an ultra-long lifetime with 90.6% retention after 10,000 cycles. These outstanding performances make the CoZnNiS@CNTs/rGO electrode could be a promising candidate for next-generation high volumetric/gravimetric energy density supercapacitors, especially in the limited space.Highly efficient light-emitting materials are essential for achieving high-performance devices. Here, a novel composite system, as well as enhanced luminescence processes, was designed, where NaLn(MoO4)2 ultra-small nucleus can be effectively isolated by In(OH)3 to form NaLn(MoO4)2@In(OH)3 composite nanoclusters due to the different nucleation rate between NaLn(MoO4)2 and In(OH)3, and then these small composite clusters gradually self-assemble into hierarchical structures. As we expected, the enhanced luminescence was achieved from hierarchical NaLn(MoO4)2 nanostructures with adjusting the distance among NaLn(MoO4)2 ultra-small nucleus by inserting In(OH)3. A series of spectroscopy results show that the In(OH)3 not only acts as an energy transfer bridge from CTB Eu3+ → O2- (or MoO42- absorption) to Eu3+, but also can effectively alleviate the concentration quenching of Ln3+ and change the J-O parameters. The Raman peak at 134 cm-1 is helpful to populate the 5D0 level of Eu3+ or the excited states of Er3+, resulting in stronger up/down-conversion emissions. The use of NaLn(MoO4)2@In(OH)3 in white light-emitting diodes (LEDs) has been demonstrated. The combination of red emission from NaLn(MoO4)2@In(OH)3 with blue, green, and yellow emission from halide perovskites could achieve white light with excellent vision performance (an LER of 376 lm/W) and superior color quality (CRI > 92). The findings of this experiment provide a new idea for the design of composite interface materials.The procalcitonin (PCT) assay is FDA-approved to help guide antimicrobial treatment, however, conflicting data exist regarding its impact on durations of therapy. The purpose of this study was to compare the impact of PCT to a targeted audit-and-feedback (TAF) strategy on antibiotic durations of therapy for community-acquired pneumonia (CAP). A retrospective cohort study was conducted at two community teaching hospitals, one implementing PCT with routine audit-and-feedback and one implementing TAF recommending 5 days of therapy for uncomplicated CAP. Three hundred eleven patients with antibiotics ordered having an indication of pneumonia were included (Pre-TAF n = 80, Pre-PCT n = 80, Post-TAF n = 80, Post-PCT n = 71). Average duration of therapy was similar at baseline (Pre-TAF = 7.0 days vs Pre-PCT = 7.8 days, p = 0.1) and post-intervention (Post-TAF = 5.5 days vs Post-PCT = 5.4 days, p = 0.8) between groups. PCT and TAF were equally effective antimicrobial stewardship strategies in reducing total days of antibiotic therapy prescribed for CAP with no differences observed in patient outcomes.
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