Notes

Target-receptive structural switching regarding ssDNA since picky and sensitive biosensor regarding up coming discovery of poisonous Pb2+ and organophosphorus pesticide.
Micropollutants reach the aquatic environment through wastewater treatment plant effluents. Ozonation, applied in wastewater treatment for micropollutants abatement, can yield transformation products (TP), which might be of ecotoxicological concern. Previous studies on TP formation were mostly performed in ultrapure water. However, the water matrix can have a substantial influence and lead to unpredictable yields of TPs with toxicological potential. In this study the acute toxicity (immobilization) of the parent substances (isoproturon and metoprolol) and also of available TPs of isoproturon, metoprolol and diclofenac towards Daphnia magna (D. magna) were investigated. Further, the acute toxicity of TP mixtures, formed during ozonation of isoproturon, metoprolol and diclofenac was evaluated in the following systems in the presence of radical scavengers (tert-butanol and dimethyl sulfoxide) and in the presence of hypobromous acid (HOBr), a secondary oxidant in ozonation. For all tested substances and TP standards, except 2,6-dichloroaniline (EC50 1.02 mg/L (48 h)), no immobilization of D. magna was detected. Ozonated pure water and wastewater did not show an immobilization effect either. After ozonation of diclofenac in the presence of dimethyl sulfoxide 95% (48 h) of the daphnids were immobile. Ozonation of parent substances, after the reaction with HOBr, showed no effect for isoproturon but a high effect on D. magna for diclofenac (95% immobilization (48 h)) and an even higher effect for metoprolol (100% immobilization (48 h)). These results emphasize that complex water matrices can influence the toxicity of TPs as shown in this study for D. magna.This study was conducted to compare the exposure levels of five heavy metals via different pathways based on the field samplings and questionnaire surveys of children residing in an informal e-waste processing village and a reference village in Viet Nam. The findings revealed that levels of the total average daily intake (ADI) of the five heavy metals collected from a child at the exposed village were 3.90 times higher (p less then 0.01) than that of a child at the reference village. Ingestion of cooked rice was the largest contributor to the total ADI of the children tested at both villages. However, the risks from water drinking and dermal contact of soil were negligible. The total non-carcinogenic risk and carcinogenic risk in an exposed child were significantly higher (p less then 0.01) than their respective risks in a reference child. The non-carcinogenic risk to an exposed child was likely to occur, while the risk to a reference child was negligible. The carcinogenic risks found in children from both of the villages, however, were higher than the acceptable values, indicating the potential health risks to the children from both villages. The susceptibility of children to heavy metal contaminations shown in this study suggests that a mitigating measure need to be initiated jointly by a public agency and a private organization to prevent children from the risks of being exposed to the contaminants.Most researches on the plastisphere in coastal environments deal with plastics floating in seawater. Comparatively smaller attention has been devoted to the plastisphere of plastics buried in marine sediments, and very little is known on that of plastics on coastal sand dunes. Yet, limited information is available on the impact of plastics, especially biodegradable plastics, on microbial organisms in their surroundings. read more Nevertheless, a large amount of plastics sink on the seabed or is deposited on beach-dune systems. We investigated the succession of plastisphere microbial community on two biodegradable composites based on poly(hydroxybutyrate-co-hydroxyvalerate) (PHBV) and seagrass fibres (PHBV/PO), buried in seabed and dune sediments over a 27 months period in mesocosm. PHBV is regarded as a valuable alternative to conventional plastics and PHBV/PO has recently been designed for applications in coastal habitat restoration. We also examined the degradation rate and impact of these plastics on the microbial cphere bacterial communities.Natural wildfires have a great effect on soil N transformation in subtropical forest. The pyrogenic organic matter (PyOM) in forest soils is mainly derived from the plant material burnt during forest fires, which affects soil N composition, N mineralization and nitrification. This study examined the effects of typical fresh plant material (leaves and twigs of Castanopsis sclerophylla, representing litter) and its biochar (representing PyOM) on N mineralization and nitrification in a subtropical forest soil. The soils were incubated with the plant material (PM), its biochar (BC) and their combinations for 84 days. Both PM and BC considerably increased soil pH and dissolved organic C, whereas PM decreased NO3--N and dissolved organic N. The additions of PM alone, and its combinations with BC resulted in net N immobilization. The rates of net N mineralization rapidly increased in first 14 days and then became stable following the addition of PM to soil. Moreover, the additions of PM and BC increased the abundances of archaeal amoA and bacterial amoA, especially with PM. The abundance of bacterial amoA correlated positively with soil pH and dissolved organic C, while archaeal amoA showed the opposite. Biochar affected soil properties and N transformation more significantly in the presence of PM, highlighting the need for further research on the interactions of plant litter and its biochar.We measured polychlorinated biphenyls (PCBs) in multiple age and size classes of Pacific sand lance (Ammodytes personatus), including eggs, young-of-the year, and adults to evaluate maternal transfer as a pathway for contaminant uptake and to add to the limited information on the occurrence of PCBs in sand lance in Puget Sound. Sampling was replicated at an urban embayment (Eagle Harbor) and a state park along an open shoreline (Clayton Beach), during spring and fall. Lipid-normalized concentrations of PCBs in sand lance at Eagle Harbor were 5-11 times higher than PCB concentrations in comparable samples at Clayton Beach. This was true for every life stage and size class of sand lance, including eggs removed from females. The same trend was observed in environmental samples. In Eagle Harbor, PCB concentrations in unfiltered water (0.19 ng/L), sieved ( less then 63 μm) nearshore bed sediments (0.78 ng/g dw) and suspended particulate matter (1.69 ng/g dw) were 2-3 times higher than equivalent samples from near Clayton Beach.
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