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Since isoprene is the most abundant hydrocarbon emitted into the atmosphere, and isoprene epoxydiols are the most important isoprene secondary organic aerosol precursors, our laboratory findings can aid in quantifying the direct radiative forcing of sulfates in the presence of organic compounds, thus more clearly resolving the impact of such aerosol particles on the Earth's climate.
To investigate the physical and mechanical behavior of polyether ether ketone (PEEK) before and after thermocycling and its potential use as a more durable prosthetic component for implant-supported and -retained removable dental prostheses (I-RDP).
Roughness and surface hardness were evaluated in specimens obtained using the subtractive method (n = 20) with Ø 9 mm and 2 mm of thickness, and retention force was measured in attachments with Ø 4 mm and 3 mm of height. For fatigue resistance test, a polyurethane matrix with two ball-abutment implants (MDL, Intra-Lock International) was used to simulate the mandibular alveolar ridge. buy Amcenestrant A total of 40 attachments (n = 20 pairs) were captured in acrylic resin blocks using a technique analagous to the direct clinical pick-up of overdenture female attachments and submitted to 2,900 insertion/removal cycles to simulate 24 months of overdenture use. Physical analyses were performed by Fourier transform infrared spectroscopy (FTIR), x-ray diffraction (XRD), and differet of greater durability for I-RDPs.
To evaluate the effect of different procedures for retightening the abutment screw on the screw stability between the abutment and implant.
External hexagon connection (EHC) and internal tri-channel connection (ITC) implants were employed in this study. Each abutment screw was used for the following applications (n = 5 for each group) group 0 = abutment was tightened and retightened with a 10-minute interval; group 1 = abutment was tightened and retightened with a 10-minute interval, then loaded for 500,000 cycles; group 2 = abutment was loaded for 83,000 cycles during tightening and retightening and then loaded for 500,000 cycles; group 3 = abutment was loaded for 167,000 cycles during tightening and retightening and then loaded for 500,000 cycles; and group 4 = abutment was loaded for 250,000 cycles during tightening and retightening and then loaded for 500,000 cycles. Both tightening and retightening torques were set at 35 Ncm, and dynamic oblique loading between 0 N and 200 N was applied on the abutment in all groups. The settlement of the abutments (settling value) after retightening and the abutments' removal torque values (RTVs) after testing were measured.
No significant differences in settling values were found for EHC or ITC. There were significant differences in the RTVs on EHC implants, but ITC implants showed no difference in RTV with different prosthetic retightening applications.
The retightening application affected the joint stability of EHC implants, but did not affect the settlement or joint stability of ITC implants.
The retightening application affected the joint stability of EHC implants, but did not affect the settlement or joint stability of ITC implants.
To evaluate the performance of fully (Celtra Duo, Dentsply Sirona) and partially (VITA Suprinity, VITA) crystallized zirconia-reinforced lithium silicate and partially sintered lithium disilicate (IPS e.max CAD, Ivoclar Vivadent) glass-ceramics submitted to polishing, glazing, or no surface treatment after aging.
Specimens of each glass-ceramic were subjected to polishing with rubber cups (POL), glazing (GL), or control (C; no treatment) and afterwards aged with 18,000 thermal cycles (5°C to 55°C). The average roughness (Ra), 2D and 3D morphology, contact angle, multispecies biofilm formation (Streptococcus mutans and Candida albicans), and mechanical strength were evaluated by atomic force microscopy (AFM, n = 5), sessile-drop goniometry (n = 5), spectrophotometry (n = 5), and flexural strength test (n = 10), respectively. Data were analyzed using two-way analysis of variance and Tukey test (α = 5%).
POL promoted lower Ra than glazing, and Celtra Duo presented higher Ra than IPS e.max CAD (P < .05).CAD, which makes zirconia-reinforced lithium silicate glass-ceramics a good option for indirect restorations.
To measure the retrieval force required to remove 1.5-mm-thick CAD/CAM zirconia copings cemented on zirconia (Zr) and titanium (Ti) stock implant abutments after a single application of erbium-doped yttrium scandium gallium garnet (ErYSGG) laser.
A total of 60 monolithic Zr copings were cemented on Zr and Ti implant abutments with either a resin-modified glass-ionomer (RelyX Luting Plus Cement, 3M ESPE; Rx) or a zinc oxide eugenol cement (Temp-Bond, Kerr; Tb). These abutment-coping specimens were randomly divided into 12 groups based on laser application (vs control [C]), abutment type (Zr vs Ti), cement (Rx vs Tb), and storage condition (dry [D] vs saline water [W]). ErYSGG laser was applied at 6 W, 30% water-60% air, and 20 Hz (300 mJ/pulse energy) postcementation following a defined pattern. The force required to remove all the cemented copings from their abutments was measured on a universal testing machine (Instron model 4204). Descriptive statistics, multi-factor analysis of variance, and post hoc Tseful for clinicians managing cement-retained implant crown complications.
Within the limitations of this study, it can be concluded that ErYSGG laser allows for easier removal of cemented Zr copings with lower removal forces, with Ti abutment groups requiring lower forces than Zr abutment specimens. No significant difference was seen between laser and control groups for Tb compared to Rx. ErYSGG laser shows great clinical promise for predictable retrievability of cemented, monolithic Zr implant crowns, especially with stronger resin-based cement such as Rx. With further clinical evidence, this could be very useful for clinicians managing cement-retained implant crown complications.
To assess the influence of substructure and dimension on the fracture strength of ceramic discs made from both lithium disilicate ceramic and zirconia.
A total of 128 intact maxillary third molars were collected, and standardized enamel and dentin discs were fabricated. Lithium disilicate ceramic (IPS e.max CAD, Ivoclar Vivadent; n = 64) and zirconia (Katana, Kuraray; n = 64) discs with 0.5-mm (n = 32 IPS and n = 32 Katana) and 1-mm (n = 32 IPS and n = 32 Katana) thickness were produced, and each group was divided into two subgroups (n = 16 each) that were luted to the enamel or dentin discs using Panavia V5 (Kuraray). Half of the specimens in each subgroup were aged (chewing simulation and thermocycling), and all specimens were loaded until fracture in a universal testing machine (Z010, Zwick/Roell). Differences between Katana and IPS with respect to enamel and dentin as substructure and the thickness of the ceramic were analyzed by use of a nonparametric test (Mann-Whitney U test).
In un-aged specimens, fracture loads were not significantly (P > .
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