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Boiling is an essential process in numerous applications including power plants, thermal management, water purification, and steam generation. Previous studies have shown that surfaces with microcavities or biphilic wettability can enhance the efficiency of boiling heat transfer, that is, the heat transfer coefficient (HTC). Surfaces with permeable structures such as micropillar arrays, in contrast, have shown significant enhancement of the critical heat flux (CHF). In this work, we investigated microtube structures, where a cavity is defined at the center of a pillar, as structural building blocks to enhance HTC and CHF simultaneously in a controllable manner. We demonstrated simultaneous CHF and HTC enhancements of up to 62 and 244%, respectively, compared to those of a smooth surface. The experimental data along with high-speed images elucidate the mechanism for simultaneous enhancement where bubble nucleation occurs in the microtube cavities for increased HTC and microlayer evaporation occurs around microtube sidewalls for increased CHF. Furthermore, we combined micropillars and microtubes to create surfaces that further increased CHF by achieving a path to separate nucleating bubbles and rewetting liquids. This work provides guidelines for the systematic surface design for boiling heat transfer enhancement and has important implications for understanding boiling heat transfer mechanisms.Self-powered ultraviolet photodetectors offer great potential in the field of optical communication, smart security, space exploration, and others; however, achieving high sensitivity with maintaining fast response speed has remained a daunting challenge. Here, we develop a titanium dioxide-based self-powered ultraviolet photodetector with high detectivity (≈1.8 × 1010 jones) and a good photoresponsivity of 0.32 mA W-1 under pulsed illumination (λ = 365 nm, 4 mW cm-2), which demonstrate an enhancement of 114 and 2017%, respectively, due to the alternating current photovoltaic effect compared to the conventional direct current photovoltaic effect. Further, the photodetector demonstrated a high on/off ratio (≈103), an ultrafast rise/decay time of 112/63 μs, and a noise equivalent power of 5.01 × 10-11 W/Hz1/2 under self-biased conditions. SP2509 order Photoconductive atomic force microscopy revealed the nanoscale charge transport and offered the possibility to scale down the device size to a sub-10-nanometer (∼35 nm). Moreover, as one of the practical applications, the device was successfully utilized to interpret the digital codes. The presented results enlighten a new path to design energy-efficient ultrafast photodetectors not only for the application of optical communication but also for other advanced optoelectronic applications such as digital display, sensing, and others.Efficient electron transmission is an important step in the process of CO2 photoreduction. In this paper, a multi-interface-contacted In2S3/Au/reduced graphene oxide (rGO) photocatalyst with the fluorescence resonance energy transfer (FRET) mechanism has been successfully prepared by the solvothermal, self-assembly, and hydrothermal reduction processes. Photocatalytic CO2 reduction experiments showed that the In2S3/Au/rGO (IAr-3) composite exhibited excellent photoreduction performance and photocatalytic stability. The yields of CO and CH4 obtained after the photoreduction process with IAr-3 as the catalyst were around 4 and 6 times higher than those of pure In2S3, respectively. Photoelectrochemical analysis showed that the multi-interface contact and FRET mechanism greatly improved the generation, transmission, and separation efficiency of carriers photogenerated within the photocatalyst. In situ FTIR test was applied to analyze the photocatalytic CO2 reduction process. 13C isotope tracer test confirmed that the carbon source of CO and CH4 was the CO2 molecules in the photoreduction process rather than the decomposition of catalyst or TEOA. A potential enhanced photocatalytic mechanism has been discussed in total.Low-dimensional Ge is perceived as a promising building block for emerging optoelectronic devices. Here, we present a wafer-scale platform technology enabling monolithic Al-Ge-Al nanostructures fabricated by a thermally induced Al-Ge exchange reaction. Transmission electron microscopy confirmed the purity and crystallinity of the formed Al segments with an abrupt interface to the remaining Ge segment. In good agreement with the theoretical value of bulk Al-Ge Schottky junctions, a barrier height of 200 ± 20 meV was determined. Photoluminescence and μ-Raman measurements proved the optical quality of the Ge channel embedded in the monolithic Al-Ge-Al heterostructure. Together with the wafer-scale accessibility, the proposed fabrication scheme may give rise to the development of key components of a broad spectrum of emerging Ge-based devices requiring monolithic metal-semiconductor-metal heterostructures with high-quality interfaces.Two-dimensional (2D) nanoporous membranes have attracted great interest in water desalination, energy conversion, electrode, and gas separation. The performances of these membranes are mainly determined by the nanopores, and only with satisfactory subnanometer pores can applications such as high-precision ion separation be realized. Therefore, to efficiently create subnanopores in 2D materials is of great importance. Here, using molecular dynamics simulations, we demonstrate that the direct irradiation of energetic ion is capable of introducing subnanopores in monolayer graphene. By changing the energy of the incident Au ion, the averaged pore diameter can be adjusted from 4.2 to 5.6 Å, and pore diameter distributions are narrow. In the formation processes of the subnanopores, the cascade collisions caused by the primary knock-on atom (PKA) predominates, and pores can only be created in ion impact positions close to the PKA, especially for the incident ion with high energy. Our results show the promise of ion irradiation as a facile method to fabricate subnanopores in 2D materials. As hydrated ions, gases, and small organic molecules have diameters of several angstroms, close to the pore sizes, the created nanoporous membranes can be used to separate those matter, which is conducive to accelerating related applications.
Read More: https://www.selleckchem.com/products/sp2509.html
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