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An overall Model pertaining to Biofilm-Driven Bacterial Electrosynthesis regarding Carboxylates Coming from Carbon.
The developed MIP-EC sensor with simple and fabrication process can provide a versatile and reliable method, which has great potential application value for the detection of small hazardous molecules.Waste biomass derived biochar has been proven as an effective and friendly amendment for remediation of heavy metals-contaminated soil. However, biochar is less effective for soil arsenic (As) immobilization in most cases. To improve the ability of biochar for As immobilization, in this study, the composite of biochar embedded with nano zero valent iron (nZVI/BC) was prepared through simple one-step pyrolysis of biomass sawdust and Fe2O3 mixture and then applied for amendment of two mining As-contaminated soils. Pristine sawdust biochar (BC) and nZVI alone or in combination were included for comparison. Results show that the prepared nZVI/BC contained about 40% Fe which was mainly present as Fe°. All treatments except BC reduced As concentration in (NH4)2SO4 extraction and gastrointestinal solution. Particularly, nZVI/BC reduced the labile As in (NH4)2SO4 extraction in two soils by over 93% and bioaccessible As in gastrointestinal solution decreased by over 85%. Fe° on the surface of nZVI/BC was oxidized into amorphous FeOOH which adsorbed or co-precipitated with As. Meanwhile, Ca-Fe-As-O and Al-Fe-As-O co-precipitated at the interface between nZVI/BC and two soils enriched with Ca and Al, respectively. Results indicated that the simply-prepared nZVI/BC was a promising material for remediation of As-contaminated soils.Covalent organic frameworks (COFs) have recently been demonstrated to have great application potentials in water treatment. Their photocatalytic performance towards bacterial disinfection and organic pollutant degradation yet has seldom been investigated. TJM20105 In this study, AgI modified COFs (using 2,5-diaminopyridine and 1,3,5-triformylphloroglucinol as precursors) (COF-PD/AgI) were fabricated and their applications to photocatalytically disinfect bacteria and degrade organic pollutants were investigated. COF-PD/AgI exhibited effective photocatalytic performance towards Escherichia coli disinfection and organic pollutant (Rhodamine B and acetaminophen) degradation. SEM images were employed to investigate cell disinfection process, while theoretical density functional theory (DFT) calculation and intermediates determination were used to elucidate organic pollutant degradation processes. Scavenger experiments, ESR spectra and chemical probes experiments confirmed O2-, h+ and OH played important roles in the photocatalytic process. The formation of dual-band Z-scheme heterojunction improved photocatalytic performance. COF-PD/AgI remained high photocatalytic activity in the four consecutive cycles and could serve as a promising photocatalyst for water purification.Aims To determine 1) the relationship between infant medical factors and early neurobehavior, and 2) the relationship between early neurobehavior at 30 weeks postmenstrual age (PMA) and neurobehavior at term equivalent age. Study design In this prospective longitudinal study, 88 very preterm infants born ≤30 weeks estimated gestational age (EGA) had neurobehavioral assessments at 30 weeks PMA using the Premie-Neuro and at term equivalent age using the NICU Network Neurobehavioral Scale (NNNS) and Hammersmith Neonatal Neurological Evaluation (HNNE). Results Lower Premie-Neuro scores at 30 weeks PMA were related to being more immature at birth (p = 0.01; β = 3.87); the presence of patent ductus arteriosus (PDA; p less then 0.01; β = -16.50) and cerebral injury (p less then 0.01; β = -20.46); and prolonged exposure to oxygen therapy (p less then 0.01; β = -0.01), endotracheal intubation (p less then 0.01; β = -0.23), and total parenteral nutrition (p less then 0.01; β = -0.35). After controlling for EGA, PDA, and number of days of endotracheal intubation, lower Premie-Neuro scores at 30 weeks PMA were independently related to lower total HNNE scores at term (p less then 0.01; β = 0.12) and worse outcome on the NNNS with poorer quality of movement (p less then 0.01; β = 0.02) and more stress (p less then 0.01; ß = -0.004), asymmetry (p = 0.01; β = -0.04), excitability (p less then 0.01; β = -0.05) and suboptimal reflexes (p less then 0.01; ß = -0.06). Conclusion Medical factors were associated with early neurobehavioral performance at 30 weeks PMA. Early neurobehavior at 30 weeks PMA was a good marker of adverse neurobehavior at NICU discharge.Background & aims Children and adolescents born very preterm are at increased risk to develop executive function deficits and to suffer from social, emotional and attentional problems. This study investigated whether executive function deficits contribute to behavioral problems in children and adolescents born very preterm at school-age. Study design Thirty-eight children and adolescents born very preterm and 41 age-matched term-born peers were assessed at a mean age of 12.9 (±1.8) years with a comprehensive battery of executive function tests, including working memory, planning, cognitive flexibility, and verbal fluency. A composite score was calculated to reflect overall executive function abilities. To assess behavioral problems, parents completed the Strengths and Difficulties Questionnaire (SDQ). Mediation analysis was applied to quantify the effect of preterm birth on behavioral problems with executive function abilities as a mediating variable. Results Executive function abilities were poorer in the very preterm compared to the term-born group (d = 0.62, p = .005) and the parents of very preterm children reported more behavioral problems on the SDQ Total Difficulties Score (d = 0.54, p = .01). The effect of birth status on behavioral problems was significantly mediated by executive function abilities while adjusting for age at assessment, sex, and socioeconomic status (F(2, 76) = 6.42, p = .002, R2 = 0.14). Conclusion Results from this study suggest that the increase in behavioral symptoms in very preterm children at school-age compared to term-born peers may partly be explained by their executive function deficits. These findings highlight the importance of continuously monitoring the development of children born very preterm to provide optimal care as they grow up.
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