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A strategy involving biochar (BC) hybrid modification was developed to promote the bioremediation effect of degrading bacteria immobilized in layer-by-layer assembly (LBL) microcapsules for the treatment of phenanthrene (PHE) polluted soil. A taxonomic and functional metagenomic approach was used to investigate changes in the microbial community structures and functional gene compositions in the PHE-polluted soil during the bioremediation process. Biofortification with an initial PHE concentration of 100 mg kg-1 dry soil in soils using the BC (3%) hybrid LBL bio-microcapsule (BC-LBL, 2.0 g kg-1 dry soil, 107 colony forming unite cell g-1 dry soil) was faster; further, a higher PHE degradation efficiency (80.5% after 25 d) was achieved when compared with that by the LBL agent (66.2% after 25 d) used. Sphingomonas, Streptomyces, Gemmatirosa, Ramlibacter, Flavisolibacter, Phycicoccus, Micromonospora, Acidobacter, Mycobacterium and Gemmatimonas were more abundant in BC-LBL treatment than those in LBL one. Functional gene annotation results showed that more gene number with BC-LBL treatment than those with LBL one. More abundant functions in the former were primarily related to the growth, reproduction, metabolism, and transportation of bacteria. BC hybridization promoting PHE degradation by microencapsulated bacteria may be due to the strong adsorption property of BC, which results in the enrichment of the nutrients that needed for bacterial growth and reproduction, as well as enhancing the mass transfer performance of PHE to BC-LBL; Meanwhile, BC could also stimulate and improve the metabolism and membrane transportation of the degrading bacteria, and finally improving the degradation function.With the rapid degradation of coral reefs due to global warming and anthropogenic impacts, relatively high-latitude areas, such as the northern South China Sea (SCS), are likely to become refuges for tropical coral species. Here we investigated the genetic features and adaptability of one dominant scleractinian coral species, Turbinaria peltata, in the northern SCS. A total of 81 samples from 5 sites were studied to explore potential mechanisms of adaptability to environmental stress as a result of climate change. Ten microsatellite markers developed in this study, one nuclear gene (internal transcribed spacer, ITS), and one mitochondrial gene (mitochondrial cytochrome oxidase subunit I gene, mtDNA COI) were used. Our results indicated that the genetic diversity of T. peltata in the northern SCS is low (Ar = 1.403-2.011, Ho = 0.105-0.248, He = 0.187-0.421) with the lowest in Dongfang population (DF) (Ar = 1.403, Ho = 0.22, He = 0.187). These results indicate that T. peltata has insufficient genetic adaptabilirotection of relatively high-latitude coral reefs.Exposure to wildfire smoke continues to be a growing threat to public health, yet the chemical components in wildfire smoke that primarily drive toxicity and associated disease are largely unknown. This study utilized a suite of computational approaches to identify groups of chemicals induced by variable biomass burn conditions that were associated with biological responses in the mouse lung, including pulmonary immune response and injury markers. Smoke condensate samples were collected and characterized, resulting in chemical distribution information for 86 constituents across ten different exposures. Mixtures-relevant statistical methods included (i) a chemical clustering and data-reduction method, weighted chemical co-expression network analysis (WCCNA), (ii) a quantile g-computation approach to address the joint effect of multiple chemicals in different groupings, and (iii) a correlation analysis to compare mixtures modeling results against individual chemical relationships. Seven chemical groups were ideluding markers of inflammation. Many of the effects identified through mixtures modeling in this analysis were not captured through individual chemical analyses. Together, this study demonstrates the utility of mixtures-based approaches to identify potential drivers and inhibitors of toxicity relevant to wildfire exposures.This study suggests a new perspective of biochar as a building material that improve not only for the strength but also hygrothermal properties. Biochar has a high porosity and surface area created by pyrolysis. It can be suitably used as a porous material because porous materials are used by incorporating into building materials for improving hygrothermal performance in the construction sector. To analyze whether biochar can be used as a functional building material to improve the hygrothermal performance, two types of biochar, made from oilseed rape (OSB) and mixed softwood (SWB), were prepared. A biochar-mortar composite was prepared according to the mixing ratio of the biochar from 2 wt% to 8 wt%, and the compressive strength and hygrothermal performance of them were analyzed. The compressive strength is the highest when 4 wt% of biochar into the mortar was mixed regardless of the type of biochar. Thermal conductivity of biochar-mortar composites was decreased as the biochar addition increased, and the value of biochar-mortar composites with 8 wt% OSB decreases by maximum 57.6% compared to the conventional cement mortar. selleck products The water vapor resistance factor of biochar-mortar composites increases, and biochar-mortar composites with 8 wt% SWB increases by maximum 50.9% compared to the reference. WUFI simulation shows that the biochar-mortar composites can contribute to a humidity control and no mold growth. The biochar-mortar composites can also contribute to energy savings although the amount of savings is insignificant. As a result, this study proved that when the mortar with biochar addition was possible to improve not only strength but also hygrothermal properties of mortar. This approach will be a new perspective that biochar can apply to the building material in practice.Microscale zero-valent iron (mZVI) has been widely used for the in-situ groundwater remediation of various pollutants. However, the aging behavior of injected mZVI particles limits the widespread application in groundwater remediation projects. To assess the long-term reactivity of mZVI particles, the mechanism of trichloroethylene (TCE) degradation by various aged mZVI particles (A-mZVI) was determined by quantitatively evaluating the contributions of chemical reduction and adsorption. Further, this study investigated the physicochemical transformation of mZVI particles aged under various hydraulic conditions (static and dynamic), redox conditions (anoxic and aerobic) and aging durations (152 d and 455 d). The results show that the removal of TCE by different A-mZVI particles increased the sorption capacity in the initial period (0-6 h). However, in the long term, a significant inhibition of TCE removal was observed because of the decreased TCE reduction capacity caused by the hindrance of electron transfer, which was generated by corrosion precipitates.
Read More: https://www.selleckchem.com/
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