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Moreover, the direct photolysis quantum yield was also lower in water matrices compared to ultra-pure water. Similar findings reported for triclosan and the herbicide 2-methyl-4-chlorophenoxyacetic acid in previous studies might suggest that the water matrix components could carry out either physical quenching of cilastatin's excited states or back-reduction to cilastatin of the partially oxidized degradation intermediates. Overall, the present results demonstrate that UVC irradiation is a fast and efficient process for the degradation of cilastatin in natural water and treated wastewater.Integration of semiconducting nanostructures with noble metal nanoparticles are turning highly desirable for cost efficient energy and environmental related applications. From this viewpoint, we report on a facile aqueous synthesis of polymer capped gold (Au) nanoparticles on free standing 2D layered structures of zinc oxide (ZnO) to result with ZnO/Au nanocomposites. Concentration of Au nanoparticles were observed to promote the preferential growth of ZnO along the (002) wurtzite plane. The ZnO/Au structures and their morphological dissemination was noted to be of few. This flake like structure was also noted to be greatly influenced by the concentration of Au in the colloidal blend. Optical band edge transformations noted in the absorption spectra across the lower wavelength region and the shift in surface plasmon resonance (SPR) towards the red region of the visible spectrum signify the improved absorptivity of the heterostructures along the visible spectrum. These heterostructures exhibited remarkable visible light driven photocatalytic activity (99% efficiency) on par with pristine ZnO. The findings also attest this new class of composite structures to open up new openings in diversified solar energy conversion related functions.Non-steroidal anti-inflammatory drugs (NSAIDs) are medications used individually or as mixtures with other pharmaceuticals for the treatment of various illnesses. Their easy accessibility and high human consumption have resulted to their detection at high concentrations in South African water resources. In the present work, an extensive review of the occurrence and ecotoxicological risk assessment of NSAIDs in South African aquatic environment is provided. Reviewed literature suggested ibuprofen, naproxen, diclofenac, ketoprofen and fenoprofen as the most prominent NSAIDs in the South African aquatic environment. Among these NSAIDs, higher concentrations of ibuprofen are common in South African waters. As a result, this drug was found to pose high ecotoxicological risks towards the aquatic organisms with the highest risk quotients of 14.9 and 11.9 found for algae in surface water and wastewater, respectively. Like in other parts of the world, NSAIDs are not completely removed in wastewater treatment plants. Removal efficiencies below 0% due to higher concentrations of NSAIDs in wastewater effluents rather than influents were observed in certain instances. The detection of NSAIDs in sediments and aquatic plants could serve as the important starting step to investigate other means of NSAIDs removal from water. In conclusion, recommendations regarding future studies that could paint a clearer picture regarding the occurrence and ecotoxicological risks posed by NSAIDs in South African aquatic environment are provided.Over the last century, contamination of polycyclic aromatic hydrocarbons (PAHs) has risen tremendously due to the intensified industrial activities like petrochemical, pharmaceutical, insecticides and fertilizers applications. PAHs are a group of organic pollutants with adverse effects on both humans and the environment. These PAHs are widely distributed in various ecosystems including air, soil, marine water and sediments. Degradation of PAHs generally occurs through processes like photolysis, adsorption, volatilization, chemical degradation and microbial degradation. PF-543 supplier Microbial degradation of PAHs is done by the utilization of diverse microorganisms like algae, bacteria, fungi which are readily compatible with biodegrading/bio transforming PAHs into H2O, CO2 under aerobic, or CH4 under anaerobic environment. The rate of PAHs degradation using microbes is mainly governed by various cultivation conditions like temperature, pH, nutrients availability, microbial population, chemical nature of PAHs, oxygen and den their mode of degradation.Phthalates (PAEs) often exist simultaneously in contaminated soil and wastewater systems, and their adsorption to biochar might impact their behavior in the environment. So far, the competitive adsorption of PAEs to biochar has not been reported. In this study, the competitive adsorption of Dibutyl phthalate (DBP) and Di(2-ethylhexyl) phthalate (DEHP) on corncob biochar (fresh and oxidized) was investigated, and experiments of kinetics, isotherms, and thermodynamics were conducted. Langmuir and Freundlich models, pseudo-first-order and second-order kinetic models were used to simulate the experimental data. In the mono PAEs component systems, the biochar showed significantly greater adsorption capacity for DEHP (11.8-16.16 mg g-1) than for DBP (9.86-13.2 mg g-1). The oxidized biochar has higher adsorption capacities than the fresh one. Moreover, a fast adsorption rate for DBP was observed, which can be attributed to the smaller size and shorter carbon chains in the DBP molecule, resulting in faster diffusion into the biochar pores. In the binary PAEs component systems, competition between DEHP and DBP in their adsorption to the biochars was observed, and DEHP (11.7-15.0 mg g-1) was preferred over DBP (3.4-7.9 mg g-1). The stronger adsorption of DEHP can be explained by stronger hydrophobic interaction with biochar. Compared to DBP, DEHP has a high octanol-water partition coefficient (logKow) and low water solubility. The positive entropy (ΔS0) and enthalpy(ΔH0) values for the adsorption of both DEHP and DBP further indicated that hydrophobic interaction played an important role, even though H-bonds and π-π interactions could also be involved.Per- and polyfluoroalkyl substances (PFAS) are a large group of perfluorinated organic molecules that have been in use since the 1940s for industrial, commercial, and consumer applications. PFAS are a growing concern because some of them have shown persistent, bioaccumulative and toxic effects. Herein, we demonstrate an innovative technology of UV-vis/ZnxCu1-xFe2O4/oxalic acid for the degradation of perfluorooctanoic acid (PFOA) in water. The magnetically retrievable nanocrystalline heterogeneous ferrite catalysts, ZnxCu1-xFe2O4 were synthesized using a sol-gel auto-combustion process followed by calcination at 400 °C. The combination of ZnxCu1-xFe2O4 and oxalic acid generate reactive species under UV light irradiation. link2 These reactive species are then shown to be capable of the photodegradation of PFOA. The degree of degradation is tracked by identifying transformation products using liquid chromatography coupled with quadrupole time-of-flight mass spectroscopy (LC-QTOF-MS).Poor effect of contaminants removal efficiency and low organic matter content of activated sludge are common in wastewater treatment plants (WWTPs) in China due to the low-strength wastewater. An anaerobic-anoxic-oxic (AAO) and an adsorption/AAO (A/AAO) combined system were established simultaneously to conduct a comparative study for realizing the conversion of carbon source in influent and the enrichment and recovery of proteins and amino acids through the assimilation of ammonia nitrogen. The experimental results showed that 63.5% of the organic matter in influent was adsorbed and flocculated in adsorption process, and the removal rates of chemical oxygen demand, total nitrogen and total phosphorus in A/AAO process were 88.7%, 77.1%, and 93.0% respectively, which were remarkably better than those in AAO process owing to the addition of improved carbon source. Ammonia assimilation rate of A/AAO process was 26.7% higher than that of AAO process, which implied that the ammonia used to synthesize sludge protein was prominently increased. Furthermore, intracellular proteins and amino acids in A/AAO process were 20% higher than those of AAO process, and the quality was equivalent with fish meal or soybean meal as feed. In addition, the microbial community analysis based on 16S rDNA was conducted. Dechloromonas, Zoogloea, Nitrospira, and Flavobacterium were the main genera, and played important roles in nutrient removal and ammonia nitrogen assimilation. The integration of adsorption process was significant to low-strength wastewater treatment and the improvement of excess sludge quality, which is a prospective inspiration for the resource recovery-based wastewater treatment process.Amendment of soil with organic urban and animal wastes can keep arable soil fertile without the need for synthetic fertilizers. However, pollutants present in these types of waste might be carried into the soil with unintended consequences for the environment. We studied an experimental agricultural plot, which had been amended with either synthetic inorganic fertilizers, human urine, manure, or wastewater treatment sludge at very high rates. We applied chemical non-target analysis to characterize present organic micropollutants, intending to compare treatments and highlight suspects of environmental concern. Soil samples were prepared by pressurized liquid and purified with solid-phase extraction before analysis with nanoflow ultra-high performance liquid chromatography coupled to high-resolution Orbitrap tandem mass spectrometry. Automated elucidation with two mass spectral libraries, multiple large chemical databases and environmental NORMAN suspect lists was able to annotate (level 3 and level 2) ∼ 20% of the 2306 detected features. A following principal component- and differential-analysis could separate the soil treatment groups' pollution profiles and highlight high relative abundance features. From cattle manure, natural compounds such as bile acids and steroids were found. Human urine led to pollution with common pharmaceuticals such as metoprolol and propranolol. The highest number was added by wastewater treatment sludge, with 25 significant contaminants, spanning blood pressure regulators, antidepressants, synthetic steroids and sleep medication. link3 Furthermore, using Kendrick mass defect plots, a series of polypropylene glycols could be revealed in the soil. Non-target analysis appears to be a promising method to characterize organic pollutants in soils.Hemophilia A and hemophilia B are X-linked inherited bleeding disorders caused by a deficiency of coagulation factor VIII and IX, respectively. Standard of care is prophylactic factor replacement therapy; however, the development of neutralizing antibodies against these factors represents serious complications underlining the need for alternative treatment approaches. Human coagulation factor X has a central role within the blood coagulation system making it an attractive target for the development of alternative treatment strategies for patients with hemophilia. This study focuses on a modified variant of the human coagulation factor X with enhanced hemostatic bypass activity due to insertion of a factor IX derived activation sequence. This molecule design leads to the direct activation of the modified factor X protein by factor XIa allowing it to bypass the need for coagulation factor VIIIa/factor IXa. The modified variant was able to correct in-vitro activated partial prothrombin time of human and murine factor VIII/factor IX deficient plasma.
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