Notes

Hand-washing techniques amongst mums involving under-5 youngsters within Vent Harcourt, Africa.
5%, 32.7%, and 3.3%, respectively. The predicted high gene abundance of xenobiotics biodegradation & metabolism, carbohydrate metabolism, and assimilatory sulfate reduction in the consortium, indicated a co-metabolism between carbohydrate metabolism, sulfate metabolism, and LEV degradation under glucose and sulfate added condition. The study revealed that simultaneous addition of glucose and sulfate is the favorable condition for LEV anaerobic degradation.As a class of highly toxic and persistent organic pollutants, polycyclic aromatic hydrocarbons (PAHs) are an increasingly urgent environmental problem. Low-molecular-weight organic acids (LMWOAs) are important factors that regulate the degradation of PAHs by plant rhizosphere microorganisms, which affect the absorption of PAHs by plant roots. However, the comprehensive mechanisms by which LMWOAs influence the biodegradation of PAHs at cellular and omics levels are still unknown. Here, we systematically analyzed the roles of citric, glutaric and oxalic acid in the PAH-degradation process, and investigated the mechanisms through which these three LMWOAs enhance phenanthrene (PHE) biodegradation by B. subtilis ZL09-26. The results showed that LMWOAs can improve the solubility and biodegradation of PHE, enhance cell growth and activity, and relieve membrane and oxidative stress. Citric acid enhanced PHE biodegradation mainly by improving the strain's cell proliferation and activity, while glutaric and oxalic acid accelerated PHE biodegradation mainly by improving the expression of enzymes and providing energy for the cells of B. subtilis ZL09-26. This study provides new insights into rhizospheric bioremediation mechanisms, which may enable the development of new biostimulation techniques to improve the bioremediation of PAHs.Cr(VI) ranks as one of the most toxic heavy metals and herein, microscopic mechanisms for adsorption and transport of different Cr(VI) oxyanions (Cr2O72- and CrO42-) at kaolinite interfaces are addressed by dispersion-corrected periodic density functional theory calculations. Cr(VI) oxyanions adsorb favorably at both tetrahedral and octahedral surfaces, and K+ ions serve as bridge for Cr(VI) oxyanions and tetrahedral surfaces while Cr(VI) oxyanions serve as bridge for K+ ions and octahedral surfaces. Adsorption structures are altered significantly by pH variation, and stability trends at different pH ranges are deciphered by the dominant interaction force with clay surfaces Electrostatic interaction with K+ ions at tetrahedral surfaces whereas combined action of electrostatic and H-bonding interactions with Cr(VI) oxyanions at octahedral surfaces. Electron transfers are strongly pH-dependent, and clay surfaces serve as electron reservoirs. CrO42- rather than Cr2O72- is dominant at clay interfaces, and HCrO4- can co-exist under acidic conditions. Cr2O72- transformation to CrO42- is kinetically blocked at pH ≈ PZC while preferred at pH 7.0 and pH less then PZC, respectively. Results greatly promote the understanding about Cr(VI) bioavailability and fate in surficial environments and are also useful for Cr(VI) removal and reclamation.A potential industrial waste-waste co-treatment process was proposed and verified for the recovery of the valuable metals Co, Ni, and Cu from copper smelting slag by utilizing high temperature SO2 off-gas. Sulfation roasting followed by water leaching under designed thermodynamic conditions was conducted to facilitate the selective formation of Co, Ni, and Cu sulfates while separating iron as oxide. Several parameters were studied such as roasting temperature, roasting time, the addition of Na2SO4, and leaching agent. Under the optimized sulfation roasting conditions (Gas flow 500 mL/min, 5% SO2 +20% O2 +75% Ar; Roasting temperature 650 °C; Roasting time 4 h; Addition of Na2SO4 30%) followed by water leaching (Leaching temperature 80 °C; Leaching time 5 h; solid to liquid ratio 0.05 g/mL), the extraction yields of Ni, Co, and Cu were shown to reach 95.8% and 91.8%, 81.6%, respectively. Furthermore, the sulfation roasting - water leaching process was confirmed on lab-scale as a feasible and efficient way to recover valuable metals and the mechanism was determined and verified from the microstructural evolution. Finally, a potential environmentally friendly industrial process in terms of the energy flow and material flow was presented based on preliminary assessments for environmental benefits, economic benefits, and heat recovery.Poor bioavailability of antibiotics, toxicity, and development of antibiotic-resistant bacteria jeopardize antibiotic treatments. To circumvent these issues, drug delivery using nanocarriers are highlighted to secure the future of antibiotic treatments. This work investigated application of nanocarriers, to prevent and treat bacterial infection, presenting minimal toxicity to the IPEC-J2 cell line. To accomplish this, polymer-based nanoparticles (NPs) of poly(lactide-co-glycolide) (PLGA) and lignin-graft-PLGA (LNP) loaded with enrofloxacin (ENFLX) were synthesized, yielding spherical particles with average sizes of 111.8 ± 0.6 nm (PLGA) and 117.4 ± 0.9 nm (LNP). The releases of ENFLX from PLGA and LNP were modeled by a theoretical diffusion model considering both the NP and dialysis diffusion barriers for drug release. Biocompatible concentrations of ENFLX, enrofloxacin loaded PLGA(Enflx) and LNP(Enflx) were determined based on examination of bacterial inhibition, toxicity, and ROS generation. Biocompatible concentrations were used for treatment of higher- and lower-level infections in IPEC-J2 cells. SecinH3 ic50 Prevention of bacterial infection by LNP(Enflx) was enhanced more than 50% compared to ENFLX at lower-level infection. At higher-level infection, PLGA(Enflx) and LNP(Enflx) demonstrated 25% higher prevention of bacteria growth compared to ENFLX alone. The superior treatment achieved by the nanocarried drug is accredited to particle uptake by endocytosis and slow release of the drug intracellularly, preventing rapid bacterial growth inside the cells.Hexavalent chromium (Cr(VI)) is one of the typical heavy metals that pose a great threat to the environment. As a novel biotechnology, algal-bacterial aerobic granular sludge (AGS) possesses the merits of both bacterial AGS and algae. This study firstly evaluated Cr(VI) removal via biosorption by algal-bacterial AGS under different operation conditions and then some environmental factors. Results show that the highest Cr(VI) reduction (99.3%) and total Cr removal (89.1%) were achieved within 6 h at pH 2 and 6, respectively. The coexisting oxyanions exhibited slight effects, while both tested natural organic matters (humic acid and tannic acid) and carbon sources promoted Cr(VI) reduction at some appropriate concentrations. The coexistence of metal cations favored Cr(VI) reduction, achieving the highest enhancement of 8.1% by Cu2+ at 5 mg/L, while the total Cr removal was suppressed to some extent. Salinity > 5 g/L severely inhibited both Cr(VI) reduction and total Cr removal. Moreover, the loaded Cr in algal-bacterial AGS was found to be almost in the form of Cr(III), with 66.
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