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Cadmium is one of the most common heavy metal pollutants in the aquatic environment. Mud crab (Scylla paramamosain) is considered a model organism to monitor the impact of heavy metals. However, knowledge about toxicological mechanism of cadmium in crustaceans still remains limited. In this study, mud crabs were exposed to different concentrations of cadmium (0, 1.25, 2.5, 5 and 10 mg/L) for 72 h. Cadmium exposure significantly decreased superoxide dismutase (SOD) activity, catalase (CAT) activity and total antioxidative capacity (T-AOC), and significantly increased malondialdehyde (MDA) and H2O2 levels. Aspartate aminotransferase (AST), alanine aminotransferase (ALT) and lactate dehydrogenase (LDH) activity significantly increased after cadmium exposure. Moreover, integrated biological responses version 2 (IBRv2) analysis suggested that cadmium exposure exerted stronger toxicity on mud crab. Furthermore, oxidative stress induced by cadmium exposure could decrease total hemocyte count (THC), interrupt Ca2+ homeostasis, and lead to cytological damage. Cadmium exposure induced DNA damage, which activated DNA damage response signaling ATR-CHK1-p53 pathway. Our results also showed that cadmium exposure significantly increased the apoptosis and caspase-3 mRNA levels, which implied that cadmium induced apoptosis through a caspase-3 pathway.Intense seaweed grazing by sea urchins has destroyed kelp forests and accelerated the transformation of these forests into barren areas known as urchin barrens. Once the sea urchins occupy the barren ground, it becomes more challenging to restore the kelp forests. Although phlorotannin, a primary herbivore defense chemical secreted by kelp, has been reported to discourage feeding activities of marine herbivores but the direct application of naturally extracted phlorotannin does not effectively repel sea urchins. In this study, we applied a simple and green Tannin-FeIII (TA-FeIII) coating on substrates as a sea urchin repellent using a cheap, ecofriendly tannin (TA) obtained from biomass as an alternative to phlorotannin. In a model aquarium experiment, most of the sea urchins (Anthocidaris crassispina) in the tank evaded the TA-FeIII-coated substrates. In field tests with 300 sea urchins, the majority of sea urchins could not crawl over the TA-FeIII-coated rope for more than 2 h in contrast to the control group. Hence, the safety, cost-effectiveness, and scalability of the TA-FeIII coating make it a practical candidate to protect the kelp ecosystem from sea urchins.Maternal transfer of contaminants is an important route of exposure for many species during embryonic development, which might compromise the organism throughout its life cycle. Here, we report the maternal offloading of polycyclic aromatic hydrocarbons (PAHs) in an elasmobranch, the Brazilian guitarfish Pseudobatos horkelii. Eighteen PAHs were determined by gas chromatography in maternal liver and uterine content (uterine eggs and early-stage development embryos) samples to determine the maternal transfer rate. The mean rate of PAHs offloaded to the offspring was of 13%, with high variability among individual congener transfer (0.7-29.9%) and benzo[b]fluoranthene attaining the highest maternal transfer rates. Differential transfer rates were attributed to physicochemical proprieties of each compound, with low molecular level PAHs presenting the highest rates. A depuration mechanism in which females decrease their maternal transfer rate as a function of size, related to consecutive reproductive cycles was not properly observed in this study. From a conservation perspective, these results indicate that elasmobranchs embryos of an endangered species can be exposed to PAHs during their development and, considering the possible harmful effects of these compounds to other early life stage organisms, deleterious effects could be a possibility, although this was not analyzed herein.The contamination of sediments by polycyclic aromatic hydrocarbons (PAHs) has been widely spread for years due to human activities, imposing the research and development of effective remediation technologies for achieving efficient treatment and reuse of sediments. In this context, the amendment of biochar in PAH-contaminated sediments has been lately proposed as an innovative and sustainable technology. This review provides detailed information about the mechanisms and impacts associated with the supplementation of biochar to sediments polluted by PAHs. The properties of biochar employed in these applications have been thoroughly examined. Sorption onto biochar is the main mechanism involved in PAH removal from sediments. Sorption efficiency can be significantly improved even in the presence of a low remediation time (i.e. 30 d) when a multi-PAH system is used and biochar is provided with a high dosage (i.e. by 5% in a mass ratio with the sediment) and a specific surface area of approximately 360 m2 g-1. The use of biochar results in a decrease (i.e. up to 20%) of the PAH degradation during bioaugmentation and phytoremediation of sediments, as a consequence of the reduction of PAH bioavailability and an increase of water and nutrient retention. selleck chemical In contrast, PAH degradation has been reported to increase up to 54% when nitrate is used as electron acceptor in low-temperature biochar-amended sediments. Finally, biochar is effective in co-application with Fe2+ for the persulfate degradation of PAHs (i.e. up to 80%), mainly when a high catalyst dose and an acidic pH are used.Graphene Oxide Monolith composites (GOMs) were prepared using dimethylaminopropylamine (DMPDA) and N-isopropylethylenediamine (IPEDA) with one-step method in water medium, respectively. Fourier transform-infrared (FTIR), X-Ray Diffraction (XRD) tests proved the formation of new structure and credible interactions between crosslinkers and GO. Scanning electron microscopy (SEM) showed distinct change of morphology after complexing. Bath adsorption tests suggested that the fast adsorption of copper ions (II) was strongly affected by pH, ionic strength, temperature, and concentration, etc.. Isothermal Langmuir and Freundlich kinetic model showed the different degree of fitting conformity according to different conditions. SEM and XRD further provided a supporter of adsorption of copper ions onto GOMs, and Density functional theory (DFT) was used to analyze the crosslinking details of DMPDA and GO and the adsorption mechanism of copper ions. The theoretical calculation results clarified an efficacious and quantitative understanding for the crosslinking and adsorption mechanism.
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