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Increasing nitrogen fertilization and irrigation can contribute to nitrous oxide (N2O) emissions from agriculture. Relative to the conventional practice of one-pass fertilization with all N applied at crop seeding, this study examined how splitting the total N fertilization into seeding time and in-crop fertigation impacts N2O emission factors (EF) in irrigated wheat (Triticum aestivum) and canola (Brassica napus) in Southern Alberta, Canada during two growing seasons (May to Oct. in 2015 and 2016). With all the N applied at crop seeding, the growing-season N2O EF of irrigated wheat and canola was in average 0.23 ± 0.03%. Conversely, implementing N fertigation lowered the magnitudes of N2O EF in each of the four crop-years, averaging 0.16 ± 0.04%. Most of the reductions in N2O emissions due to fertigation occurred with low and intermediate N rates (total rates of 60 and 90 kg N ha-1) and in the second year of the study. This second year had recurrent, early-season rainfalls following seeding (and prior to fertigation) that triggered differences in the daily and cumulative N2O fluxes. Within this year, fertigation on wheat consistently lowered the growing-season N2O EF from a high of 0.27% to only 0.11% (P less then 0.001). Also, at the intermediate rate of 90 kg N ha-1, fertigation synergistically reduced the N2O EF of canola by half, from 0.13% to 0.06% (P less then 0.01). However, the mitigating effects of fertigation vanished with the highest N rate in the study (120 kg N ha-1). PIM447 Even with fertigation, this highest N rate resulted in high emissions in wheat, and lesser so in canola in part due to the higher N uptake of canola. Moreover, canola often manifested narrower ratios of N2O emission-to-grain yield (EFyield) than wheat. This interplay of crop species, rainfall and N management suggests that implementing fertigation with reduced N rates can proactively mitigates N2O.The antimicrobial triclosan (TCS) is a pervasive and persistent environmental micropollutant which can contaminate land, biota, and water through the land application of biosolids. Many existing sludge management techniques have limited effectiveness against TCS and TCS metabolites including triclosan-sulfate (TCS-SO4). The objective of this study was to evaluate the impacts of different digestion types (anaerobic, aerobic/anoxic, and sequential anaerobic + aerobic/anoxic), temperatures, and digester sludge retention times (SRTs) on the destruction of organic matter, and on TCS/TCS metabolites. Conventional mesophilic anaerobic digesters (AD), room temperature cycling aerobic/anoxic digesters (AERO/ANOX), and sequential AD + AERO/ANOX digesters were all effective in removing organic matter. The optimum single-stage AD, and AERO/ANOX scenarios were both 20-day SRTs which had 52.3 ± 1.4 and 47.1 ± 3.7% chemical oxygen demand (COD) removals, respectively. Sequential AD + AERO/ANOX digesters improved organic matter destruction, removing up to 68.2 ± 2.1% of COD at an 8-day AD + 12-day AERO/ANOX second-stage (mesophilic) SRTs. While AD showed modest levels of TCS removals (all less then 40%), TCS was substantially more degradable aerobically with AERO/ANOX removing up to 80.3 ± 2.5% of TCS and nearly all TCS-SO4 entering the digester at a 20-day SRT. Sequential AD + AERO/ANOX removed virtually all TCS-SO4 entering the system and improved TCS removals from first stage ADs. However, they were less effective than a single-stage AERO/ANOX digester operating at the same overall SRT. These results demonstrate that AERO/ANOX and sequential AD + AERO/ANOX processes could be used to reduce the amount of TCS, TCS-SO4 and TCS-related compounds in digested sludge, minimizing the environmental burden of the land application of biosolids.The aims of this study were to select the most suitable macrophyte species and substrate to be used in horizontal subsurface flow (HSSF) wetlands for the treatment of a local cheese factory wastewater, and to quantify the influence of plant species and substrates by applying of a simple first-order kinetic model. Microcosms-scale HSSF wetlands were planted with Canna glauca or Typha domingensis. LECA and river stones were used as substrates. Both studied macrophytes showed a high tolerance to the treated wastewater. HSSF wetlands were efficient for the treatment of diluted cheese production wastewater. COD, TP, NH4+-N and TN showed high removal efficiencies in all the HSSF wetlands. HSSF wetlands planted with C. glauca showed the best performance for removal of NH4+-N. The highest SRP removal was obtained in HSSF wetlands planted C. glauca with LECA as substrate. A simple first-order kinetics model was applied. The fitted parameters of the modified first-order model k-C* allowed to demonstrate the effect of the plants in the treatment of the effluent. HSSF wetlands planted with C. glauca using river stones were the systems that showed the fastest TIN removal. According to the obtained results, it is proposed to use C. glauca and river stones as substrate in a HSSF wetland for the treatment of this wastewater. The present study provides useful data to design a wetland at a larger scale.Cyanobacteria and their toxic secondary metabolites are a challenge in water treatment due to increased biomass and dissolved metabolites in the raw water. Retrofitting existing water treatment infrastructure is prohibitively expensive or unfeasible, hence 'in-reservoir' treatment options are being explored. In the current study, a treatment system was able to photocatalytically inhibit the growth of Microcystis aeruginosa and remove released microcystins by photocatalysis using titanium dioxide coated, porous foamed glass beads and UV-LEDs (365 nm). A 35% reduction of M. aeruginosa PCC7813 cell density compared to control samples was achieved in seven days. As a function of cell removal, intracellular microcystins (microcystin-LR, -LY, -LW, and -LF) were removed by 49% from 0.69 to 0.35 μg mL-1 in seven days. Microcystins that leaked into the surrounding water from compromised cells were completely removed by photocatalysis. The findings of the current study demonstrate the feasibility of an in-reservoir treatment unit applying low cost UV-LEDs and porous foamed beads made from recycled glass coated with titanium dioxide as a means to control cyanobacteria and their toxins before they can reach the water treatment plant.
Most studies relying on time-activity diary or traditional air pollution modelling approach are insufficient to suggest the impacts of ignoring individual mobility and air pollution variations on misclassification errors in exposure estimates. Moreover, very few studies have examined whether such impacts differ across socioeconomic groups.
We aim to examine how ignoring individual mobility and PM2.5 variations produces misclassification errors in ambient PM2.5 exposure estimates.
We developed a geo-informed backward propagation neural network model to estimate hourly PM2.5 concentrations in terms of remote sensing and geospatial big data. Combining the estimated PM2.5 concentrations and individual trajectories derived from 755,468 mobile phone users on a weekday in Shenzhen, China, we estimated four types of individual total PM2.5 exposures during weekdays at multi-temporal scales. The estimate ignoring individual mobility, PM2.5 variations or both was compared with the hypothetical error-free estimate misclassification error occurs in the estimate neglecting PM2.5 variations than that ignoring individual mobility, which is seldom reported before.
Ignoring individual mobility, PM2.5 variations or both leads to misclassification errors in ambient PM2.5 exposure estimates. A larger misclassification error occurs in the estimate neglecting PM2.5 variations than that ignoring individual mobility, which is seldom reported before.Manure application mitigates land degradation and improves soil fertility. Despite many individual studies on manure effects, a comprehensive overview of its consequences for a broad range of soil properties is lacking. Through a meta-analysis of 521 observations spanning the experiments from days after pulse addition up to 113 years with continues manure input, we quantified and generalized the average responses of soil biochemical properties depending on climate factors, management, soil, and manure characteristics. Large increase of pools with fast turnover (microbial carbon (C) and nitrogen (N) +88% and +84%, respectively) compared to stable organic matter pools (+27% for organic C, and +33% for total N) reflects acceleration of C and N cycles and soil fertility improvement. Activities of enzymes acquiring C-, energy-, N-, phosphorus- and sulfur were 1.3-3.3 times larger than those in soil without manure for all study durations included. Soil C/N ratio remained unaffected, indicating the stability of coupled C and N cycles. Microbial C/N ratio decreased, indicating a shift towards bacterial domination, general increase of C and N availability and acceleration of element cycling. Composted manure or manure without mineral fertilizers induced the greatest increase compared to non-composted manure or manure with mineral fertilizers, respectively, in most biochemical properties. The optimal manure application rate for adjusting proper soil pH was 25 Mg ha-1 year-1. Among manure types, swine manure caused the greatest increase of N-cycle-related properties microbial N (+230%), urease (+258%) and N-acetyl-β-D-glucosaminidase (+138%) activities. Manure application strategies should avoid P and N losses and pollution via runoff, leaching or gaseous emissions due to fast mineralization and priming of soil organic matter. In conclusion, manure application favors C accumulation and accelerates nutrient cycling by providing available organic substances and nutrients and thus increasing enzyme activities.Recent work has demonstrated that surface colour affects the formation of cyanobacterial subaerial biofilms on polycarbonate coupons and, in turn, influences their bioreceptivity. To explore whether colour is important on other substrates, the influence of colour on the primary bioreceptivity of granite to the terrestrial green alga Apatococcus lobatus (Trebouxiophyceae, Chlorophyta) has been assessed. Two granitoids (Grissal and Rosa Porriño) with the same texture, and very similar chemical composition, open porosity and surface roughness, but different coloration related to feldspars (i.e. greyish and reddish) were used to conduct bioreceptivity studies in parallel field and laboratory tests. Light microscopy, colour spectrophotometry, PAM fluorometry, and optical profilometry were used to evaluate colonisation and its impacts. Short-term results (after 7 and 10 weeks of colonisation by a mono-species biofilm) from both lab and field trials, showed significantly more algae growth on reddish granite (Rosa Porriño) than on greyish granite (Grissal). Also, optical profilometry and light microscopy demonstrated that on both granites algal aggregates developed in hollows. We attribute the roughly double levels of A. lobatus growth on reddish vs greyish granite to differences in the amount of radiant energy absorbed and the higher levels of red wavelength light (known to encourage algal growth) reflected from the reddish surface.
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