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Quick Cognitive-Behavioral Treatments with regard to Destruction Elimination (BCBT-SP) by means of Online video Telehealth: A Case Case in point In the COVID-19 Outbreak.
Additionally, the release of iron nanoparticles from the composite at various pHs (3-10) were found negligible, which demonstrates the effectiveness of smec-nZVI to remove As(V) from contaminated water without posing any secondary pollutant.The heterogeneous catalytic process has been under development for aqueous pollutant degradation, yet electron transfer efficiency often limits the effectiveness of catalytic reactions. In this study, a novel composite material, manganese doped iron-carbon (Mn-Fe-C), was tailor designed to promote the catalytic electron transfer. The Mn-Fe-C composite, synthesized via a facile carbothermal reduction method, was characterized and evaluated for its performance to activate persulfate (PS) and degrade Rhodamine Blue (RhB) dye under different pH, catalyst dosages, PS dosages, and pollutant concentrations. Electron spin resonance, along with quenching results by ethanol, tert-butanol, phenol, nitrobenzene and benzoquinone, indicated that surface bounded SO4•- was the main contributor for RhB degradation, while the roles of aqueous SO4•- and •OH were very minor. Through characterization by XRD, XPS and FTIR analysis, it was determined that the electron transfer during activation of PS was accelerated by the oxygen functional groups on catalyst surface and the promoted redox cycle of Fe3+ and Fe2+ by Mn. Finally, the Mn-Fe-C composite catalyst exhibited an excellent reusability and stability with negligible leached Fe and Mn ions in solutions. Results of this study provide a promising design for heterogeneous catalysts that can effectively activate PS to remove organic pollutants from water at circumneutral pH conditions.Biochar-derived dissolved organic matter (BDOM), which has a substantial impact on the environmental behavior of heavy metals, is critical for understanding the environmental efficacy of biochar. Here, we used a suite of advanced spectroscopic and mass spectroscopic methods to investigate the relationship among the pyrolysis temperature of biochar, composition of BDOM, and interactions of BDOM with Cu. The binding affinity of BDOM and Cu showed incredibly increase, with the increasing pyrolysis temperature (300-500 °C) which promoted the release of condensed aromatic compounds and oxygen-containing functional groups from biochar into dissolved phase. A notable difference in the sequences binding with Cu was occurred during the changing pyrolysis temperature. The amide only involved in the binding process between Cu and BDOM at low-temperature (300 and 400 °C), whereas phenolic only associated with the such binding process at high-temperature (500 °C). Apart from this, the carboxyl and polysaccharides took part in the binding process of Cu with BDOM, no matter how higher the temperature is. A further analysis by X-ray absorption spectroscopy revealed that bidentate carboxylic-Cu complexes appear to be the predominant binding pattern for Cu to BDOM. Our results might contribute to provide novel information for the environment applications of biochar.The impact of microplastic pollution on terrestrial biota is an emerging research area, and this is particularly so for soil biota. In this study, we addressed this knowledge gap by examining the impact of aged low-density polyethylene (LDPE) and polyester fibres (i.e. polyethylene terephthalate, PET) on a forest microbiome composition and activity. We also measured the corresponding physicochemical changes in the soil. We observed that bacteria community composition diverged in PET and LDPE treated soils from that of the control by day 42. These changes occurred at 0.2% and 0.4% (w/w) of PET and at 3% LDPE. Additionally, soil respiration was 8-fold higher in soil that received 3% LDPE compared to other treatments and control. There were no clear patterns linking these biological changes to physicochemical changes measured. Taken together, we concluded that microplastics aging in the environment may have evolutionary consequences for forest soil microbiome and there is immediate implication for climate change if the observed increase in soil respiration is reproducible in multiple ecosystems.The development of multi-responsive chemosensors has a bright application prospect in environmental monitoring and biological diagnosis. In this paper, we report two kinds of fluorescent polyaniline-like derivatives containing of carbazole or fluorene moieties with two-dimensional (2D) nano-layered structure and their applications in the detection of Al3+, Fe3+, Cu2+ and HCl in different environments. Through the analysis of the structure and properties of these two 2D materials, we find that the prepared (Poly(9,9'-(9,9-dihexyl-9H-fluorene-2,7-diyl)bis(9H-carbazol-3-amine))) PDFCA material performs excellent sensing properties for above analytes. Relevant density functional theory (DFT) calculation further confirms the potential application of 2D nano-layered PDFCA material in sensing field. This study presents that 2D nano-layered PDFCA material is considerably competitive in the development of multi-responsive chemosensors, and it will greatly accelerate the research of 2D polymer materials.The insights on the primary surface-reactive oxygen species and their relation with lattice defects is essential for designing catalysts for plasma-catalytic reactions. Herein, a series of Ba1-xCexTiO3 perovskite catalysts with high specific surface areas (68.6-85.6 m2 g-1) were prepared by a facile in-situ Ce-doping strategy and investigated to catalytically decompose toluene. Combining the catalysts with a nonthermal plasma produced a significant synergy effect. The highest decomposition efficiency (100%), COx selectivity (98.1%), CO2 selectivity (63.9%), and the lowest O3 production (0 ppm) were obtained when BC4T (Ce/Ti molar ratio = 4100) was packed in a coaxial dielectric barrier discharge reactor at a specific input energy of 508.8 J L-1. The H2-TPR, temperature-programmed Raman spectra, EPR and OSC results suggested that superoxides (•O2-) were the primary reactive oxygen species and were reversibly generated on the perovskite surface. Molecular O2 was adsorbed and activated at the active sites (Ti3+-VO) via an electron transfer process to form •O2-. Surface-adsorbed •O2- had a greater effect on the heterogeneous surface plasma reactions than the dielectric constant, and enhanced the toluene decomposition and intermediate oxidation. A possible reaction path of toluene decomposition was also proposed.Novel particle electrodes, i.e. flotation tailings particle electrode (FPE), were prepared using flotation tailings, garden soil, and soluble starch with a mass ratio of 1631, and then used in tetracycline wastewater treatment. The physicochemical properties of FPE were systematically characterized using SEM, XRD, FT-IR and XRF. Tetracycline adsorption and its adsorption mechanism onto FPE was explored for the first time. Parameters affecting FPE's degradation efficiency and energy consumption such as current density, electrolysis time, initial concentration, initial pH and aeration rate were examined. The electrocatalytic degradation of tetracycline shows that the degradation of tetracycline meets the pseudo-first-order kinetics. Moreover, the numbers of •OH produced on the surfaces of the cathode, anode and particle electrode were compared. Results showed that the adsorption-saturated FPE can be regenerated by electrochemical action to induce further absorption and form in-situ electrocatalysis. In order to find out the transformation products in water and degradation pathways of Tetracycline, UHPLC method was used to obtain the degradation pathways for Tetracycline. So, this work could provide a fabrication of high-efficiency and low-cost electrocatalytic for removal of pharmaceuticals pollutants from waste water as well as deeper insight into electrocatalytic mechanism, transformation products, and degradation pathways of Tetracycline in water.A novel biochar metal oxide composite was synthesized for effective removal of arsenate (As(V)) from aqueous solution. The materials synthesized for As(V) removal was based on a biosolid-derived biochar (BSBC) impregnated with zirconium (Zr) and zirconium-iron (Zr-Fe). see more The synthesized materials were comprehensively characterized with a range of techniques including Brunauer-Emmett-Teller (BET-N2) surface area, zeta potential, Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The results confirmed that loading of Zr and Zr-Fe onto the biochar surface was successful. The influence of pH, biochar density, ionic strength, As(V) dose rate, major anions and cations on As(V) removal was also investigated. Under all pH and reaction conditions the Zr-Fe composite biochar removed the greatest As(V) from solution of the materials tested. The maximum sorption capacity reached 15.2 mg/g for pristine BSBC (pH 4.0), while modified Zr-BSBC and Zr-FeBSBC composites achieved 33.1 and 62.5 mg/g (pH 6), respectively. The thermodynamic parameters (Gibbs free energy, enthalpy, and entropy) suggested that the adsorption process is spontaneous and endothermic. The ZrBSBC and Zr-FeBSBC showed excellent reusability and stability over four cycles. Unmodified biochar resulted in partial reduction of As(V) under oxic conditions, whilst modified biochars did not influence the oxidation state of As. All results demonstrated that the Zr and Zr-Fe BSBC composites could perform as promising adsorbents for efficient arsenate removal from natural waters.Microplastics (MPs) are widely found in complex solid matrices such as soil, sediments and sludge. The separation procedure is crucial for effective analysis of MPs, but existing methods varied among studies. Here, we systematically summarize and compare separation methods including density, oil, electrostatic, magnetic, and solvent extraction separation. Density separation is the most commonly used approach, but time-consuming and discharging hazardous materials dependent on extraction solutions. In contrast, oil, electrostatic, magnetic separation and solvent extraction separation are emerging approaches with advantages of low-cost, quick, or environmentally-friendly, but with high request of instruments. Despite variation among these approaches, the separation efficiency is closely related to characteristics of MPs including polymer types, sizes and shapes. The treatment of digestion and fluorescence staining can facilitate the detection of MPs. This analysis suggests that further optimization and improvement of existing approaches can facilitate the development of new separation technology for assaying MPs in complex environmental matrices.Chlorothalonil (CHL) and procymidone (PRO) are fungicides that exhibit low toxicity and are widely used in many countries. And both fungicides are frequently detected in the food chain. However, the health risk posed by these fungicides is still unclear. Here, 8-week-old male C57BL/6 mice were orally treated with CHL (10, 50 mg/kg/day), PRO (20, 100 mg/kg/day) and CHL+PRO (5+10, 25+50 mg/kg/day) by dietary supplementation for 10 weeks. Hepatic pathological analysis showed that exposure to CHL, PRO and CHL+PRO could cause liver injury. The glucose, triglyceride (TG) levels and the related gene expression to glucolipid metabolism changed significantly. The significantly reduced acylcarnitine levels demonstrated that CHL, PRO and CHL+PRO exposure inhibited fatty acids (FAs) β-oxidation. In addition, CHL and PRO altered the structure of the gut microbiota and destroyed the integrity of the intestinal barrier function. In particular, AF12, Odoribacter, Prevotella and Lactobacillus were highly correlated with carnitine.
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