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It is also understood that in order to gain a better understanding of local post-corrosion bond behavior, de-bonding between reinforcement and concrete needs to be modeled in a discrete analysis framework.The disposal of high-level radioactive waste (HLW) in deep stable geological formations is accepted at an international level to be the most promising option for its long-term management. The supercontainer concept is currently being considered as the Belgian reference design, wherein the waste will be stored in geological stable clay formations. The outer barrier of the supercontainer is the envelope, which should be made of a corrosion-resistant material as it will be in contact with the aggressive species leaching from the host rock (i.e., chloride) and diffusing through the cementitious barriers of the disposal system. Polarization measurements are carried out to study the pitting susceptibility and the uniform corrosion of possible candidate materials in chloride-rich concrete pore solutions, aerated by high-purity oxygen. The tests are carried out at a deep soil-representative temperature of 60 °C. All materials showed high pitting resistance in aerated concrete pore solutions and can withstand chloride concentrations up to 1 M. Regular 316L and LDX2304 stainless steel also showed good corrosion resistance and can serve as a more economical alternative. The pH of the used pore solutions did affect the measured corrosion rate irrespective of the alloying elements inside the steel grades.To solve the global shortage of land and offshore resources, the development of deep-sea resources has become a popular topic in recent decades. Deep-sea composites are widely used materials in abyssal resources extraction, and corresponding marine exploration vehicles and monitoring devices for deep-sea engineering. This article firstly reviews the existing research results and limitations of marine composites and equipment or devices used for resource extraction. By combining the research progress of smart composites, deep-sea smart composite materials with the three characteristics of self-diagnosis, self-healing, and self-powered are proposed and relevant studies are summarized. Finally, the review summarizes research challenges for the materials, and looks forward to the development of new composites and their practical application in conjunction with the progress of composites disciplines and AI techniques.The finite element analysis of tubular structures is typically based on models constructed employing beam-type elements. This modeling technique provides a quick and computationally efficient option for calculation. Nevertheless, it shows a series of limitations related to the simplicity of this type of element, among which the inability of accounting for the stiffness behavior at the joint level is of notable importance when modeling complex tubular structures. Despite these limitations, the alternative of simulating complex tubular structures with shell- or volume-type elements is highly costly due to the complexity of the modeling process and the computational requirements. Previous research has proposed alternative beam models that improve the estimations when modeling these structures. These research validations were limited to simple models. This paper presents a validation process utilizing a previously developed beam T-junction model in a complex tubular structure, intended to be representative for buses' and coaches' upper structures. Results obtained reveal that the accuracy of beam element type models can be significantly improved with the adequate implementation of elastic elements to account for the real junction stiffness.Since glass fiber-reinforced polymer (GFRP) bars have a lower modulus than steel bars, the design of GFRP-reinforced concrete (GFRP-RC) is often governed by the serviceability limit state (deflection and cracking) rather than the ultimate state. A new design method has been proposed in this paper for GFRP-RC beams based on the flexure crack width. The state when the maximum flexure crack width in the tensile zone reaches the limit of 0.5 mm specified by ACI 440.1R-15 was used as the design limit state. The concrete compressive strain at the extreme compression fiber of concrete under the design limit state was obtained by four-point bending tests of eight full-scale GFRP-RC beams and finite element analysis. Based on the concrete compressive strain under the design limit state and cross-sectional analysis, a design method for calculating the longitudinal reinforcement ratio of GFRP-RC beams under the design limit state is proposed. This design method is proven to be feasible by the experimental and the finite element results. In addition, the flexural capacity coefficient was discussed to investigate the safety reserve of the design method.001TiO2/TiOF2 photocatalytic composites with a high activity 001 crystal plane were prepared by one-step hydrothermal methods using butyl titanate as a titanium source and hydrofluoric acid as a fluorine source. X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), raman spectroscopy, N2 adsorption-desorption curve (BET), UV-Vis diffuse absorption spectroscopy (UV-Vis DRS), X-ray photoelectron spectroscopy (XPS), and fluorescence spectroscopy (PL) were used to evaluate the structure, morphology, specific surface area, optical properties, and photocarrier separation ability of 001TiO2/TiOF2. Ammonia nitrogen was taken as the target pollutant, and the degradation performance of the catalyst was investigated. The results show that hydrofluoric acid improves the content of 001 crystal plane of TiO2 with high activity; it also improves the specific surface area and dispersion of the composite material and adjusts the ratio of 001TiO2 to TiOF2 in the composite material to enhance the absorption capacity of the composite material and reduce the band gap width of the composite material. The degradation rate of ammonia nitrogen by 100 mg F15 is 93.19% when the initial concentration of ammonia nitrogen is 100 mg/L and pH is 10. Throughout the reaction process, the 001TiO2/TiOF2 composite produces superoxide anion radical (·O2-) and hydroxyl radical (·OH) to oxidize NH3·H2O and generate N2 accompanied by a small amount of NO3- and NO2-.The article presents the results of research on a lightweight floor system (LFS) with a heat diffuser made of metal lamellae. It differs from traditional layered floors in the absence of a screed layer, which reduces thermal inertia and predisposes it to be used with renewable energy sources. As part of the research, a real model of the floor, consisting of nine ceramic tiles, was made. Polyurethane adhesive was used to connect the individual layers of this composite. The model was subjected to a thermal action. Selleck NVP-ADW742 It was constructed with the measuring equipment consisting of strain gauges. These were located at the boundaries of the composite layers and measured the material's deformation. The measurement results were verified by numerical calculations. For this purpose, a computational model was made using FEM (finite element method). Comparable results of deformations were obtained (the differences did not exceed 6.1%), which made it possible to perform numerical calculations of light floor materials stresses. Additionally, the displacement of the tested model was measured and numerically verified. The results of these verifications can be useful not only in the heated/cooled LFS with aluminium lamellae, but also in other building partitions inside and outside the building.The reduced form of graphene oxide (r-GO) represents a versatile precursor to obtain graphene derivatives. Graphene oxide (GO) consists of a layered material based on a carbon skeleton functionalized by different oxygen-containing groups, while r-GO is obtained by the almost complete removal of these oxygen-containing functional groups. The r-GO has mechanical, electrical, and optical properties quite similar to graphene, thus, it proves to be a convenient 2D material useful for many technological applications. Nowadays, the most important aspects to consider in producing r-GO are (i) the possibility of obtaining the highest reduction grade; (ii) the possibility of improving the dispersion stability of the resulting graphene using surfactants; (iii) the use of environmentally friendly and inexpensive reducing agents. Consequently, the availability of effective soft-chemistry approaches based on a green reducing agent for converting GO to r-GO are strongly needed. Among the green reductants, the most suitable is L-ascorbic acid (L-aa). Different studies have revealed that L-aa can achieve C/O ratio and conductivity values comparable to those obtained by hydrazine, a typical reducing agent. These aspects could promote an effective application strategy, and for this reason, this review summarizes and analyzes, in some detail, the up-to date literature on the reduction of GO by L-aa. The results are organized according to the two most important approaches, which are the reduction in liquid-phase, and the reduction in gel-phase. Reaction mechanisms and different experimental parameters affecting the processes were also compared.There is a serious wear problem in the middle plate of scraper conveyors, which causes the problems of high transportation cost, low efficiency, and a lot of material waste. Therefore, it is necessary to study the wear performance of middle plate materials. A new high-titanium low alloy wear-resistant steel (ZM4-13) and a typical material (NM400) for middle plates are studied in this paper. The findings show that the mass loss of ZM4-13 and NM400 rises with the increase of coal gangue percentage. They do not increase monotonically with the change of pH value, and there is a critical value the critical value of NM400 is between 6-8, and the critical value of ZM4-13 is between 7-9. When the pH value is less than the critical value, the mass loss decreases with the increase of pH value; when the pH value is greater than the critical value, the mass loss increases with the increase of pH value. Under the condition of high gangue and neutral solutions, ZM4-13 has better wear resistance. Its wear resistance can reach up to 1.09-2.10 times compared with NM400. The in-situ precipitated TiC particles are dispersed in ZM4-13. The high hardness of the TiC precipitation area in ZM4-13 hinders the plowing of hard particles and the plastic deformation of surface materials, so ZM4-13 is more wear-resistant than NM400, especially suitable for the harsh working conditions of coal mine production.Asphalt mixture is a typical viscoelastic material, and its road performance will change with the action of environment and load during actual service. This study conducted experimental research on the surface course asphalt mixture of three categories and six typical structures of RIOHTrack based on the Dynamic Mechanical Analysis method. Moreover, this study explored the performance evolution law of asphalt mixture under the coupling action of load and environment in the process of loading from 0 million to 54 million standard axle times. Results demonstrated that the phase transition characteristic temperature of the surface course materials of the three types of typical structures showed a trend of first increasing and then decreasing with the accumulation of load and environmental effects, indicating the presence of two stages of the dual coupling effect of environmental aging and load rolling on the asphalt mixture during service. In addition, the results suggested that the phase transition characteristic temperature, modulus, and phase angle of the surface layer materials have obvious material differences and structure dependencies.
Website: https://www.selleckchem.com/products/NVP-ADW742.html
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