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The different N fertilizers did not lead to differences in crop yields, i.e. 18.5 ± 2.9 Mg grain Ha-1 and 17.4 ± 1.2 Mg grain Ha-1 for digestate and urea respectively.Recent warming over the Tibetan Plateau (TP) is approximately twice the global-mean surface temperature increase and poses a threat to the healthy growth of forests. Although many studies have focused on whether recent climate warming has caused forest growth decline on the TP, it remains unclear how asymmetric warming, that is faster increasing nighttime temperature than daytime, impacts forest growth decline. We explored this question by using a ring-width index series from 1489 juniper trees (Juniperus prezwalskii and J. tibetica) at 50 sites on the TP. We calculated the percentage of trees with growth decline (PTD) to reconstruct historical forest growth decline and employed a piecewise structural equation meta-model (pSEM) and linear mixed model (LMM) to explore influencing factors. We found that the PTD has decreased since the late 19th century, with an abrupt decreasing trend since the 1980s. Results of the pSEM show that winter minimum temperature has a stronger indirect negative effect on the variation in PTD (β = -0.24, p less then 0.05) compared to that of the weak indirect positive effect of summer maximum temperature (β = 0.16, p less then 0.05). The results of LMM show that the variation in PTD is directly negatively (p less then 0.001) affected by both winter minimum temperature and summer total precipitation, but the former has a greater independent contribution than the latter (with 17.7% vs 2.5% of variances independently explained, respectively). These results suggest that increased winter minimum temperature substantially mitigates the growth decline in juniper forests on the TP. As the minimum temperature generally occurs at night, we conclude that the asymmetric increase in nighttime temperature has decreased the incidence of juniper forest growth decline on the TP under climate warming. This alleviating effect of nighttime warming is likely due to reduced low-temperature constraints and reduced damage to tree growth.Mussel farming has been proposed as a mechanism to mitigate eutrophication in coastal waters. However, localizing the intensive filtration of organic matter by mussels can cause a concomitant enrichment of organic matter in sediments below farms, which may influence biogeochemical processes and fates of nutrients in the system. In the context of mitigating eutrophication, it is important to quantify sedimentary changes induced at early life stages of mussel farms. Accordingly, this study investigated how a newly re-established mussel farm affected sedimentation rates, sediment characteristics, sediment-water solute fluxes and nitrate (NO3-) reduction rates (measured in situ) during the first year of production. Sedimentation rates were enhanced at the farm relative to a reference station, and both organic and inorganic carbon accumulated in the sediment with time. Increased organic matter input likely drove the slightly elevated sedimentary effluxes of ammonium (NH4+) and dissolved inorganic phosphorus (DIP) ting the environmental impact of mussel aquaculture.This study explores the efficiency and kinetics of the photoactivated periodate process for the degradation of 2,4-dichlorophenol (2,4-DCP) in water. The obtained results show that the degradation rate was considerably higher for UV/IO4- compared to UV irradiation alone. Pseudo first-order reaction rate kinetics were obtained for all process conditions. The pH did not have a significant impact on the decomposition of 2,4-DCP using photoactivated periodate. Therefore, the applied method can be used to treat (waste)water at various pH. By raising the initial concentration of periodate to 5 mM, the degradation rate increased, while it decreased again at a concentration of 8 mM. As the 2,4-DCP concentration increased, the removal rate decreased. The extent of degradation was observed to be proportional with the UV intensity. A mechanistic study revealed that iodine radicals dominated the degradation of 2,4-DCP by photoactivated periodate, whereas OH and O(3P) only played a minor role. At pH 5.0, all chlorine atoms in 2,4-DCP were released as chloride ions in the UV/IO4- process, hence reaching a total dechlorination. Finally, the presence of inorganic salts, even at high levels, did not significantly impact the degradation. According to the results achieved in this study, the UV/IO4- system can be considered as a valuable alternative to treat effluents containing chlorinated organic compounds such as pulp and paper mill effluents and brine (waste)water.Naturally-ignited wildfires are increasing in frequency and severity in northern regions, contributing to rapid permafrost thaw-induced landscape change driven by climate warming. Low-severity wildfires typically result in minor organic matter loss. The impacts of such fires on the hydrological and geochemical dynamics of peat plateau-wetland complexes have not been examined. In 2014, a low-severity wildfire, with minimal ground surface damage, burned approximately one-half of a 5 ha permafrost plateau in the wetland-dominated landscape of the Scotty Creek watershed, Northwest Territories, Canada, in the discontinuous permafrost zone. In March 2016, hydrometeorological and permafrost conditions on the burned and unaffected plateaus were monitored including snowpack characteristics and surface energy dynamics. Pore water samples were collected from the saturated layer as thaw progressed throughout the growing season on the burned and unaffected plateaus. Repeated probing of the frost table depth was coupled wiildfires have the potential to trigger a series of complex, inter-related hydrological, thermal and biogeochemical processes and feedbacks.Marine aerosols are believed to have an organic surface coating on which fatty acids act as an important component due to their high surface activity. In addition, various kinds of enzyme species are abundantly found in seawater, some of which have been identified to exist in marine aerosols. Herein, from the perspective of marine aerosol interface simulation, we investigate the effect of Burkholderia cepacia lipase on the surface properties of stearic acid (SA) monolayer at the air-water interface by using surface-sensitive techniques of Langmuir trough and Infrared reflection-absorption spectroscopy (IRRAS). Our findings indicate that the stearic acid film undergoes a significant expansion, especially when the lipase concentration is 500 nM, because of the incorporation of lipase as observed from the surface pressure-area (π-A) isotherms. IRRAS spectra also show reduced intensities and ordering in the methylene stretching vibration region of stearic acid as a result of low surface density and disordered packing as the enzyme concentration increases. In particular, when the concentration of lipase is 500 nM, the lowest Ias/Is values are shown on both pure water subphase and artificial seawater subphase, indicating more gauche conformations for SA. Furthermore, SA films with lipase incorporation were also studied at three different pH of subphase environment, considering the decrease of pH caused by the reaction with acidic gases during the aerosol aging process. The results reflect a more pronounced expansion of SA monolayer in acidic environment at pH 2.5, suggesting that hydrophobic interaction plays an important role in the disorder of the SA monolayer. In view of the coexistence of fatty acids and enzymes in the marine environment, this study provides a further understanding of the surface organization and behavior of organic-coated marine aerosols and deepen the knowledge of lipid-enzyme interfacial interactions occurring in the atmosphere.Habitat degradation is expected to alter community structure and consequently, ecosystem functions including the maintenance of biodiversity. Understanding the underlying abiotic and biotic assembly mechanisms controlling temporal and spatial community structure and patterns is a central issue in biodiversity conservation. In this study, using monthly time series of fish abundance data collected over a three-year period, we compared the temporal community dynamics in natural habitats and poplar plantations in one of the largest river-lake floodplain ecosystems in China, the Dongting Lake. We found a prevailing strong positive species covariance, i.e. species abundance changes in the same way, in all communities that was significantly negatively impacted by higher water nutrient levels. BMS-777607 In contrast to species covariance, community stability, which was measured by the average of aggregated abundance divided by temporal standard deviation, was significantly higher in poplar plantations than in natural habitats. The positive species covariance, which was consistent for both wet and dry years and among habitat types, had significantly negative effects on community stability. Furthermore, our results demonstrated that the ecological stochasticity (i.e. community assembly processes generating diversity patterns that are indistinguishable from random chance) was significantly higher in natural sites than in poplar plantations, suggesting that deterministic processes might control the community composition (richness and abundance) at the modified habitat through reducing species synchrony and positive species covariance observed in the natural habitats, leading to significantly lower temporal β-diversity. When combined, our results suggest that habitat modification created environmental conditions for the development of stable fish community in the highly dynamic floodplains, leading to niche-based community with lower temporal β-diversity.Low-frequency high-magnitude storms can flush disproportionate amounts of terrigenous dissolved organic carbon (DOC) and particulate organic carbon (POC) into rivers during a short period. However, previous studies focused on the impacts of storms on organic carbon transport in headwater streams that are minimally influenced by human activities and are far from lakes. To better estimate the lake carbon budget and manage lake water environments, we need to understand the transport of storm-induced organic carbon into lakes by eutrophic rivers. Based on daily and hourly time-series monitoring data, this paper systematically studied the influences of storm precipitation on DOC and POC transport in the eutrophic Tiaoxi River entering Lake Taihu, the 3rd largest freshwater lake in China. The results showed that seven storms transported 59% of the annual total organic carbon into Lake Taihu in 2019, and all storms resulted in transport peaks. During the storm period on August 9-16, 2019, DOC was negatively related to the water level (r = -0.44, p less then 0.05), but POC responded positively (r = 0.52, p less then 0.05); allochthonous organic carbon contents were elevated, but the autochthonous components were diluted. Moreover, the storm-induced input of riverine organic carbon influenced the lake water environment across a large region, and the impacts lasted more than 10 days. These findings have important implications for accurately estimating riverine organic carbon fluxes into lakes and making better-informed decisions about when to pump drinking water from lakes.
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