Notes

Useful modifications in cortical control of presentation within glioma-infiltrated cortex.
The implementation of two-child policy has changed the mode of obstetrics and has presented great challenges. With hierarchical management of high-risk patients and control of the cesarean section rate, we can ensure the safety of pregnant women and newborns.
The implementation of two-child policy has changed the mode of obstetrics and has presented great challenges. With hierarchical management of high-risk patients and control of the cesarean section rate, we can ensure the safety of pregnant women and newborns.COVID-19 suddenly struck Wuhan at the end of 2019 and soon spread to the whole country and the rest of world in 2020. To mitigate the pandemic, China authority has taken unprecedentedly strict measures across the country. That provides a precious window to study how the air quality response to quick decline of anthropogenic emissions in terms of national scale, which would be critical basis to make atmospheric governance policies in the future. In this work, we utilized observations from both remote sensing and in-situ measurements to investigate impacts of COVID-19 lockdown on different air pollutions in different regions of China. It is witnessed that the PM2.5 concentrations exhibited distinct trends in different regions, despite of plunges of NO2 concentrations over the whole country. The steady HCHO concentration in urban area provides sufficient fuels for generations of tropospheric O3, leading to high concentrations of O3, especially when there is not enough NO to consume O3 via the titration effect. Moreover, the SO2 concentration kept steady at a low level regardless of cities. As a conclusion, the COVID-19 lockdown indeed helped reduce NO2 concentration. However, the atmospheric quality in urban areas of China has not improved overall due to lockdown measures. It underscores the significance of comprehensive control of atmospheric pollutants in cleaning air. Reducing VOCs (volatile organic compounds) concentrations in urban areas would be a critical mission for better air quality in the future.Atmospheric concentration of legacy (LFRs) and emerging flame retardants (EFRs) including 8 polybrominated diphenyl ethers (PBDEs), 6 novel brominated flame retardants (NBFRs), 2 dechlorane plus isomers (DP), and 8 chlorinated organophosphate flame retardants (OPFRs) were consecutively measured in eight major cities across Pakistan. A total of 96 samples (48 PM2.5 & 48 PUFs) were analyzed and the concentrations of ∑8PBDEs (gaseous+particulate) ranged between 40.8 and 288 pg/m3 with an average value of 172 pg/m3. ∑6NBFRs ranged between 12.0 and 35.0 pg/m3 with an average value of 22.5 pg/m3 while ∑8OPFRs ranged between 12,900-40,800 pg/m3 with an average of 24,700 pg/m3. Among the studied sites, Faisalabad city exhibited the higher concentrations of FRs among all cities which might be a consequence of textile mills and garment manufacturing industries. While analyzing the diurnal patterns, OPFRs depicted higher concentrations during night-time. The estimated risks of all groups of FRs from inhalation of ambient air were negligible for all the cities, according to USEPA guidelines. Nonetheless, our study is the first to report gaseous and particulate concentrations of FRs in air on a diurnal basis across major cities in Pakistan, offering insights into the atmospheric fate of these substances in urban areas in a sub-tropical region.Microplastics (MPs) in aquatic environment usually carry hazardous matters, including toxic heavy metals. Quantification of heavy metals in MPs is crucial for the comprehensive understanding of their ecotoxicology in field environment. However, conventional methods for heavy metal determination either are applicable only to bulk/collective samples or require strict operation environment. Here we demonstrated that laser induced breakdown spectroscopy (LIBS) is a robust tool for the characterization of heavy metals in single MPs. Single-particle LIBS selects individual MPs with specific sizes (down to tens of microns), shapes, and morphologies and analyzes simultaneously multiple elements in milliseconds without sample pretreatment. In addition to the elaborate optical design, we also used stretched thin polyethylene film as a substrate, which significantly suppress the matrix interference to the particles' spectra. AZD5069 The single particle LIBS was demonstrated to be a quantitative analytical method, and was applied to heavy metal analysis of the MPs collected in the seawaters of the Beibu Gulf of China. Positive correlation between the spectral intensities and the local marine pollutions as well as significant heterogeneity in the elemental compositions were observed. The results demonstrate that single-particle LIBS is a promising method for MPs characterization and is suitable for studying pollutant transportation by using MPs as vectors.Detection of metal nanoparticles (NPs) in the environment is an analytical challenge of interest due to increasing use of nanomaterials in consumer and industrial products. Detecting NPs associated with human activities is affected by both the magnitude and variation in background concentrations of natural NPs. In this work, we investigated the potential release of titanium dioxide (TiO2) NPs from sunscreen in three recreational rivers, with a time-intensive sampling regime on one river, in order to determine the range and variability of natural, background titania (Ti). Conventional ICP analysis for total metal concentrations, single particle ICP-MS for NP concentrations, and electron microscopy aided in assessing mineralogical morphology and composition. Oxybenzone, a widely-used organic sunscreen, was measured and used as a surrogate for the intensity of recreational activity in the water. Statistically significant increases in Ti concentrations were observed in Clear Creek, CO during one recreation period, but the significance of other instances of recreation-associated Ti increases was unclear, in part due to storm impacts on the natural suspended sediment load of the stream. A comparison of three recreational rivers showed increases in both Ti mass concentrations and NP sizes occur during recreation in both Clear Creek, CO and the Salt River, AZ, but no detectable changes in the Truckee River, NV. However, size distributions were variable in background samples, which make the significance of differences observed during recreation unclear. These results underline that the release of engineered nanoparticles to a natural system cannot be detected without a well-defined background, including measures of its variability during the study period.High hydraulic pressure in air-cathode microbial fuel cells (MFCs) can lead to severe cathodic water leakage and power reduction, thereby hindering the practical applications of MFCs. In this study, an alternative air cathode without a diffusion layer was developed using a cross-linked hydrogel, oxidized konjac glucomannan/2-hydroxypropytrimethyl ammonium chloride chitosan (OKH), for ion bridging. The cathode was placed horizontally to avoid hydraulic pressure on its surface. Ion transportation was sustained with a minimal OKH hydrogel loading of 10 mg/cm2. A maximum power density of 1.0 ± 0.04 W/m2 was achieved, which was only slightly lower than the 1.28 ± 0.02 W/m2 of common air cathodes. Moreover, the cost of the OKH hydrogel is only $0.12/m2, which can reduce ~85% of the cathode cost without using the advanced polyvinylidene fluoride diffusion layer. Therefore, the development of this new diffusion-layer-free air cathode using conductive ionic hydrogel provides a low-cost strategy for stable MFC operation, thereby demonstrating great potential for practical applications of MFC technology.The trends of enzyme activities and litter chemistry after abandonment of arable soil and succession of natural vegetation were studied in a deciduous forest zone (Moscow region, Russia). The Luvic Phaeozem chronosequence included an arable field, 3 fields with increasing abandonment periods (7, 11, 35 years), and the soil under natural forest as a reference site (never used for cropland). The activities of four hydrolytic enzymes (β-glucosidase, cellobiohydrolase, β-galactosidase, chitinase) in the topsoil (0-5 cm) were compared with chemical functional groups of plant litter identified by 13C NMR spectra. The total enzyme activity increased 5-fold during 35 years of postagricultural restoration of arable soil. The share of C-cycle enzymes with "narrower" substrate specificity (cellobiohydrolase and chitinase) increased during 35 years from 19% to 42% of the total enzyme pool. We explain this gain by the increase in the diversity and recalcitrance of organic compounds in the plant litter from cropland to natural forest. Aromaticity index of plant litter built up remarkably from 0.11 in the young abandoned land to 0.14-0.15 in the 35-year abandoned land and the reference site. The share of enzymes with a "narrower" substrate specificity correlated closely with the portions of aryl C, O-aryl C, and carbonyl C functional groups in plant litter. Accordingly, the succession of natural vegetation on abandoned cropland leads to strong diversification of the plant litter composition and a corresponding production of soil enzymes with "narrower" substrate specificity.The activation of peroxymonosulfate (PMS) for organic contaminant oxidation usually relies on the formation of reactive oxygen species (ROSs). However, the ubiquitous anions and natural organic matter can easily scavenge ROSs and/or PMS, resulting in lower efficiencies and/or the formation of toxic byproducts. Relying on the unique long-distance electron transfer property, the recently developed Galvanic Oxidation Process (GOP) successfully achieved bisphenol A (BPA) degradation when BPA and PMS were physically separated in two reactors. In this study, we systematically investigated the performance of GOP at different PMS or BPA concentrations, pH, and ionic strength (IS) in both PMS and BPA solutions. The kinetic modeling employing the Langmuir-Hinshelwood model at different BPA concentrations suggested that although BPA and PMS were physically separated, the oxidation of the adsorbed BPA and reduction of the adsorbed PMS still followed a similar mechanism to that in traditional heterogeneous catalytic processes. The anions in the target water showed little impact on BPA degradation; higher IS enhanced the solution conductivity but inhibited BPA and electrode interactions, resulting in increased and then decrease BPA degradation rate. The electrodes presented high stability with a rate increase of 12% after 13 times of uses, and their hydration significantly facilitated BPA degradation but reduced the current by decreasing the potential difference between the anode and cathode. The graphite sheet itself without catalyst coating was also capable of shuttling electrons, while the use of a graphite fiber anode increased the BPA degradation by near 100% because of the larger surface area. The developed continuous stirred-tank reactor coupled with GOP (CSTR-GOP) achieved stable BPA degradation in less than 35 min and its scaling up is promising for future applications.Hydrogen sulfide (H2S) represents one of the main pollutants originating from both geologic phenomena such as volcanoes, geysers, fumaroles and hot springs, and geothermal plants that produce heat and electricity. Many increasing data suggest that H2S retains a variety of biological properties, and modulates many pathways related to cardiovascular pathophysiology although its role as beneficial/adverse determinant on cardiovascular disease (CVD) is not clearly established. In this review, the current knowledge on the association between H2S exposure and risk of CVD in geothermal areas has been examined. The few epidemiological studies carried out in geothermal areas suggest, in some cases, a protective role of H2S towards CVD, while in others a positive association between exposure to H2S and increased incidence of CVD. Most of the studies have an ecological design that does not allow to produce evidence to support a causal relationship and also often lack for an adequate adjustment for individual CVD risk factors.
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