Notes

Rich D. Lewontin (1929-2021).
The intracycle strain thickening and intracycle strain stiffening of high-content LMPP blends were comparatively dominant at medium strain amplitudes.The accelerated ageing of wood in terms of heating or iron rusting has a potential effect on the physio-mechanical, chemical and biological properties of wood. The effects of accelerated ageing on the mechanical, physical and fungal activity properties of some wood materials (Schinus terebinthifolius, Erythrina humeana, Tectona grandis, Pinus rigida and Juglans nigra) were studied after several cycles of heating and iron rusting. BTK animal study The fungal activity was assayed against the growth of Aspergillus terreus, Aspergillus niger, Fusarium culmorum and Stemphylium solani. In addition, the mechanical and optical properties of paper sheets produced from those wood pulps by means of Kraft cooking were evaluated. The mechanical and chemical properties of the studied wood species were affected significantly (p less then 0.05) by the accelerated ageing, compared to control woods. With Fourier transform infrared (FTIR) spectroscopy, we detected an increase in the intensity of the spectra of the functional groups of cellulont effects on the mechanical and chemical properties of the studied wood species and affected the properties of the produced pulp paper.The conditioning of the root canal wall during chemo-mechanical root canal treatment differentially affects the adhesion of root canal sealers. This investigation evaluated the impact of sodium hypochlorite (NaOCl) concentration as used in a root canal irrigation concept called continuous chelation, with 1-hydroxyethylidene-1,1-diphosphonic acid (HEDP) contained in the NaOCl solution that is applied. Fourier-transform infrared spectra of the dentinal wall were gathered. The consequential effects on push-out bond strength of an epoxy resin (AH Plus) versus a hydraulic CaSi sealer (BioRoot RCS) were assessed. Single-rooted extracted human teeth were used and irrigated with pure NaOCl at a concentration of 0% (physiological saline), 2.5%, or 5.25%. Dual Rinse HEDP (9%) was added to the solutions, or not added for further control. Pure NaOCl solutions caused a decrease in the amide III phosphate ratios, which was counter-acted by the addition of HEDP. It was observed that the adhesion of the epoxy resin sealer under investigation was negatively affected by this NaOCl deproteinization of the canal wall in a dose-dependent manner, while the opposite was observed with the CaSi sealer. HEDP when used in conjunction with NaOCl was beneficial for the adhesion of both sealers.Suction cups of cephalopods show a preeminent performance when absorbing irregular or flat objects. In this paper, an octopi-inspired suction cup, driven by hydraulically coupled dielectric elastomer actuators (HCDEAs), is proposed, which is considered to be controlled easily and have compact structure. To investigate the performance of suction cups, experiments have been conducted to clarify the effect of the pre-stretch ratio and chamber angle on suction forces. It could be seen that both factors have a complicated influence on suction forces, and the best performance obtained was a reasonable combination of the pre-stretch ratio and chamber angle. Here, we achieved a maximum suction force of 175 mN with λp = 1.2, α = 23° under a DC voltage of 3500 V. To enhance the capacity and adaptation of the suction cup, flat objects of various types of materials were introduced as targets. Experimental results displayed that for tested materials, including a dry/wet acrylic plate, CD, ceramic wafer, and aluminum plate, the suction cup showed outstanding performance of absorbing and lifting the target without any damage or scratch to them. Our research may serve as a guide to the optimal design and provide insights into the performance of the HCDEAs-actuated suction cup.Spoolable reinforced plastic line pipes (RTPs), exhibiting a series of advantages such as good flexibility, few joints, long single length, light weight, easy installation, etc., have been widely used in the onshore oil and gas industry such as oil and gas gathering and transportation, high pressure alcohol injection, water injection, sewage treatment, and other fields. However, due to the lack of clear standard specificationof the limit operating properties for RTPs, three typical failure modes, i.e., tensile, flexure, and torsion, frequently occur in terrain changes, construction operation, and subsequent application, which seriously affects the promotion and use of RTPs. In this paper, the stress distribution of a non-bonded polyester fiber reinforced high-density polyethylene (HDPE) pipe (DN 150, PN 2.5 MPa) was systematically studied by the finite element method (FEM), and then the limit operating values under the axial tensile, coiled bending, and torsion load were determined. The corresponding experiments were conducted to validate the reliability and accuracy of the FEM model. The FEM results showed that the critical strain for axial tensile was 3%, the minimum respooling bend radius was 1016.286 mm, and the limit torsion angle of this RTP was 58.77°, which are very close to the experimental results. These limit values will be useful to establish normative guidelines for field construction and failure prevention of onshore RTP.We processed a series of shape memory Eucommia rubber (ER) composites with both carbon-carbon and ionic cross-linking networks via a chemical cross-linking method. The influence of the carbon-carbon cross-linking and ion cross-linking degree of ER composites on curing, mechanical, thermal, and shape memory properties were studied by DSC, DMA, and other analytical techniques. Dicumyl peroxide (DCP) and zinc dimethacrylate (ZDMA) played a key role in preparing ER composites with a double cross-linking structure, where DCP initiated polymerization of ZDMA, and grafted ZDMA onto polymer molecular chains and cross-linked rubber molecular chains. Meanwhile, ZDMA combined with rubber macromolecules to build ionic cross-linking bonds in composites under the action of DCP and reinforced the ER composites. The result showed that the coexistence of these two cross-linking networks provide a sufficient restoring force for deformation of shape memory composites. The addition of ZDMA not only improved the mechanical properties of materials, but also significantly enhanced shape memory performance of composites. In particular, Eucommia rubber composites exhibited outstanding mechanical properties and shape memory performance when DCP content was 0.2 phr.Bioactive polypropylene (PP) films with active agents) presence for food packaging application have been prepared and characterized. The novel modified PP films were obtained via PP/additives systems regranulation and cast extrusion. The influence of two types of plasticizers (natural agents as well as commercial synthetic product) and bioactive additives on final features, e.g., mechanical properties, was evaluated. Moreover, the biocidal activity of the films was determined. Due to their functional properties, they are developed as additives to packaging plastic materials such as polyolefins. The study results presented in our work may indirectly contribute to environmental protection by reducing food waste. The aim of the work was to obtain innovative, functional packaging materials with an ability to prolong the shelf life of food products. The best antimicrobial properties were observed for the sample based on 5 wt.% oregano oil (OO) and 5 wt.% cedar oil (OC) in PP matrix. A microbial test revealed that the system causes total reduction in the following microorganisms B. subtilis, E. coli, S. aureus, P. putida, C. albicans, A. alternata, F. oxysporum.A simple and efficient process for fabricating customized aspheric lenses is reported, in which a stereolithographic 3D printer combined with the meniscus equilibrium post-curing technique is employed. Two kinds of UV-curable resins, DentaClear and HEMA, were used for printing aspheric lenses in our experiments. The printed DentaClear lens featured low surface profile deviation of ~74 μm and showed satisfactory optical imaging resolution of 50.80 lp/mm, i.e., 4.92 μm. The surface roughness of the printed lens with DentaClear was measured to be around 2 nm with AFM. The surface roughness was improved as a result of post-curing, which reduced the ripples on printed lens surfaces. In contrast, the printed HEMA lens exhibited a significant stair-stepping effect with a large surface profile deviation of ~150 μm. The ripples were somewhat apparent even if the printed HEMA lens surface was smoothed by means of post-curing. No sharp image can be obtained with the HEMA lens in the resolution testing. The composition of HEMA resin may be the reason for the relatively poor surface quality and optical properties.Losartan potassium (LP) is an angiotensin receptor blocker used to treat hypertension. At higher pH, it shows poor aqueous solubility, which leads to poor bioavailability and lowers its therapeutic effectiveness. The main aim of this research was to develop a direct compressed effervescent floating matrix tablet (EFMT) of LP using hydroxyl propyl methylcellulose 90SH 15,000 (HPMC-90SH 15,000), karaya gum (KG), and an effervescent agent, such as sodium bicarbonate (SB). Therefore, an EFMT has been developed to prolong the stomach residence time (GRT) of a drug to several hours and improve its bioavailability in the stomach region. The blended powder was evaluated for pre-compression characteristics, followed by post-compression characteristics, in vitro floating, water uptake studies, and in vitro studies. The optimized formulation of EFMT was investigated for in vivo buoyancy by X-ray imaging and pharmacokinetic studies in Albino rabbits. The results revealed that the parameters of pre- and post-compression were within the USP limits. All tablets showed good floating capabilities (short floating lag time 24 h), good swelling characteristics, and controlled release for over 24 h. The Fourier-transform infrared (FTIR) and differential scanning calorimetry (DSC) spectra showed drug-polymer compatibility. The optimized formulation F3 (HPMC-90SH 15,000-KG) exhibited non-Fickian diffusion and showed 100% drug release at the end of 24 h. In addition, with the optimized formulation F3, we observed that the EFMT floated continuously in the rabbit's stomach area; thus, the GRT could be extended to more than 12 h. The pharmacokinetic profiling in Albino rabbits revealed that the relative bioavailability of the optimized LP-EFMT was enhanced compared to an oral solution of LP. We conclude that this a potential method for improving the oral bioavailability of LP to treat hypertension effectively.The difference in compatibility at the molecular level can lead to a change of microphase separation structure of thermoplastic polyurethanes blend systems, which will improve their thermal and mechanical properties. In this study, TDI-polyester based TPU was blended with MDI-polyether-based TPU and MDI-polyester based TPU, with different ratios. In the blend system, the obvious reduction of the melting temperature of the high-temperature TDI-polyester based TPU component indicates its hard segments can be mutually integrated with the other component. For TDI-polyester based TPU/MDI-polyether based TPU blends, their similar hard segment ratio and similar chemical structure of the soft segment give the molecular chains of the two components better compatibility. The aggregation structure of the two kinds of chains can rearrange at the molecular level which makes the hard domains mutually integrate to form a new phase separation structure with larger phase region distance. As a result, the yield strength of this blend increased by almost 143% when the elongation at break was only reduced by 12%.
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