Notes

Within the spot light: understanding the position with the Main Health care Officer in the crisis.
Shape-memory polymer composite (SMPC) blends with thermo-responsive shape memorizing capability have received increasing interest and have been a grooming research area due to their various potential applications. In this work, we report three thermo-responsive SMPCs derived from poly(ε-caprolactone) (PCL) and the polystyrene-block-polybutadiene-block-polystyrene-tri-block copolymer (SBS) encapsulated with CuO, Fe2O3, and CuFe2O4, namely, SMPC-CuO, SMPC-Fe 2 O 3 , and SMPC-CuFe 2 O 4 , respectively. We have also synthesized the neat shape-memory polymer matrix SMP in the context of the effect of the metal oxide encapsulates on the shape-memory property. Neat SBS rubber and PCL are used as the polymer-elastomer blend matrix to form SMP. The objective of this study is to understand the effect of these three metal oxide nanofillers encapsulated within the SMP matrix and their thermal, mechanical, and shape-memory properties. Morphological, thermal, mechanical, and shape-memory properties of the prepared SMPCs are completely characterized. It is revealed that the addition of nano-metallic-oxide fillers into the polymeric matrix significantly improved the overall properties of SMPCs. The tensile test confirmed that SMPC-CuFe 2 O 4 possesses a high tensile modulus and is found to be very rigid when compared to other SMPCs. The shape fixing property is found in the increasing order as follows SMPC-CuO > SMPC-Fe 2 O 3 > SMP > SMPC-CuFe 2 O 4 . The better thermal, mechanical, and shape-memory performances were shown by the SMPC-Fe 2 O 3 composite, and thus, it can be considered as the better shape-memory polymer nanocomposite among all others. An optimum storage modulus was attained by SMPC-Fe 2 O 3 among the SMPCs. More interestingly, we have developed a microvalve actuator system using SMPC-Fe 2 O 3 , which could be useful for promising microsystem applications.A flame-retardant composite was synthesized through a simple graphene oxide functionalization route with hexachlorocyclotriphosphazene and p-phenylenediamine. Flame experiments conducted on the synthesized composite proved its importance as tremendously resistant to fire. The thermogravimetric analysis (TGA) shows clearly that the functionalized graphene oxide (FGO) exhibits an enhanced thermal stability and better temperature resistance. A thermoset epoxy resin was prepared by incorporating different percentages (2, 5, and 10%) of FGO to diglycidyl ether of bisphenol A (DGEBA). The flame-retardant properties, thermal degradation behavior, and combustion of the DGEBA thermosets cured by m-phenylenediamine were investigated using a Bunsen burner flame approaching the flame temperature of a fire and TGA. The chemical structure of FGO was characterized with spectroscopic and imaging techniques including Fourier transform infrared spectroscopy, Raman spectroscopy, X-ray diffraction, TGA, scanning electron microscopy, energy-dispersive X-ray spectroscopy elemental mapping, and X-ray photoelectron spectroscopy. Due to its high flame-retardant capabilities, such a composite could promise potential applications in the manufacture of inflammable materials for different uses.This work dealt with a potential and effective method to reuse modified alginate beads after the removal of Cu(II) ions for efficient adsorption of tetracycline (TC) from aqueous solutions. The modified alginate beads were fabricated by a polyacrylamide (PAM) network interpenetrated in alginate-Ca2+ network (PAM/CA) decorated with polyethylene glycol as a pore-forming agent. The porous PAM/CA was characterized using scanning electron microscopy, Brunauer-Emmett-Teller, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy analysis. The adsorption kinetics, isotherms, adsorption stability, and reusability studies of the adsorbent toward Cu(II) ions were scrutinized. The column performance of porous PAM/CA was tested with Cu(II)-containing electroplating wastewater. After Cu(II) adsorption, the Cu(II)-adsorbed PAM/CA (PAM/CA@Cu) was applied to remove TC from aqueous solutions without any regeneration process. The effects of pH, initial TC concentration, ionic strength, and coexisting ions on the adsorption were also discussed in detail. Compared with many reported adsorbents, the PAM/CA@Cu exhibited an excellent adsorption performance toward TC with a maximum adsorption capacity of 356.57 mg/g predicted by the Langmuir model at pH 5.0 and 30 °C with the absence of coexisting ions. The possible adsorption mechanism of TC onto the PAM/CA@Cu was revealed.Drilling fluid and filtrates invasion often alter the near-wellbore flow properties during overbalanced drilling. The utilization of polymeric gels to prevent drilling fluid loss reduces the risk of formation damage caused by this alteration. In this study, the internal and external filter cake evolution by polyacrylamide (PAM) cross-linked with polyethylenimine (PEI) was investigated. The analysis conducted in this study showed that the cross-linked polymer activates and forms a mature gel inside the formation's pores. Gel also formed a dense uniform structure on the rock's surface, preventing further fluid loss. A high sealing pressure of up to 1000 psi was achieved, allowing drilling to continue without the need for additional casing string to prevent lost circulation. Moreover, the PAM/PEI formula showed less invasion of filtrate and evolution of a thin shallow internal filter cake that penetrated less than half of the filter disk thickness. In comparison to the full invasion and particle depositions that occurred with the water-based mud (WBM), the PAM/PEI formula is expected to reduce the impact of lost circulation materials (LCMs) on formation damage.In the present paper, the formation and development of cavitation inside the nozzle of an atomizer with different geometrical characteristics have been studied numerically. Different shapes of inlet nozzles and different nozzle-length-to-diameter ratios have been investigated. The developed model has been built as a three-dimensional (3D) one, where the turbulence is modeled considering large eddy simulation. The obtained computational results showed good agreement with the reported experimental results. It has been found that the occurrence of cavitation depends on the amount of energy needed to overcome the viscosity and friction between the liquid layers. Remodelin The mass flowing through the nozzle decreases with increasing cavitation. The intensity of cavitation depends on the nozzle entrance shape. Sharp edges cause cavitation to occur early in the nozzle, followed by an inclined shape, and then the curved entrance. The dissipative energy in the cavitation and bubble collapse result in an increase in the turbulent kinetic energy of the issuing liquid.
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