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Significant along with Long lasting Anorexia Therapy and Futility: A Time for each and every Objective?
Diamond-like carbon (DLC) and titanium-doped DLC coatings were prepared by hybrid PECVD/direct current magnetron sputtering (DCMS). In this study, we show that the operating conditions of titanium-doped DLC coatings used for implants in surgical devices significantly modify their surface properties and consequently their interaction with cells. The coatings showed uniform distribution on the substrate and their biocompatibility was tested by way of rat calvaria osteoblasts. Doping DLC with Ti changed the roughness and wettability of the film interface. The autoclaving of the samples led to the surface oxidation and the formation of TiO2 on the top-most layers of Ti-doped DLC. This was quantitatively assessed by X-ray photoelectron spectroscopy (XPS) and revealed the presence of Ti3+ and Ti4+ species in redox reactions during their interactions with cells. By XPS analysis, the oxidative carbonaceous species C=O and O=C-C were detected during the bacterial inactivation. Reactive oxygen species (ROS) were identified on the sputtered samples and the ⦁OH radical was identified as the most important oxidative radical intermediate leading to bacterial disinfection. The position of the intra-gap of the oxidized C species is suggested within the TiO2 bandgap.Permeable pavements, as additive structures that have a good capability for runoff and pollutant reduction, are extensively used for sustainable urban drainage techniques. However, the exact mechanisms of runoff retention and pollutant reduction of a permeable pavement system remain unclear and so, it has become an ongoing issue and motivation for hydrologists and design and structural engineers. find more In this research paper, a suite of four scale-based runoff plots representing permeable pavements were designed with different permeable surface types and gravel layer thickness treatments, and coupled with simulated rainfall experiments to analyze the impacts of structural factors of permeable pavements on runoff retentions and pollution reduction. The present results showed that the average time to runoff for permeable pavements under low-intensity rainfall scenarios was approximately 78.5 min, while this was shortened to only 51.5 min under high-intensity rainfall scenarios. In terms of the average runoff retentioproperties of permeable pavements and help design engineers in optimizing their design of permeable pavements for better runoff retention and pollution removal.Rivers are critical ecosystems for protecting and harboring high biodiversity. Tropical rivers particularly are unique for facing extreme climatic events under the current accelerated disruption from human activities. The Bobos-Nautla river basin is exposed to climatic events and disturbances from anthropogenic impacts that stress aquatic organisms. We assessed the health condition of this river system using a non-conventional biomonitor, Corydalus sp., with a set of early-warning biomarkers including lipid peroxidation levels (LPO) and antioxidant activity, superoxide dismutase (SOD), catalase (CAT), glutathione peroxidase (GPx), and the neurotransmitter acetylcholinesterase (AChE) considering their spatial and temporal variations. Biomarkers and water quality parameters were analyzed, and the integrated biomarker response (IBR) was assessed as a stress index. Biomarkers showed no significant spatial differences; however, a high-stress period during the rainy season was detected, evidenced by the highest LPO levels; this period is related to the leaching of allochthonous materials from agricultural and urban zones. The peak IBR value during the rainy season confirmed the seasonality of biomarkers. A slight increase in IBR was recorded in lowlands, seemingly associated with agricultural land and human settlements. A principal component analysis showed nutrient enrichment during the rainy season and depletion during the cold-dry season, together with a peak activity of antioxidant enzymes. These results highlight the importance of climatic events such as the rainy season on the health condition of Corydalus sp., which is highly sensitive to the complex mixtures of pollutants that enter the waterbody during extreme climatic events, promoting oxidative stress. Our results also showed the ability of Corydalus sp. to recover and return to a basal level.The main goal of this work was to produce an easily recoverable waste-based magnetic activated carbon (MAC) for an efficient removal of the antiepileptic pharmaceutical carbamazepine (CBZ) from wastewater. For this purpose, the synthesis procedure was optimized and a material (MAC4) providing immediate recuperation from solution, remarkable adsorptive performance and relevant properties (specific surface area of 551 m2 g-1 and saturation magnetization of 39.84 emu g-1) was selected for further CBZ kinetic and equilibrium adsorption studies. MAC4 presented fast CBZ adsorption rates and short equilibrium times ( less then 30-45 min) in both ultrapure water and wastewater. Equilibrium studies showed that MAC4 attained maximum adsorption capacities (qm) of 68 ± 4 mg g-1 in ultrapure water and 60 ± 3 mg g-1 in wastewater, suggesting no significant interference of the aqueous matrix in the adsorption process. Overall, this work provides evidence of potential application of a waste-based MAC in the tertiary treatment of wastewaters. Graphical abstract.Efficient and selective removal of antibiotics from wastewater is quite important but challenging. In this work, the nitrogen-doped mesoporous carbon nanospheres (NMCN) with different pore size (from 2.67 to 4.62 nm) were successfully prepared by changing the hydrothermal condition, and their removal performance on tylosin was evaluated. The adsorption experimental data were fitted well with the pseudo-second-order kinetic model. Besides, Langmuir isotherm model could better describe the adsorption process. Notably, the NMCN with medium pore size (3.36 nm) exhibited the highest adsorption capacity (1333 mg g-1), which was 24% and 14% higher than that of NMCNs with smaller and larger pore size, respectively. In order to study the adsorption mechanism, the mesoporous carbon nanospheres without N-doped was prepared, and the comparison of nitrogen adsorption-desorption isotherms was conducted. The result proved that in addition to the modified surface property, large specific surface area, and high pore volume, the pore size could precisely influence the adsorption performance of the proposed adsorbent.
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