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The quantitative relationship between three-dimensional (3D) fluorescence spectra characteristics of DOM and water quality indicators or NPS pollution was established, which realized the convenient quantitative evaluation of pollution load and pollution source contribution using DOM fluorescence spectra characteristics. The strength of the correlation between DOM fluorescence spectra characteristics and water quality indicators (or NPS pollution) was affected by seasonal rainfall due to changes in the contribution of PS and NPS pollution. This study provides a new approach for source identification of water pollution and quantification of pollution sources using 3D fluorescence fingerprint of DOM.Climate change is likely to influence the reservoir of soil phosphorus (P) as plants adaptably respond to climate change in the perspective of P acquisition capability via root proliferation and mediating biochemical properties in the rhizosphere to access various soil P fractions. It is particularly important in cropping soils where P fertilizer plus soil P is required to synchronize crop P demand for the production sustainability under climate change. However, few studies have examined the effect of CO2 and temperature co-elevation on plant P acquisition, P fractions and relevant functional genes in the rhizosphere of different crops. Thus, the present study investigated the effect of elevated CO2 and warming on P uptake of soybean and rice grown in Mollisols, and soil P fractions and relevant biochemical properties and microbial functions in the rhizosphere with or without P application. Open-top chambers were used to achieve elevated CO2 of 700 ppm combined with warming (+ 2 °C above ambient temperature).al genes played an essential role in the conversion of P.Various carbon sources as substrates and electron donors can produce methane via different metabolic pathways. In particular, the methane produced by rice cultivation has a severe impact on climate change. However, how Fe3+, the most abundant oxide in paddy soil, mediates the methanogenesis of different carbon sources is unknown. In this study, we investigated the effect of four carbon sources with different chain lengths (acetate, glucose, nonanoate, and starch) on CH4 production and associated methanogens in iron-rich paddy soil over 90 days of anaerobic incubation. We found that glucose and starch were the more preferential substrates for liberating methane compared to acetate, and the rate was also faster. Nonanoate was unable to support methane production. Methanosarcinales and Methanobacteriales were the most predominant methanogenic archaea as shown by 16S rRNA gene sequencing, though their abundance changed over time. Additionally, a significantly higher content of iron-reducing bacteria was observed in the glucose and starch treatments, and it was significantly positively correlated with the copy number of the methanogenic mcrA gene. Together, we confirmed the methanogenic capacity of different carbon sources and their related microorganisms. We also showed that iron oxides play a central role in regulating methane emissions from paddy soils and need more attention to be paid to them.Bioneutralization of alkaline bauxite residues (BR) may be achieved through in situ organic acids produced from fermentative decomposition of carbohydrates-rich organic matters (e.g., plant residues), which are driven by organophilic and heterotrophic prokaryotes tolerant of extremely saline and alkaline conditions. selleck chemical The present study investigated if the resilience of tolerant prokaryotes in soil microbial inoculums could be improved by pre-culturing them in carbohydrate-rich plant residues, leading to enhanced bioneutralization efficacy in strongly alkaline BR. In a 2-week microcosm experiment with BR (pH ~ 10.5), it was found that the resilience of prokaryotic communities and their functional modules and bioneutralization efficacy were significantly boosted in BR admixed with plant residues (i.e., SM sugarcane mulch, LH Lucerne hay) pre-cultured with soil microbial inoculum. The results showed that 10-20% of the initially inoculated soil prokaryotic features were recovered in treatments with pre-cultured plant residues. Besides, the enriched diverse prokaryotes formed highly clustered networks in the amended BR. These modules actively drove C and N mineralization and sustained 0.8-2.0 units of pH reduction, despite the buffering effects of alkaline minerals in BR solid phase. In contrast, soil microbial inoculation cultured in the growth medium lost >99% of the original prokaryotic features in soil inoculums, resulting in merely 0.2-0.7 unit pH reduction in the treated BR. Therefore, pre-culturing soil inoculum in plant residues would be preferred as an integral system to treat BR for effective bioneutralization.With the push for sustainable design strategies, recyclable packaging is widely favored by the public in the express delivery industry due to its potential for lowering environmental burden and solving climatic challenges. The goal of this paper was to quantify and integrate the environmental footprints of polypropylene hollow board express box (PPH-EB) and establish evaluation model between the recyclable ability and environment performance (EMRE) based on life cycle assessment. This work was carried out by multiple indicators to avoid environmental problem-shifting, and corrugated cartons express box (C-EB) was taken as control objects. The results show that integrated index of PPH-EB is 94.42% lower than that of C-EB. Industrial Water Use (IWU), Primary Energy Demand (PED) and SO2 are major factors affecting results of PPH-EB, which mainly come from polypropylene particles and water resource consumption from recycle process. The most obvious advantage of PPH-EB compared with C-EB is the nearly 1700 times difference in normalized COD index caused by direct emission of paper preparation process. Scenario analysis showed that integrated index of PPH-EB was lower than that of traditional corrugated cartons after more than twice of use, but if the recycling times of PPH-EB continued to increase, the effect on reducing environmental burden was no longer significant. Therefore, although the recyclable times plays a role in decreasing the environmental impact, it is not a permanent strategy. In the design stage of the recyclable express box, the recyclable ability should be reasonably designed through EMRE, so as to minimize the environmental burden.Wildfires affect different physical, chemical, and hydraulic soil properties, and the magnitude of their effects varies depending on intrinsic soil properties and wildfire characteristics. As a result of climate change, the frequency and intensity of wildfires have increased, and understanding their impact and predicting the temperature to which soils were exposed in previous events is becoming increasingly critical. Hence, the objectives of this study were to develop a soil-heating laboratory procedure to (a) identify changes in soil properties at different temperatures and (b) to infer the temperature ranges to which heated soils have been exposed. Saturated (Ks) and unsaturated (Ku) hydraulic conductivity, pH, electrical conductivity (EC), wet aggregate stability (WAS), soil water repellency index (RIm), and soil organic matter content (SOM) were measured in six laboratory heated (LH) soils at 300, 500, 700, and 900 °C for 2 h. Bulk density (BD) and soil texture were measured in unheated (UH) and wildfire-unheated (WH) samples. UH samples were used as baselines to quantify changes in soil properties, and WH and LH samples were compared to determine the temperatures to which WH soils were exposed. The results show that in the studied temperature range, WAS exhibited a U-shaped trend, opposite to that of pH and EC. Ks and Ku (negative tension of -3 cm) tend to increase with temperature, reaching a maximum of 1.27·10-4 and 5.62·10-5 (m/s) at 900 °C, respectively. RIm was highly dependent on texture; loam soils had an average minimum and maximum of 1.84 and 2.73, at 900 and 300 °C, respectively, while sandy loam soils had an average minimum and maximum of 1.29 and 2.08 at 300 and 900 °C, respectively. Finally, the parameters that provided laboratory variation and a temperature range consistent with the results observed in naturally heated soils were WAS, RIm, pH, and EC.The ecological stability of Mediterranean ecosystems is being threatened by climate change. One of the impacts that is expected to be aggravated is the effect of summer drought prolongation toward previous or subsequent seasons by becoming more frequent. This, along with wildfires, could trigger synergistic negative effects on ecosystem regeneration capacity. Here we assessed how extending summer drought in two different ways (to autumn, AutExcl treatment, or bringing it forward to the following spring, SprExcl treatment) would affect plant recovery after an experimental fire carried out in summer in a Mediterranean seeder community. By installing rainout shelters, we assessed differences in seedling emergence, survival and establishment in the main families (Cistaceae, Labiatae, Leguminosae), and the effect on species richness and community composition. We observed that these post-fire dry season extensions reduced the total number of established seedlings and species richness. The most impacting drought treatment was AutExcl. However, the regeneration response was variable depending on the studied family. SprExcl was also determinant for Labiate survival rates. These results suggest that drought events which prolong the usual summer season may have a permanent drought legacy effect on seeder communities as practically all the seeder species populations were established in the first post-fire year. This fact is relevant for Mediterranean ecosystems dominated by seeder species as severer and longer droughts are increasingly recorded and are expected to become more frequent in forthcoming decades.The surface urban heat island (SUHI) phenomenon is characterized by both high spatial and temporal variability, while its diurnal (i.e., diel) variations have rarely been investigated because traditional satellites and sensors flying on polar orbits (e.g., Landsat, MODIS) have no diurnal sampling capability. Here we combined land surface temperature (LST) data from the Geostationary Operational Environmental Satellites (GOES-R) and the Ecosystem Spaceborne Thermal Radiometer Experiment on Space Station (ECOSTRESS) to explore the diurnal variations of SUHI and thermal differentiation among various land covers over the Boston Metropolitan Area. With the combined use of the LST data from GOES-R and ECOSTRESS, we took advantage of the strengths of both GOES-R (i.e., high frequency in each day and night) and ECOSTRESS (i.e., much finer spatial resolution). The SUHI intensity of the urban-core and suburban areas both exhibited clear diurnal patterns for different seasons a continuous increase in the SUHI intensity context of climate change.Stranding data can provide conservation-valuable information on cetaceans over long time and large space, representing a low-cost but useful approach to monitor these indicator species and their inhabiting environments. Here, we established a national dataset by collating all available records of cetacean strandings (CSs) along >30,000-km coastline of China over seven decades. Between 1950 and 2018, a total of 1763 CSs were recorded across 36 cetacean species from eight families. Importantly, 30.5% of the recorded species are currently recognized as threatened levels on the IUCN Red List. In quantity, Odontocete species accounted for 89.9% of total CSs. In 1763 CSs, 91.8% were events of single individual. Furthermore, 31.9% and 42.4% were events of alive and dead animals, respectively. The number of CSs increased gradually from 1950 to 2018, and more rapidly between 1990 and 2018. CSs occurred in all months, while a seasonal pattern could be observed with 38.5% reports between March and June. The most commonly recorded species were finless porpoises (Neophocaena spp.
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