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Smart Town and Problems Operations: Classes to the COVID-19 Crisis.
space availability and sewage treatment capacity. In addition, the optimized method proposed in this paper could reflect the pollutant accumulation characteristics of the catchment. It not only reduce the total cost of the water environment management but also effectively reduce the impact of non-point source pollution on urban water system, and could be more widely used in other areas and PPP projects.A series of environmental protective policies have been taken recently in the Pearl River Estuary (PRE) to alleviate water pollution; however, their influence on the reduction of heavy metals in estuarine water has not been known. This study selected Guangzhou as a representative city in the PRE and collected estuarine water monthly from 2008 to 2017 to track the variation of As, Hg, Pb, Cd, Cu, Zn, and Se. During the last decade, the high time-resolved record showed that the concentration of Hg, Pb, Cd, Cu, and Zn in estuarine water reduced by 39.5%, 91.0%, 86.2%, 74.6%, and 97.3%, respectively. However, the concentration of As kept in a stable range (1.89-2.69 μg L-1) and Se (0.17-0.65 μg L-1) increased slightly. The principal component analysis (PCA) and absolute principal component scores-multiple linear regression (APCS-MLR) results suggested that the upstream industrial effluents were major sources for Hg (45.5-92.7%), Pb (47.3-100%), Cd (42.0-90.6%), Cu (85.5-100%), and Zn (100%) and the geogenic source was major origin for As (84.6-98.3%) and Se (0-67.5%). The risk quotient of Hg, Pb, Cd, Cu, and Zn to aquatic organisms largely decreased from 0.03, 0.59, 0.03, 2.06, and 0.26 in 2008 to 0.02, 0.05, 0.006, 0.52, and 0.007 in 2017, respectively. The effective control of heavy metal pollution in the study area can be primarily due to the relocation of hundreds of polluting factories during the last decade.Carbon emissions in the transportation sector are of great concern, since they are the third leading contributor to China's carbon emissions. This research examines the decoupling relationship between economic outputs and carbon emissions of 11 provinces in 2000-2016 by focusing on Yangtze River Economic Belt (YREB), which is the densest traffic and economic corridor in China. Although many studies have focused on the decoupling state and its driving forces between economic outputs and carbon emissions, few studies further addressed the microscale analysis for decoupling drivers. This paper reveals the characteristic, inequality contribution ratio, and dynamic evolution of the drivers by integrating Dagum's Gini ratio with kernel density estimation in YREB. Results are as follows (1) The decoupling states presented weak decoupling state at the whole belt in the majority of the latter observed sub-periods. The decoupling states at the provincial level turned more satisfactory during the four observed sub-periods, especially for Shanghai and Zhejiang. (2) The energy intensity (EI) effect is the predominant driver for promoting the decoupling state in the vast majority of provinces, whereas value added per capita effect is the major role for inhibiting the decoupling state. (3) During the four observed sub-periods, the Gini inequality and transvariation intensity of the EI effect between sub-regions are the main sources of the provincial differences in YREB. The driving force of EI effect is increasing, but the provincial differences are expanding in the upstream and downstream regions by analyzing its dynamic evolution. selleck chemicals Understanding the temporal and spatial microscale inequality of the decoupling drivers provides governments with differentiated and forward-looking suggestions towards coordinating regional economic growth and carbon emissions reduction.Plants possess an essential ability to rapidly down-regulate light-harvesting in response to high light. This photoprotective process involves the formation of energy-quenching interactions between the chlorophyll and carotenoid pigments within the antenna of Photosystem II (PSII). The nature of these interactions is currently debated, with, among others, 'incoherent' or 'coherent' quenching models (or a combination of the two) suggested by a range of time-resolved spectroscopic measurements. In 'incoherent quenching', energy is transferred from a chlorophyll to a carotenoid and is dissipated due to the intrinsically short excitation lifetime of the latter. 'Coherent quenching' would arise from the quantum mechanical mixing of chlorophyll and carotenoid excited state properties, leading to a reduction in chlorophyll excitation lifetime. The key parameters are the energy gap, [Formula see text] and the resonance coupling, J, between the two excited states. Coherent quenching will be the dominant process when [Formula see text] Due to the large reorganization energy of the carotenoid excited state, we find that the presence (or absence) of coherent interactions have almost no impact of the dynamics of quenching. Counter-intuitively significant quenching is present even when the carotenoid excited state lies above that of the chlorophyll. We also show that, above a rather small threshold value of [Formula see text]quenching becomes less and less sensitive to J (since in the window [Formula see text] the overall lifetime is independent of it). The requirement for quenching appear to be only that [Formula see text] Although the coherent/incoherent character of the quenching can vary, the overall kinetics are likely robust with respect to fluctuations in J and [Formula see text] This may be the basis for previous observations of NPQ with both coherent and incoherent features.Non-photochemical quenching (NPQ) in photosynthetic organisms provides the necessary photoprotection that allows them to cope with largely and quickly varying light intensities. It involves deactivation of excited states mainly at the level of the antenna complexes of photosystem II using still largely unknown molecular mechanisms. In higher plants the main contribution to NPQ is the so-called qE-quenching, which can be switched on and off in a few seconds. This quenching mechanism is affected by the low pH-induced activation of the small membrane protein PsbS which interacts with the major light-harvesting complex of photosystem II (LHCII). We are reporting here on a mechanistic study of the PsbS-induced LHCII quenching using ultrafast time-resolved chlorophyll (Chl) fluorescence. It is shown that the PsbS/LHCII interaction in reconstituted proteoliposomes induces highly effective and specific quenching of the LHCII excitation by a factor ≥ 20 via Chl-Chl charge-transfer (CT) state intermediates which are weakly fluorescent.
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