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Tartaric acid (TA) as typical SOAs was introduced to the reaction system to further boost the photocatalytic Cr(VI) reduction via acting as hole scavenger, constructing charge-transfer-complex for quick electron transportation, and producing COO·- radicals. This work opened a new opportunity for modified MOFs for boosted elimination activities for environmental pollutants.We investigated the trophic structure and habitat use of ten cetacean species occurring in the oceanic waters of the western South Atlantic using naturally-occurring stable isotopes. We analysed δ15N in individual amino acids (AA) to estimate cetacean trophic position (TP) and to evaluate the spatial differences in baseline δ15N (source AAs). We adjusted cetacean bulk-skin δ13C and δ15N for the effect of trophic level using their estimated TPs, obtaining δ13CAdjusted and δ15NAdjusted, respectively. These values were applied to estimate the overlap in the niche areas of cetacean baseline sources. Our analyses showed spatial segregation between Steno bredanensis and the remaining odontocetes, and the high δ15N in this species reflects its occurrence in neritic waters of the southern region. The highest TPs were observed in Physeter macrocephalus, Stenella attenuata and Globicephala melas, while the lowest TPs were reported for S. longirostris, S. clymene and Orcinus orca. Overall, source AA-δ15N showed similar patterns as those of baseline-δ15N (zooplankton) and were higher in species sampled in the southernmost region of the study area (e.g., Delphinus delphis). Isotopic niche areas estimated using δ13CAdjusted and δ15NAdjusted suggested high overlap in foraging area between S. frontalis and Tursiops truncatus, with the latter occupying a higher TP. Our analyses of δ15N in AAs provide a unique insight into the trophic ecology, forage areas and spatial segregation in resource use among these cetacean populations. Additionally, our work provides AA-δ15N baseline for future studies on the trophic ecology and habitat use of marine organisms in the western South Atlantic.
As the amount of time people spend indoors increases globally, exposure to indoor air pollutants has become an important public health concern. Asthma is a complex disease caused and/or exacerbated by increased exposure to diverse chemical, physical and biological exposures from multiple indoor and outdoor sources. This review aims to investigate the relationship between increased indoor PM and VOC concentrations (i.e. objectively measured) and the risk of adult asthma in higher-income countries.
Eleven databases were systematically searched on the February 1, 2019 and again on the February 2, 2020. Articles were limited to those published since 1990. Reference lists were independently screened by three reviewers and authors were contacted to identify relevant articles. Backwards and forward citation chasing was used to identify further studies. Data were extracted from included studies meeting our eligibility criteria by three reviewers and assessed for quality using the Newcastle-Ottawa scale designed feased asthma symptoms. To prevent poor health outcomes among the general population, health professionals and industry must make a concerted effort to better inform the general population of the importance of appropriate use of and storage of chemicals within the home as well as better health messaging on product labelling.Wastewater management and its treatment have revolutionized the industry sector into many innovative techniques. However, the cost of recycling via chemical treatment has major issues especially in economically poor sectors. On the offset, one of the most viable and economical techniques to clean wastewater is by growing microalgae in it. Since wastewater is rich in nitrates, phosphates and other trace elements, the environment is suitable for the growth of microalgae. On the other side, the cost of harvesting microalgae for its secondary metabolites is burgeoning. While simultaneously growing of microalgae in photobioreactors requires regular feeding of the nutrients and maintenance which increases the cost of operation and hence cost of its end products. The growth of microalgae in waste waters makes the process not only economical but they also manufacture more amounts of value added products. However, harvesting of these values added products is still a cumbersome task. On the offset, it has been observed that pretreating the microalgal biomass with ultrasonication allows easy oozing of the secondary metabolites like oil, proteins, carbohydrates and methane at much lower cost than that required for their extraction. Among microalgae diatoms are more robust and have immense crude oil and are rich in various value added products. However, due to their thick silica walls they do not ooze the metabolites until the mechanical force on their walls reaches certain threshold energy. In this review recycling of wastewater using microalgae and its pretreatment via ultrasonication with special reference to diatoms is critically discussed. Perspectives on circular bioeconomy and knowledge gaps for employing microalgae to recycle wastewater have been comprehensively narrated.Microorganisms have been used for the production of various enzymes, including inducible tannase for various industrial and environmental applications. Tannases have lot of potential to convert hydrolysable tannins to gallic acid, which is one of the important industrial and therapeutic significant molecules whose demand is over 10000 tons per year. Tannins invariably occur in angiosperms, gymnosperms and pteridophytes, and predominantly present in various parts of plants such as, leaves, roots, bark and fruit. Furthermore, tannery effluents are frequently loaded with significant levels of tannic acid. Tannase can be effectively used to decrease tannin load in the toxic tannery effluent thus providing the opportunity to minimize the operational cost. Over the past three decades, tannase from microbial sources has been proposed for the degradation of natural tannins. The availability of various agro-industrial residues paves a way for maximum utilization of tannase production for the degradation of tannin and eventually the production of gallic acid. In this review, an illustrative and comprehensive account on tannase from microbial source for current day applications is presented. The present review emphasises on up-to-date microbial sources of tannases, biochemical properties, optimization of tannase production in solid state and submerged fermentation and its industrial and environmental applications.In order to avoid SARS-CoV-2 transmission inside educational buildings and promote the safe reopening of schools, the Italian Government, in line with the other European countries and in accordance with the WHO recommendations, adopted a contingency plan including actions able to guarantee adequate air ventilation in classrooms. Therefore, in this pilot study, a surveillance activity based on the real-time monitoring of CO2 levels as a proxy of SARS-CoV-2 transmission risk, was conducted inside 9 schools (11 classrooms) located in Apulia Region (South of Italy) during the reopening of schools after the lockdown due to COVID-19 pandemic. More specifically, monitoring activities and data treatment were conducted to evaluate the initial scenario inside the classrooms (first stage of evaluation) and the potential improvements obtained by applying a detailed operating protocol of air ventilation based on specific actions and the simultaneous real time visualization of CO2 levels by non-dispersive infrared (NDIR) se adequate air ventilation in educational buildings, a 4 level-risk classification including specific corrective actions for each level was provided.Microalgae sorbents are microalgae that have the potential to passively bind heavy metals/contaminants to their cellular structures in a process called biosorption. This study investigates the use of two species of microalgae to remove the toxic heavy metal cobalt from aqueous solution. Two microalgae isolates, Phormidium tenue and Chlorella vulgaris, were collected from the Wadi Hanifah Stream in Riyadh, the Kingdom of Saudi Arabia. We determined the capacity of both isolates to bioremove Co+2 ions and the optimum conditions under which this occurs. The two isolates were additionally characterized by microscopic and Fourier transform infrared spectroscopy (FTIR). In the current investigation, Phormidium tenue removed 94% of Co+2 under ideal conditions of pH 6, contact duration (30 min), starting concentration (50 mgL-1) and biosorbent dose (1gL-1); while Chlorella vulgaris removed 87% of Co+2 under the same parameters except pH 5.5 and contact duration (60 min). Fourier transform infrared spectroscopy (FTIR) confirms the binding of Co+2 to the biomass, which comprises many of the functional groups. selleck inhibitor Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) showed some alterations to the shape of algal cells and cellular components for both microalgae studied. In addition, equilibrium study by both Langmuir and Freundlich models was performed to detect the effect of certain equilibrium factors on the capacity of the biosorption mechanism. Finally, Phormidium tenue and Chlorella vulgaris were discovered to be promising microalgae for effective cobalt biosorption in aquatic conditions.The heavy metals lead (Pb), mercury (Hg), and cadmium (Cd) are ubiquitous environmental pollutants and are known to exert severe adverse impacts on the nervous system even at low concentrations. In contrast, the heavy metal manganese (Mn) is first and foremost an essential nutrient, but it becomes neurotoxic at high levels. Neurotoxic metals also include the less prevalent metalloid arsenic (As) which is found in excessive concentrations in drinking water and food sources in many regions of the world. Males and females often differ in how they respond to environmental exposures and adverse effects on their nervous systems are no exception. Here, we review the different types of sex-specific neurotoxic effects, such as cognitive and motor impairments, that have been attributed to Pb, Hg, Mn, Cd, and As exposure throughout the life course in epidemiological as well as in experimental toxicological studies. link2 We also discuss differential vulnerability to these metals such as distinctions in behaviors and occupations across the sexes. Finally, we explore the different mechanisms hypothesized to account for sex-based differential susceptibility including hormonal, genetic, metabolic, anatomical, neurochemical, and epigenetic perturbations. An understanding of the sex-specific effects of environmental heavy metal neurotoxicity can aid in the development of more efficient systematic approaches in risk assessment and better exposure mitigation strategies with regard to sex-linked susceptibilities and vulnerabilities.Gold nanoparticles (AuNPs) and AuNPs functionalized by β-cyclodextrin (β-CD/AuNPs) were prepared successfully through chemical reduction method. The structural, morphological, optical, compositional and vibrational studies for the AuNPs and β-CD/AuNPs were carried out. link3 Functionalization of AuNPs by β-CD was confirmed with FT-IR results. The UV-visible absorption spectra exhibit a red-shift with decreasing average particle size. This sustains the enhancement in surface area (SA) to volume (V) ratio that is one of the peculiar characteristics of nanoparticles. TEM results show that β-CD/AuNPs formed were monodispersed and self assembled. Also it shows a decrease in average particle size and improved distribution. The use of β-CD in the synthesis of AuNPs are revealed not only create uniform small sized nanoparticles but these water soluble nanoparticles have very good antibacterial action by inhibiting the growth of bacteria commonly found in water and sensing activity for sensing the concentration of toxic metals in water.
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