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Funneling Natural Emission in to Waveguides via Epsilon-Near-Zero Metamaterials.
Due to the higher potential for enhancing nutrient use efficiency, nanofertilizer (NF) is crucial in sustainable crop production. Thus, foliar-applied mixed nanofertilizer (MNFf) and commercial fertilizer (CF) into the soil (CFs) were claimed together ([MNFf + CFs]) and comparative nutrient use efficiency (NUE), productivity, and nutritional properties of tomato fruits were investigated. The mixed nanofertilizer (MNF) was prepared in our laboratory and characterized using scanning electron microscopy, X-ray diffraction, and Fourier transform infrared. To avoid the interference of other factors, all the treatments were divided into three groups (i) blank treatment (no fertilizer), (ii) CF treatment, and (iii) combined [MNFf + CFs] treatment. The vegetative growth and qualitative and quantitative attributes of tomatoes were recorded, and the NUE, total production, and benefit-cost ratio (BCR) were also calculated. In addition, comparative nutritional properties for all treatments were analyzed. The plant's height, stem diameter, root length, photosynthetic pigments, leaf minerals, and qualitative traits of tomato fruits were significantly (p less then 0.05) increased by [MNFf + CFs] treatment compared to CFs. The protein, fiber, Fe, Zn, and K contents were significantly (p less then 0.05) increased by 23.80, 38.10, 44.23, 60.01, and 2.39%, respectively, with the [MNFf + CFs] treatment as compared to CFs, while the ash and protein contents were both lower than the untreated tomato. Moreover, [MNFf + CFs] treatment has significantly (p less then 0.05) increased the antioxidant properties. The NUE, total production, and BCR were also increased by 26.08, 26.04, and 25.38%, respectively, with the same treatment. Thus, [MNFf + CFs] treatment could be a potential alternative for reducing the excess use of CF.X-ray photoelectron and near-edge X-ray absorption fine structure (NEXAFS) spectra, as well as the ground-state electronic/geometrical structures of a newly discovered nonclassical isomer C 2v -C66(NC), and two classical fullerene isomers C 2-#4466C66 and C s -#4169C66 with their hydrogenated derivatives [C 2v -C66H4(NC), C 2-#4466C66H4, and C s -#4169C66H4] have been calculated at the density functional theory (DFT) level. GSK-3 cancer Significant differences were observed in the electronic structures and simulated X-ray spectra after hydrogenation. Simultaneously, both X-ray photoelectron and NEXAFS spectra reflected conspicuous isomer dependence, indicating that the "fingerprints" in the X-ray spectra can offer an effective method for identifying the above-mentioned fullerene isomers. The simulated ultraviolet-visible (UV-vis) absorption spectroscopy of C 2v -C66H4(NC) has also been generated by means of the time-dependent DFT method, and the calculations are well consistent with the experimental results. Consequently, this work reveals that X-ray and UV-vis spectroscopy techniques can provide valuable information to help researchers explore the fullerene electronic structure and isomer identification on the future experimental and theoretical fullerene domains.A new series of 1,2,3-triazole hybrids containing either 2- or 4-hydroxyphenyl benzothiazole (2- or 4-HBT) and naphthalen-1-ol or 8-hydroxyquinoline (8-HQ) was synthesized in high yields and fully characterized. In vitro DNA binding studies with herring fish sperm DNA (hs-DNA) showed that quinoline- and 2-HBT-linked 1,2,3-triazoles of shorter alkyl linkers such as 6a are better with a high binding affinity (3.90 × 105 L mol-1) with hs-DNA as compared to naphthol- and 4-HBT-linked 1,2,3-triazoles bound to longer alkyl linkers. Molecular docking of most active 1,2,3-triazoles 6a-f showed high binding energy of 6a (-8.7 kcal mol-1). Also, compound 6a displayed considerable antibacterial activity and superior antifungal activity with reference to ciprofloxacin and fluconazole, respectively. The docking results of the fungal enzyme lanosterol 14-α-demethylase showed high binding energy for 6a (-9.7 kcal mol-1) involving dominating H-bonds, electrostatic interaction, and hydrophobic interaction. The absorption, distribution, metabolism, and excretion (ADME) parameter, Molinspiration bioactivity score, and the PreADMET properties revealed that most of the synthesized 1,2,3-triazole molecules possess desirable physicochemical properties for drug-likeness and may be considered as orally active potential drugs. The electrophilicity index and chemical hardness properties were also studied by density functional theory (DFT) using the B3LYP/6-311G(d,p) level/basis set.An electronic textile-based NO2 gas sensor was fabricated using commercial silk and graphene oxide (GO). It showed a fast response time and excellent sensing performance, which was simply accomplished by modifying the heat-treatment process. The heat treatment was conducted at 400 °C and different heating rates of 1, 3, and 5 °C/min. Compared with our previous research, the response time significantly decreased, from 32.5 to 3.26 min, and we found that the highest response was obtained with the sensor treated at a heating rate of 1 °C/min. To find the reason for this enhanced sensing performance, the morphology, structure, and chemical composition of the reduced GO (rGO) were investigated, depending on the thermal treatment process, using scanning electron microscopy, X-ray diffraction, Raman spectroscopy, and X-ray photoelectron spectroscopy. We also measured the temperature-dependent resistance of rGO, which was well described by the fluctuation-induced tunneling (FIT) model. These results revealed that the rGO thermally treated with 1 °C/min of heating rate had the largest amount of oxygen groups. This means that the oxygen functional groups play an important role in NO2 gas-sensing performance.Dye wastewater has become one of the difficult industrial wastewaters due to its significant characteristics such as high chroma and poor biodegradability. Here, we use collagen fibers (CFs) as the matrix, glutaraldehyde as the cross-linking agent, and polyethyleneimine (PEI) as the ammoniating modifier to prepare cationic-modified collagen fibers (CF-PEI). The CF-PEI still maintained the original fibrous structure with a larger adsorption area. The content of primary amino groups on CF-PEI was significantly increased, which not only improved the hydrophilic swelling performance of CFs but also improved the adsorption capacity. The adsorption capacity of CF-PEI for soap yellow and acid red could reach 538.2 and 369.7 mg g-1, respectively. The adsorption rate was fast, and the adsorption equilibrium could be reached in about 60 min. Desorption regeneration studies have shown that 0.1 mol L-1 HCl could achieve a better desorption effect, and the CF-PEI had a good recycling performance. The ammoniated modified CF-PEI was an excellent adsorption treatment material for anionic dye wastewater. It is expected to become an effective way for high-value resource utilization of waste dander in the leather industry.A modular and flexible three-step synthetic strategy has been developed for the synthesis of acridone natural products of biological significance. The tetracyclic core of acridone derivatives has been achieved efficiently in high yield from commercially available anthranilic acid and phenol derivatives via condensation reaction, followed by regioselective annulation. Acridone alkaloids acronycine and noracronycine are synthesized in improved overall yields in fewer steps than the previously reported approaches. The method has further been used for the synthesis of atalaphyllidine and 5-hydroxynoracronycine in excellent yields for the first time. Moreover, the synthetic utility of the present strategy has been showcased by the synthesis of oxa and thia analogues of acronycine alkaloid.Nonpolar solvents have been reported to exhibit a nonlinear flux-pressure behavior in hydrophobic membranes. This study explored the flux-pressure relationship of six nonpolar solvents in a lab-cast hydrophobic poly(dimethylsiloxane) (PDMS) membrane and integrated the permeance behavior in the evaluation of the proposed transport model. The solvents exhibited a nonlinear relationship with the applied pressure, along with the point of permeance transition (1.5-2.5 MPa), identified as the critical pressure corresponding to membrane compaction. Two classical transport models, the pore-flow model and solution-diffusion model, were evaluated for the prediction of permeance. The solution-diffusion model indicated a high correlation with the experimental results before the point of transition (R 2 = 0.97). After the point of transition, the compaction factor (due to membrane compaction after the critical pressure) derived from the permeance characteristics was included, which significantly improved the predictability of the solution-diffusion model (R 2 = 0.91). A nonlinear flux-pressure behavior was also observed in hexane-oil miscella (a two-component system), confirming the existence of a similar phenomenon. The study revealed that a solution-diffusion model with appropriate inclusion of compaction factor could be used as a prediction tool for solvent permeance over a wide range of applied transmembrane pressures (0-4 MPa) in solvent-resistant nanofiltration (SRNF) membranes.Recently, transition metal (TM)-porphyrin-like graphene has been predicted to be a promising material for CO2 capturing under favorable conditions. Such materials can capture CO2 at 300 K and release it at 450 K. However, the captured CO2 gas is mostly stored in oceans. With the aid of first principles calculations, we herein propose a method in which the captured CO2 is converted into an environmentally friendly product, formic acid. Addition of H2 to CO2 molecules adsorbed on Sc- and Ti-porphyrin-like graphene was found to catalyze this conversion. We also performed nudged elastic band calculations and thermodynamic analysis using the first-order Polanyi-Wigner equation and equilibrium statistical mechanics to investigate the chemical reactions involved in this conversion. In addition, we performed Bader charge analysis to obtain insights into the mechanism of charge transfer and adsorption throughout the conversion. Our study presents a novel method in which the captured CO2 is treated by converting it into an environmentally friendly product. Since this method does not require CO2 storage, it is expected to be an effective strategy to manage the rising CO2 level in the environment.Nature manifests diverse and complicated patterns through efficient physical, chemical, and biological processes. One of the approaches to generate complex patterns, as well as simple patterns, is the use of the cellular automata algorithm. However, there are certain limitations to produce such patterns experimentally due to the difficulty of finding candidate programmable building blocks. Here, we demonstrated the feasibility of generating an ocellated lizard skin-like pattern by simulation considering the probabilistic occurrence of cells and constructed the simulation results on DNA lattices via bottom-up self-assembly. To understand the similarity between the simulated pattern (SP) and the observed pattern (OP) of lizard skin, a unique configuration scheme (unit configuration was composed of 7 cells) was conceived. SPs were generated through a computer with a controlling population of gray and black cells in a given pattern. Experimental patterns (EPs) on DNA lattices, consisting of double-crossover (DX) tiles without and with protruding hairpins, were fabricated and verified through atomic force microscopy (AFM).
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