Notes

Cholangioscopy as well as double-balloon enteroscopy mediated "sandwich puncture" of a completely sealed choledochojejunostomy.
The obtained samples are also analyzed for antimicrobial activity using Gram-negative and Gram-positive bacteria, which are majorly involved in implant failure. The F doped samples revealed excellent bactericidal activity. Hence, this study confirms that the non-toxic and excellent antibacterial mesoporous F doped HAp can be a useful candidate for biocidal implant application.Recently, sophisticated technologies are applied to design a certain surface nature that can have superhydrophobic properties. Thus, a simple spray technique was introduced to prepare a superhydrophobic surface using rGO with Ni-S system (rGO-Ni) by using NiSO4 catalyst under microwave irradiation at various reaction times of 5, 10, 20, and 30 min. The GO reduction was conducted at a fixed Ar/H2 ratio, a flow rate of 0.4 L/min, microwave power of 720 W, and a mass of 0.5 g. GO powder with nickel sulfate catalyst was treated under Ar/H2 (41) mixture for GO reduction, where Ar and H2 were expected to prevent the rebinding of oxygen released from GO. The result of XRD and Raman measurement confirms that rGO-Ni prepared at reaction time 20 min exhibit the highest reduction of GO and the presence of various Ni-S crystal structures such as NiS, NiS2, Ni3S2, and Ni3S4 due to decomposition of NiSO4. The rGO-Ni coating performance shows superhydrophobic nature with a contact angle of 150.1°. The AFM images show that the addition of nickel to rGO produces a quasi-periodic spike structure, which increases the superhydrophobicity of the r-GO-Ni coated glass with a contact angle of 152.6°. It is emphasized that the proposed simple spray coating using rGO-Ni provides a more favorable option for industry application in obtaining superhydrophobic surfaces.Industrial spray coating processes are known to produce excellent coatings on large surfaces and are thus often used for in-line production. However, they could be one of the most critical sources of worker exposure to ultrafine particles (UFPs). A monitoring campaign at the Witek s.r.l. (Florence, Italy) was deployed to characterize the release of TiO2 NPs doped with nitrogen (TiO2-N) and Ag capped with hydroxyethyl cellulose (AgHEC) during automatic industrial spray-coating of polymethyl methacrylate (PMMA) and polyester. Aerosol particles were characterized inside the spray chamber at near field (NF) and far field (FF) locations using on-line and off-line instruments. Results showed that TiO2-N suspension produced higher particle number concentrations than AgHEC in the size range 0.3-1 µm (on average 1.9 102 p/cm3 and 2.5 101 p/cm3, respectively) after background removing. At FF, especially at worst case scenario (4 nozzles, 800 mL/min flow rate) for TiO2-N, the spray spikes were correlated with NF, with an observed time lag of 1 minute corresponding to a diffusion speed of 0.1 m/s. The averaged ratio between particles mass concentrations in the NF position and inside the spray chamber was 1.7% and 1.5% for TiO2-N and for AgHEC suspensions, respectively. The released particles' number concentration of TiO2-N in the size particles range 0.3-1 µm was comparable for both PMMA and polyester substrates, about 1.5 and 1.6 102 p/cm3. In the size range 0.01-30 µm, the aerosol number concentration at NF for both suspensions was lower than the nano reference values (NRVs) of 16·103 p/cm-3.Over past decades, the multicolor carbon dots (M-CDs) have attracted enormous attentions due to their tunable photoluminescence and versatile applications. Herein, the nitrogen-doped (N-doped) M-CDs including green, chartreuse, and pink emissive CDs are successfully synthesized by ultrasonic treatment of kiwifruit juice with different additive reagents such as ethanol, ethylenediamine, and acetone. Owing to their strong fluorescence upon irradiation with 365 nm UV light, the highly water-soluble M-CDs present great potential in the anticounterfeit field as fluorescent inks. Particularly, the resulting green emission CDs (G-CDs) with excellent fluorescence and stability are applied as a label-free probe model for "on-off" detection of Fe3+. The fluorescence of G-CDs is significantly quenched by Fe3+ through static quenching. The nanoprobe demonstrates good selectivity and sensitivity toward Fe3+ with a detection limit of ~0.11 μM. TEN-010 inhibitor Besides, the quenched fluorescence of G-CDs by Fe3+ can be recovered by the addition of PO43- or ascorbic acid (AA) into the CDs/Fe3+ system to realize the "off-on" fluorescent process. Furthermore, NOT and IMPLICATION logic gates are constructed based on the selection of Fe3+ and PO43- or AA as the inputs, which makes the G-CD-based sensors utilized as various logic gates at molecular level. Therefore, the N-doped M-CDs hold promising prospects as competitive candidates in monitoring the trace species, applications in food chemistry, anticounterfeit uses, and beyond.As the building block of brain-inspired computing, resistive switching memory devices have recently attracted great interest due to their biological function to mimic synapses and neurons, which displays the memory switching or threshold switching characteristic. To make it possible for the Si-based artificial neurons and synapse to be integrated with the neuromorphic chip, the tunable threshold and memory switching characteristic is highly in demand for their perfect compatibility with the mature CMOS technology. We first report artificial neurons and synapses based on the Al/a-SiNxOyH/P+-Si device with the tunable switching from threshold to memory can be realized by controlling the compliance current. It is found that volatile TS from Al/a-SiNxOyH/P+-Si device under the lower compliance current is induced by the weak Si dangling bond conductive pathway, which originates from the broken Si-H bonds. While stable nonvolatile MS under the higher compliance current is attributed to the strong Si dangling bond conductive pathway, which is formed by the broken Si-H and Si-O bonds. Theoretical calculation reveals that the conduction mechanism of TS and MS agree with P-F model, space charge limited current model and Ohm's law, respectively. The tunable TS and MS characteristic of Al/a-SiNxOyH/P+-Si device can be successfully employed to mimic the biological behavior of neurons and synapse including the integrate-and-fire function, paired-pulse facilitation, long-term potentiation and long-term depression as well as spike-timing-dependent plasticity. Our discovery supplies an effective way to construct the neuromorphic devices for brain-inspired computing in the AI period.Nanotechnology offers new opportunities for the development of novel materials and strategies that improve technology and industry. This applies especially to agriculture, and our previous field studies have indicated that zinc oxide nanoparticles provide promising nano-fertilizer dispersion in sustainable agriculture. However, little is known about the precise ZnO-NP effects on legumes. Herein, 1 mg·L-1 ZnO-NP spray was dispersed on lentil plants to establish the direct NP effects on lentil production, seed nutritional quality, and stress response under field conditions. Although ZnO-NP exposure positively affected yield, thousand-seed weight and the number of pods per plant, there was no statistically significant difference in nutrient and anti-nutrient content in treated and untreated plant seeds. In contrast, the lentil water stress level was affected, and the stress response resulted in statistically significant changes in stomatal conductance, crop water stress index, and plant temperature. Foliar application of low ZnO-NP concentrations therefore proved promising in increasing crop production under field conditions, and this confirms ZnO-NP use as a viable strategy for sustainable agriculture.Nanolaminates are extensively studied due to their unique properties, such as impact resistance, high fracture toughness, high strength, and resistance to radiation damage. Varieties of nanolaminates are being fabricated to achieve high strength and fracture toughness. In this study, one such nanolaminate fabricated through accumulative roll bonding (Cu(16)/Nb(16) ARB nanolaminate, where 16 nm is the layer thickness) was used as a test material. Cu(16)/Nb(16) ARB nanolaminate exhibits crystallographic anisotropy due to the existence of distinct interfaces along the rolling direction (RD) and the transverse direction (TD). Nanoindentation was executed using a Berkovich tip, with the main axis oriented either along TD or RD of the Cu(16)/Nb(16) ARB nanolaminate. Subsequently, height profiles were obtained along the main axis of the Berkovich indent for both TD and RD using scanning probe microscopy (SPM), which was later used to estimate the pile-up along the RD and TD. The RD exhibited more pile-up than the TD due to the anisotropy of the Cu(16)/Nb(16) ARB interface and the material plasticity along the TD and RD. An axisymmetric 2D finite element analysis (FEA) was also performed to compare/validate nanoindentation data, such as load vs. displacement curves and pile-up. The FEA simulated load vs. displacement curves matched relatively well with the experimentally generated load-displacement curves, while qualitative agreement was found between the simulated pile-up data and the experimentally obtained pile-up data. The authors believe that pile-up characterization during indentation is of great importance to documenting anisotropy in nanolaminates.Reduced graphene oxide (rGO) is one of the most well-known graphene derivatives, which, due to its outstanding physical and chemical properties as well as its oxygen content, has been used for wastewater treatment technologies. Particularly, extra functionalized rGO is widely preferred for treating wastewater containing dyes or heavy metals. Nevertheless, the use of non-extra functionalized (pristine) rGO for the removal of cationic pollutants is not explored in detail or is ambiguous. Herein, pristine rGO-prepared by an eco-friendly protocol-is used for the removal of cationic pollutants from water, i.e., methylene blue (MB) and mercury-(II) (Hg-(II)). This work includes the eco-friendly synthesis process and related spectroscopical and morphological characterization. Most importantly, the investigated rGO shows an adsorption capacity of 121.95 mg g-1 for MB and 109.49 mg g-1 for Hg (II) at 298 K. A record adsorption time of 30 min was found for MB and 20 min for Hg (II) with an efficiency of about 89% and 73%, respectively. The capture of tested cationic pollutants on rGO exhibits a mixed physisorption-chemisorption process. The present work, therefore, presents new findings for cationic pollutant adsorbent materials based on oxidized graphenes, providing a new perspective for removing MB molecules and Hg(II) ions.This paper proposes a new graphene gamma- and beta-radiation sensor with a backend RF ring oscillator transducer employed to convert the change in the graphene resistivity due to ionizing irradiation into a frequency output. The sensor consists of a CVD monolayer of graphene grown on a copper substrate, with an RF ring oscillator readout circuit in which the percentage change in frequency is captured versus the change in radiation dose. The novel integration of the RF oscillator transducer with the graphene monolayer results in high average sensitivity to gamma irradiation up to 3.82 kΩ/kGy, which corresponds to a percentage change in frequency of 7.86% kGy-1 in response to cumulative gamma irradiation ranging from 0 to 1 kGy. The new approach helps to minimize background environmental effects (e.g., due to light and temperature), leading to an insignificant error in the output change in frequency of the order of 0.46% when operated in light versus dark conditions. The uncertainty in readings due to background light was analyzed, and the error in the resistance was found to be of the order of 1.
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