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A negative water time lag, ranging from -11 to -20 min depending on the draw solution concentration, is observed in the AL-DS orientation. Still, in the AL-FS orientation, the water flux is practically constant from the experiment's onset, leading to a negligible water time lag (<1 min). The new method demonstrated in this paper can be a potent tool for characterizing osmotic membranes.The efficient preparation of hydrophilic polypropylene membranes has always been a problem. Here, a twin-screw extruder was used to melt-blend ethylene-vinyl alcohol copolymer and polypropylene; then, hollow fibers were extrusion-molded with a spinneret and taken by a winder; after this, dimethyl sulfoxide was used to dissolve the ethylene-vinyl alcohol copolymer of the fiber to obtain a polypropylene hollow-fiber membrane. This procedure was used to study the effects of different contents and segment structure of ethylene-vinyl alcohol copolymer on the structure and filtration performance of the membranes; furthermore, the embedded factor and blocked factor were used to evaluate the ethylene-vinyl alcohol copolymer embedded in the matrix without dissolving and or being completely blocked in the matrix, respectively. The results show that the increase in ethylene-vinyl alcohol copolymer could reduce the embedded factor and increase the blocked factor. The increase in the polyethylene segments of ethylene-vinyl alcohol copolymer could increase both the embedded factor and blocked factor. The water permeation of the membrane reached 1300 Lm-2·h-1·bar-1 with a 100% rejection of ink (141 nm) and the elongation at break reached 188%, while the strength reached 22 MPa. The dissolution-induced pores method provides a completely viable alternative route for the preparation of polypropylene membranes.The pathogenic variant of the TAZ gene is directly associated with Barth syndrome. Because tafazzin in the mitochondria is responsible for cardiolipin (CL) remodeling, all molecules related to the metabolism of CL can affect or be affected by TAZ mutation. In this study, we intend to recover the distortion of the mitochondrial lipid composition, especially CL, for Barth syndrome treatment. The genetically edited TAZ knockout HAP1 cells were demonstrated to be a suitable cellular model, where CL desaturation occurred and monolyso-CL (MLCL) was accumulated. From the species analysis by mass spectrometry, phosphatidylethanolamine showed changed species content after TAZ knockout. TAZ knockout also caused genetic down-regulation of PGS gene and up-regulation of PNPLA8 gene, which may decrease the biosynthesis of CLs and increase the hydrolysis product MLCL. Supplemented phosphatidylglycerol(181)2 (PG(181)2) was successfully biosynthesized to mature symmetrical CL and drastically decrease the concentration of MLCL to recover the morphology of mitochondria and the cristae shape of inner mitochondria. Newly synthesized mature CL may induce the down-regulation of PLA2G6 and PNPLA8 genes to potentially decrease MLCL production. The excess supplemented PG was further metabolized into phosphatidylcholine and phosphatidylethanolamine.Fabrication of highly efficient oil/water separation membranes is attractive and challenging work for the actual application of the membranes in the treatment of oily wastewater and cleaning up oil spills/oil leakage accidents. In this study, hydrophilic poly(ethylene-co-polyvinyl alcohol) (EVOH) nanofiber membranes were made using an electrospinning technique for oil/water separation. The as-prepared EVOH electrospun nanofiber membranes (ENMs) exhibited a super-hydrophilic property (water contact angle 33.74°) without further treatment. As prepared, ENMs can provide continuous separation of surfactant-free and surfactant-stabilized water-in-oil emulsions with high efficiency (i.e., flux 8200 L m-2 h-1 (LMH), separation efficiency >99.9%). In addition, their high stability (i.e., reusable, mechanically robust) would broaden the conditions under which they can be employed in the real field oil/water separation applications. Various characterization techniques (including morphology investigation, pore size, porosity, mechanical properties, and performance test) for gravity-driven oil/water separation were employed to evaluate the newly prepared EVOH ENMs.Rapid population growth and urbanization are two main drivers for the over-abstraction of conventional freshwater resources in various parts of the world, which leads to the situation of water scarcity (per capita availability <1000 m3/year). Predictions based on the World Bank projected population data and the FAO AQUASTAT database for freshwater availability show that by 2050, 2 billion people living in 44 countries will likely suffer from water scarcity, of which 95% may live in developing countries. Among these, the countries that will likely be most strongly hit by water scarcity by 2050 are Uganda, Burundi, Nigeria, Somalia, Malawi, Eritrea, Ethiopia, Haiti, Tanzania, Niger, Zimbabwe, Afghanistan, Sudan, and Pakistan. Currently, these countries have not yet established desalination to meet their freshwater demand. However, the current global trend shows that membrane-based desalination technology is finding new outlets for supplying water to meet growing water demand in most of the water-scarce countries. These 14 water-scarce countries will demand an additional desalination capacity of 54 Mm3/day by 2050 in order to meet the standard of current municipal water demand and to compensate for the withdrawal of renewable resources. selleck products Case studies from India, China, and South Africa have highlighted that other countries may apply the strategy of using desalinated water for industrial users. Moreover, challenges to the widespread adoption of desalination exist such as expense, significant energy use, the need for specialized staff training, the large carbon footprint of facilities, environmental issues such as greenhouse gas emission (GHGs), chemical discharge, and operational problems such as membrane fouling.As an attractive way to deal with fresh water shortage, membrane-based desalination technologies are receiving increased interest. However, concentrated seawater brine, in needing further treatment, remains a main obstacle for desalination via membrane technology. Here, a hybrid technology integrating pressure-retarded osmosis with activated sludge process (PRO-MBR) was applied for simultaneously treating concentrated seawater brine and municipal wastewater. Performance of the PRO-MBR, including water flux, power density, contaminants removal, and membrane fouling was evaluated and compared at two different membrane orientations (i.e., active layer facing feed solution (AL-FS) mode and active layer facing draw solution (AL-DS) mode). During the PRO-MBR process, the municipal wastewater was completely treated regardless of the membrane orientation, which means that there was no concentrated sewage needing further treatment, owing to the biodegradation of microorganisms in the bioreactor. In the meantime, the concentrated brine of seawater desalination was diluted into the salinity level of seawater, which met the standard of seawater discharge. Owing to the high rejection of forward osmosis (FO) membrane, the removal efficiency of total organic carbon (TOC), total phosphorus (TP), ammonia nitrogen (NH4+-N), and total nitrogen (TN) was higher than 90% at both modes in the PRO-MBR. In addition, the PRO-MBR can simultaneously recover the existing osmotic energy between the municipal wastewater and the seawater brine at both modes. Compared with the AL-DS mode, the AL-FS mode took a shorter time and achieved a bigger power density to reach the same terminal point of the PRO-MBR owing to a better water flux performance. Furthermore, the membrane fouling was much more severe in the AL-DS mode. In conclusion, the current study demonstrated that the PRO-MBR at the AL-FS mode can be a promising and sustainable brine concentrate and municipal wastewater treatment technology for its simultaneous energy and water recovery.Mung bean (Vigna radiata) flour serves as an excellent biopolymer and a potential material for producing antioxidant and antimicrobial phyto-films. In addition to mung bean flour, this study also combined the longkong (Aglaia dookkoo Griff.) pericarp extract (LPE, 1.5%) and ultrasonication process (0 (C1), 2 (T1), 4 (T2), 6 (T3), 8 (T4), and 10 (T5) min, sonicated at 25 kHz, 100% amplitude) in film emulsion production to improve the antioxidant and antimicrobial efficiency in the phyto-films. This study showed that sonication increased the phyto-films' color into more lightness and yellowness, and the intensity of the color changes was in accordance with the increased sonication time. Alternatively, the thickness, water vapor permeability, and solubility of the films were adversely affected by extended sonication. In addition, elongation at break and tensile strength increased while the Young modulus decreased in the phyto-films with the extended sonication. Furthermore, the droplet size and polydispersity ine used in the film emulsions to enhance the efficiency of the antioxidant and antimicrobial properties of phyto-films.Collagen-based barrier membranes are nowadays the prevalent option for Guided Bone Regeneration (GBR) procedures. Xenogeneic collagen is highly biocompatible as it shares a similar structure to native human collagen, which prevents it from eliciting an exaggerated host immune response. Most commercially available collagen barrier membranes are porcine-derived, while bovine-derived alternatives are still rarely available. The aim of the present study was to investigate the tissue responses and the barrier functionality of a novel GBR membrane composed of bovine collagen type I (BM). Therefore, the subcutaneous implantation model in Wistar rats was performed to compare the novel medical device with two already clinically used native porcine-based barrier membranes, i.e., Jason® membrane (JM) and Bio-Gide® (BG), at 10-, 30-, 60-, and 90-days post implantationem. Histochemical and immunohistochemical stains were used for histopathological evaluation including a biocompatibility scoring according to the DIN EN ISO 10993-6 norm as well as histomorphometrical analyses of the occurrence of M1 and M2 macrophages and the transmembraneous vascularization. The bovine membrane exhibited a host tissue reaction that was comparable to both control materials, which was verified by the scoring results and the histomorphometrical macrophage measurements. Moreover, the novel membrane exhibited an integration pattern without material fragmentation up to day 60. At day 90, material fragmentation was observable that allowed for "secondary porosity" including transmembrane vascularization. The results of this study suggest that the novel bovine barrier membrane is fully biocompatible and suitable for indications that require GBR as a suitable alternative to porcine-sourced barrier membranes.Multi-stage A/O-MBR processes were designed to improve wastewater treatment efficiency; three different designs were carried out and compared in this study. The 2(A/O)-MBR process, i.e., with two sets of anoxic/oxic tanks in series, showed better effluent quality than A/O-MBR and 3(A/O)-MBR processes. The removal rates of COD, NH4+-N, TP and TN were 95.29%, 89.47%, 83.55% and 78.58%, respectively, complying satisfactorily with China's urban sewage treatment plant pollutant discharge standards. In terms of membrane fouling, the 3(A/O)-MBR process demonstrated the lowest fouling propensity. The microbial community structure in each bioreaction tank was analyzed, the results from which matched with the process efficiency and fouling behavior.
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