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Bacterial cellulose (BC) has shown potential as a separation material. Herein, the performance of BC in pressure-driven separation is investigated as a function of incubation conditions and post-culture treatment. The pure water flux of never-dried BC (NDBC), was found to be 9 to 16 times higher than that for dried BC (DBC), in a pressure range of 0.25 to 2.5 bar. The difference in pressure response of NDBC and DBC was observed both in cross-flow filtration and capillary flow porometry experiments. DBC and NDBC were permeable to polymers with a hydrodynamic radius of ∼60 nm while protein retention was possible by introducing anionic surface charges on BC. The results of this work are expected to expand the development of BC-based filtration membranes, for instance towards the processing of biological fluids.Various Pickering emulsions-based system have been increasing demand for potential applications in a wide variety of fields. However, tunable emulsifiers and controllable Pickering emulsions with the ability to respond to external triggers remains an outstanding challenge. Here, we demonstrate the photo-tuning amphiphilicity in Pickering emulsions using β-cyclodextrin-grafted alginate and azobenzene derivative supramolecular self-assemblies as photoactivatable emulsifiers. Specifically, the photoisomerization of a host-guest system between β-cyclodextrin and azobenzene derivative was employed to tailor the polarity of the microenvironment, resulting in the reversible variation of hydrophilic/hydrophobic balance. The photoactivatable emulsifier based on supramolecular self-assemblies could effectively destabilize o/w emulsions by tailoring the amphiphilic balance at oil-water interface under an external UV irradiation, leading to the oil-water separation from Pickering emulsion. The light regulating demulsification is further showcased here by the photodelivery of hydrophobic model drug. Finally, this study provides a sustainable yet eco-friendly formulation for the fabrication of stimuli-responsive Pickering emulsions.Molecular-scale interactions between water and cellulose microfibril bundles in plant cell walls are not fully understood, despite their crucial role for many applications of plant biomass. Recent advances in X-ray and neutron scattering analysis allow more accurate interpretation of experimental data from wood cell walls. At the same time, microfibril bundles including hemicelluloses and water can be modelled at atomistic resolution. Computing scattering patterns from atomistic models enables a new, complementary approach to decipher some of the most fundamental questions at this level of the hierarchical cell wall structure. This article introduces studies related to moisture behavior of wood with small/wide-angle X-ray/neutron scattering and atomistic simulations, recent attempts to combine these two approaches, and perspectives and open questions for future research using this powerful combination. Finally, we discuss the opportunities of the combined method in relation to applications of lignocellulosic materials.Osteomyelitis is a complex disease in orthopedics mainly caused by bacterial pathogens invading bone or bone marrow. The treatment of osteomyelitis is highly difficult and it is a major challenge in orthopedic surgery. The long-term systemic use of antibiotics may lead to antibiotic resistance and has limited effects on eradicating local biofilms. Localized antibiotic delivery after surgical debridement can overcome the problem of antibiotic resistance and reduce systemic toxicity. Chitosan, a special cationic polysaccharide, is a product extracted from the deacetylation of chitin. It has numerous advantages, such as nontoxicity, biocompatibility, and biodegradability. Recently, chitosan has attracted significant attention in bacterial inhibition and drug delivery. Because chitosan contains many functional bioactive groups conducive to chemical reaction and modification, some chitosan-based biomaterials have been applied as the local antibiotic delivery systems in the treatment of osteomyelitis. This review aims to introduce recent advances in the biomedical applications of chitosan-based drug delivery systems in osteomyelitis treatment and to highlight the perspectives for further studies.In this study, Lactococcus lactis was embedded in a film of corn starch (NS) and carboxymethyl cellulose (CMC) prepared using a casting method. At a CMCNS ratio of 55, the composite film had the best comprehensive properties. Scanning electron microscopy images clearly showed that L. lactis was effectively embedded. The film with 1.5 % L. DN02 ic50 lactis showed the best performance and the lowest water vapor transmission rate (5.54 × 10-11 g/m s Pa. In addition, the edible film retained a viable count of 5.64 log CFU/g of L. lactis when stored at 4 °C for 30 days. The composite film with 1.5 % L. lactis showed the highest release of nisin (3.35 mg/mL) and good antibacterial activity against Staphylococcus aureus (53.53 %) after 8 days. Therefore, this edible film is a viable alternative antimicrobial strategy for the active packaging of foods containing low moisture content.The use of xanthan gum (XG) as a thickener increases solution viscosity, and therefore, the cost of subsequent processes such as fluid transportation and purification. Herein, we investigate the degradation of XG by urea, sodium dodecyl sulfate (SDS) and cetyltrimethylammonium bromide (CTAB). The results showed that CTAB degraded the XG more than SDS or urea. Interestingly, the degree of CTAB-induced degradation varied with the concentration regime. Thus, increasing CTAB concentration from 0.01 to 0.1 M decreased the complex viscosity (|η*|), whereas from 0.2 to 0.5 M the |η*| increased. For XG/SDS, the |η*| was unchanged with increasing SDS concentration from 0.01 to 0.1 M, whereas it decreased from 0.2 to 0.5 M. For XG/urea, the |η*| was stable in all concentrations. At the atomic-scale, computer simulations revealed that the degrading effect of CTAB was due to preferential interaction with the XG sidechain. These findings can enhance industrial applications of XG.
Website: https://www.selleckchem.com/products/dn02.html
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