Notes

Focusing the particular network control of biohybrid hydrogel matrices to modulate the discharge associated with SDF-1.
Tungsten trioxide nanoparticles (WO3 NPs) have shown increasing promise in biological and biomedical fields in recent years. However, their possible hazards, especially the adverse effects related to their sizes on human health and environment, are still yet poorly understood. In this study, we compared the hepatotoxicity in mice induced by WO3 nanorods of two different lengths (125-200 nm and 0.8-2 μm) via intraperitoneal injection, and explored the protective role of melatonin, an antioxidant, against the hepatotoxicity. The results showed that 10 mg/kg/day of shorter WO3 nanorods could cause obvious hepatic function impairment, histopathological lesions, and significant enhancement in levels of oxidative stress and inflammation in mouse liver. However, similar effects were found only in the 20 mg/kg/day longer WO3 nanorods-treated mice, and these adverse effects were attenuated by pretreatment with melatonin. These findings indicate that WO3 nanorods can exert hepatotoxicity in mice in a dose- and length-dependent manner, and that shorter WO3 nanorods cause more severe hepatotoxicity than their longer counterparts. Melatonin could serve as an effective protective agent against the longer WO3 nanorods-induced hepatotoxicity by decreasing the oxidative stress level. This study is important for determining the environmental and human health risks of exposure to WO3 NPs and their size-dependent toxicity, and provides an appealing strategy to avoid the adverse effects. WO3 nanorods with different lengths can exert hepatotoxicity in mice, in a dose- and length-dependent manner. Short WO3 nanorods causes more severe hepatic injury than long ones. Melatonin exhibits an effectively protective effects against WO3 nanorods-induced hepatic injury through reducing the oxidative stress level.Dust is an important factor to indoor pollution that contains suspended particles and heavy metals. Since today, use of computer has become an essential part of human life. Therefore, this study aimed to compare the amount of heavy metals deposited on CRTs and LCDs and their risk assessment. Ten dust samples for each type of monitor were collected from CRT and LCD screens in accordance with the standard OSHA ID-125 and ID-206, wet filter wipe method. Concentrations of Pb, Hg, Cd, Cr, and Cu were measured by inductively coupled plasma-optical emission spectrometer. Exposure and risk assessment of these elements were estimated using USEPA's exposure parameters. The average concentrations of heavy metals in the dust on CRTs (0.82 mg/kg) were higher than LCD screens (0.69 mg/kg). Cr with 62.824% and Hg with 0.849% had the highest and lowest average concentration in both types of monitors. The non-carcinogenic risk and carcinogenicity indexes of CRT monitors were 0.0009, and 3.94 × 10-11 and for LCD monitors were 0.0008 and 2.94 × 10-11. In both monitors, ingestion is the main route to exposure with heavy metals. The average concentration of heavy metals in CRT dust. HI values for studied metals in dust of CRTs and LCDs were less than safe limit of 1. Because RI less then 10-4, cancer risk of studied elements in dust can be ignored.Bacteria play an important role in pollutant transformation in activated sludge-based wastewater treatment plants (WWTPs). Exploring the microbial community structure and diversity is essential to improving the performance of wastewater treatment processes. This study employed Illumina MiSeq high-throughput sequencing to investigate the microbial community composition and diversity in a cattle farm wastewater treatment plant (Cf-WWTP). The results showed that the dominant phyla in the whole process were Proteobacteria, Bacteroidetes, and Firmicutes. The principal coordinate analysis (PCoA) indicated that the different stages had a significant impact on the microbial community structure; Bacteroidetes was the dominant phylum in the anearobic stage and Proteobacteria was the dominant phylum in the anoxic-oxic stage. Redundancy analysis (RDA) revealed that total phosphorus (TP) was the most significant factor that regulated the microbial community composition, followed by chemical oxygen demand (COD), total nitrogen (TN), and pH. Proteobacteria, Patescibacteria, and Chloroflexi were simultaneously negatively correlated with TN, COD, and TP. Nitrogen metabolic pathway and transformation mechanism was elucidated by a complete denitrification function predicted with phylogenetic investigation of communities with reconstruction of unobserved states (PICRUSt), as well as detection of ammonia-oxidizing bacteria (AOB) and nitrite-oxidizing bacteria (NOB). These results provide new insights into our understanding of microbial community and metabolic functions of Cf-WWTP.This work aims to assess multidimensional energy poverty and energy efficiency for environmental policy measures using data envelopment analysis (DEA), a DEA-Like mathematical composite indicator applied on a dataset based on multiple sets of variables from South Asian economies. The multidimensional energy poverty index (MEPI) is computed to analyze the combining effects and energy poverty in these countries. Simultaneously, South Asia's metropolitan areas' population rose by 130 million between 2001 and 2011 and is projected to expand by approximately 250 million by 2030. The findings reveal that endogenous increasing population shocks account for about 72% of energy use. In contrast, the long-term effects of remittance revenue, economic growth, and urbanization on energy use are approximately 20%, 8.25%, and 0.03%, respectively. This work advocates more coordinated and innovative policies to eliminate energy poverty. It can act as a base for policymakers and government officials to make efficient policies and enforce them properly in the regional power sector. Policies should be designed around a smarter use of biomass for cooking, alternate sources for domestic energy production, increased programs for biomass-based cookstoves, and periodic regional-level energy database development.In this study, a ternary magnetically separable nanocomposite of silver nanoparticles (AgNPs) embedded in magnetic graphene oxide (Ag/Fe3O4@GO) was designed and synthesized. Beta-cyclodextrin was used as a green reducing and capping agent for decorating of AgNPs on Fe3O4@GO. The fabricated material was characterized using X-ray diffractometry, Fourier transform infrared spectroscopy, scanning electron microscopy, vibrating sample magnetometry, and energy-dispersive X-ray spectroscopy. The catalytic properties of the prepared Ag/Fe3O4@GO for the reduction of 4-nitrophenol (4-NP) and methylene blue (MB) dye with sodium borohydride were investigated in detail. The morphological and structural studies revealed that Fe3O4 and AgNPs with a mean size of 12 nm were uniformly distributed on the GO sheet at high densities. The catalytic tests showed that Ag/Fe3O4@GO exhibited an ultrafast catalytic reduction of 4-NP and MB with a reduction rate constant of 0.304 min-1 and 0.448 min-1, respectively. Moreover, the catalyst demonstrated excellent stability and reusability, as evidenced by the more than 97% removal efficiency maintained after five reuse cycles. The Ag/Fe3O4@GO catalyst could be easily recovered by the magnetic separation due to the superparamagnetic nature of Fe3O4 with high saturated magnetization (45.7 emu/g). Besides, the formation of networking between the formed AgNPs and β-CD through hydrogen bonding prevented the agglomeration of AgNPs, ensuring their high catalytic ability. The leaching study showed that the dissolution of Fe and Ag from Ag/Fe3O4@GO was negligible, indicating the environmental friendliness of the synthesized catalyst. Finally, the high catalytic performance, excellent stability, and recoverability of Ag/Fe3O4@GO make it a potential candidate for the reduction of organic pollutants in wastewater.Pakistan's agricultural productivity is considered to be low despite several agriculture promotion policies. Such policies concentrate primarily on on-farm development and overlook rich prospects for off-farm diversification. Livelihood diversification of small-scale farmers plays a major role in reducing hunger and mitigating the adverse impacts of climate change. Therefore, this paper seeks to analyze livelihood diversification in managing catastrophic risks among rural farm households of Khyber Pakhtunkhwa Province of Pakistan. We have interviewed a total of 600 farm households through a standardized questionnaire in two districts (Nowshera and Charsadda) of Khyber Pakhtunkhwa Province of Pakistan that were badly affected by the 2010 flood. For empirical analysis, a logistic regression model was chosen to analyze the important attributes that are correlated to livelihood diversification of the rural households in flood-susceptible areas of Pakistan. The survey findings indicate that 50% of the total samplermers could only improve if the Government pays due consideration and adopts the right policy initiatives that promote the diversification of livelihoods as part of the creation of national jobs to save many lives and improve livelihoods.In recent decades, anthropogenic activities have resulted in road dust and roadside soil hosted metal(oid)s pollution in the urban environment. In the South-Asian megacity "Dhaka", schools are situated in the areas with high population density and high traffic emissions. As the school-going children are the most vulnerable receptor, school premises in Dhaka city represent an important yet overlooked exposure point to contaminated dust and soil. Eflornithine Therefore, the present study investigated the metal(oid)s (Cu, Pb, Zn and As) pollution in dust and soil at school compounds, explored their possible sources and estimated the associated human health risk. This study revealed that dust contained higher concentration of metal(oid)s than soil, and the Azimpur Govt. Girls School & College was identified as the most contaminated site. The enrichment of school dust with Cu, Zn and Pb were strictly related to the dense population and substantial traffic activity in the study areas. Arsenic content in school soil was several folds higher than its concentration in the upper crust. Natural and anthropogenic activities possibly posed a synergistic effect on such high soil As. The multivariate statistics suggested that Cu, Zn and Pb were likely to be originated from traffic-related activities, while Zr, Fe, Ti and Rb from natural sources, and K, Sr and Ca from industrial activities. The assessment of health risk suggested the children as a vulnerable receptor and ingestion was identified as the dominant pathway of dust and soil exposure. The hazard index (HI) values were lower than unity, suggesting no possible non-cancer health risk. Arsenic posed a lifetime carcinogenic risk to the population in the study area through soil ingestion and dermal adsorption.The Cu(II) metal-organic frameworks (MOFs) based on 1,3,5-benzenetricarboxylic acid (Cu3(BTC)2) was synthesized by the hydrothermal method. The synthesized Cu3(BTC)2 exhibited pyramid-shaped morphology and showing an average specific area of 32.16 m2 g-1. The Cu3(BTC)2 photocatalysts were characterized using Fourier-transform infrared spectroscopy (FTIR), powder X-ray diffraction (PXRD), field emission scanning electron microscopy-energy-dispersive X-ray spectroscopy (FESEM-EDX), UV-Vis diffusive reflectance spectra, and Brunauer-Emmett-Teller (BET). The photocatalytic activity of Cu3(BTC)2 was examined on Rhodamine B (RhB) degradation under visible light irradiation. The outcomes displayed exceedingly enhanced photocatalytic activity under visible light. In addition, its recyclability was also confirmed for multiple cycles. The easiness of construction and high photocatalytic performance of Cu3(BTC)2 photocatalysts can be capable in environmental applications to treat water contamination.
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