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Bioactive ingredients, organic task, and also starchy foods digestibility regarding dried up soya remains in the soybean gas industry and the effects of hot-air dehydrating.
The Hb200 hybrid maintained excellent catalytic activity during reuse in 3 cycles, with only 10% lower mineralization efficiency in the last cycle. GC-MS analysis showed that most of the contaminants in the effluent, including bis(2-ethylhexyl) phthalate, one of the most toxic, were eliminated or transformed after the EF treatment with Hb200.β-Cyclodextrin (β-CD) is an inexpensive and reproducible material derived from corn starch. It is possible that tetrafluoroterephthalonitrile-crosslinked β-cyclodextrin polymer (TFN-CD), a cheap but efficient adsorbent, could be a suitable binding agent for use in the passive sampling technique, diffusive gradients in thin-films (DGT). Herein, the TFN-CD binding gel was prepared and then evaluated as the binding phase of DGT to sample six endocrine disrupting chemicals (EDCs) in water. The TFN-CD dispersed uniformly in the binding gel due to its hydrophilicity. The quantitative recoveries (99.3%-106%) of EDCs from the TFN-CD binding gel could be conveniently achieved by ultrasonic extraction using 5 mL methanol for 10 min. Compared with the excellent HLB (hydrophilic-lipophilic-balanced resin) binding gel, the TFN-CD binding gel had comparable or even faster adsorption kinetics, although the equilibrium adsorption capacity was slightly lower. GSK2830371 cost The effective adsorption capacities of TFN-CD-based DGT (TFN-CD-DGT) were roughly estimated to enable a 7-days deployment in EDC solution of 25.7-30.0 μg L-1. Studies of influencing factors showed that the ionic strength (0-0.5 M), pH (3.73-9.13), dissolved organic matter (0-20 mg L-1) and long-term storage (204 days) had negligible influence on the performance of TFN-CD-DGT. Finally, the TFN-CD-DGT was successfully used to record sudden increases in bulk concentrations during simulated discharge events in pond water. These results demonstrate that TFN-CD is a suitable binding agent for sampling of EDCs, and the low cost of TFN-CD could be conducive to the application of DGT in large-scale sampling.Cd and As are difficult to co-remediate in co-contaminated soils. In this study, remediation materials comprising large-grained and nano-sized biochar (BC), ferrihydrite (FH), and complexes thereof were added to Cd- and As-contaminated soil. The uptake of Cd and As by pak choi (Brassica chinensis L.) was then evaluated using a pot experiment and the Cd and As concentrations of the soil pore water and leaching water were measured. The Cd and As concentrations of the pore and leaching water were slightly increased with the addition of BC, and decreased with addition of FH and the biochar-ferrihydrite complex (BC-FH). However, nano-sized BC (BCN), FH (FHN), and BC-FH (BC-FHN) had little influence on the decreases in Cd and As of the two monitored water types. Large-grained remediation materials, rather than nanomaterials, decreased the Cd and As concentrations of the two monitored water types. Nonetheless, nanomaterial treatments more effectively decreased the Cd and As concentrations in plants by an average of >10% relative to the large-grained treatments. The DLVO theory analysis suggested that BCN, FHN, and BC-FHN, immobilized in the topsoil, adsorbed heavy metals in the rhizosphere soil. The remainder of the nano-sized materials was dispersed in the rhizosphere soil pores, shielding the uptake of Cd and As by the roots. Although the doses of nanomaterials used in this study were less than one-fortieth of those of the large-grained materials, changes in the plant rhizosphere microenvironment caused by the nanomaterials decreased the risk of toxicity transfer from the soil to the plants.Wastewater containing 2,4,6-trichlorophenol (2,4,6-TCP) is highly toxic and causes harmful effects on aquatic ecosystems and human health. In this study, wastewater containing high levels of 2,4,6-TCP was successfully co-metabolized by introducing municipal domestic wastewater (MDW) as the co-catabolic carbon source. The concentration of degraded 2,4,6-TCP increased from 0 to 208.71 mg/L by adjusting the influent MDW volume during a 150-day-long operation. An MDW dose of 500 mL was found optimal, with an average concentration of 250 mgCOD/L. Unlike the long-term experiment, changing the MDW adding mode in a typical cycle further increased the concentration of 2,4,6-TCP removed to 317 mg/L. The main MDW components, such as the sugars, VFAs, and slowly biodegradable organic substances, improved 2,4,6-TCP degradation, achieving a TOC removal efficiency of 90.98% and a dechlorination efficiency of 100%. The MDW level did not change the 2,4,6-TCP degradation rate (μTCP) in a typical cycle compared to the single carbon source, and the μTCP remained at a high level of 50 mg 2,4,6-TCP/h. Macrogenetic analysis demonstrated that MDW addition promoted the growth of 43 bacterial genera (41.49%) responsible for 2,4,6-TCP degradation and intermediates' metabolism. The key genes for 2,4,6-TCP metabolism (pcpA, chqB, mal-r, pcaI, pcaF, and fadA) were detected in the activated sludge, which were distributed among the 43 genera. To conclude, this study proposes a new carbon source for co-metabolism to treat 2,4,6-TCP-polluted wastewater.Manganese dioxide (MnO2) is a Mn deposit widely accumulated in the corrosion layer of pipelines, and iodide (I-) is a halogen ion frequently detected in waters. The biofilm dwelling on the corrosion scales often secretes extracellular polymeric substances (EPS) into drinking water. The paper aimed to study the I- oxidation by MnO2 and iodinated disinfection byproducts (I-DBPs) formation with biofilm EPS as a precursor. More than 93% of formed free iodine was finally converted into organic iodine in the MnO2/I-/EPS system. Compared with humic acid, EPS had a lower carbonaceous I-DBPs (C-IDBPs) formation while a higher nitrogenous I-DBPs (N-IDBPs) formation. The formation of iodomethanes (I-THMs), iodoacetonitriles (I-HANs) and iodoacetic acids (I-HAAs) decreased with the increase of pH due to the weakening of polarization effect and redox potential, while the iodoacetamides (I-HAcAms) formation achieved the maximum at pH 6.0 due to the difference between the hydrolysis rate of I-HANs and decomposition rate of I-HAcAms.
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