Notes

Coupling of decreased compacted snow piling up and improved light-absorbing debris boosts glacier retire within the Tibetan Level of skill.
ots, as evidenced by increased Rhodamine 123 (Rhd 123) and Evan's blue fluorescence, respectively. These findings clearly showed that applying pesticides in excess of permissible amounts might induce oxidative stress and cause oxidative damage in non-target host plants. Overall, the current study indicates that a thorough and secure method be used before selecting pesticides for increasing production of agronomically important vegetable crops in various agro-climatic zones.In this research, we have investigated a novel magnetic nanocomposite including NiFe2O4@MIL-101(Fe)/GO for the delivery of the antibiotic tetracycline (TC). Moreover, the antibacterial activity of NiFe2O4@MIL-101(Fe)/GO, NiFe2O4@MIL-101(Fe)/GO/TC and pure TC was evaluated by agar well diffusion and minimum inhibitory concentration (MIC) methods on both Gram-negative (Escherichia coli) and Gram-positive (Staphylococcus aureus) bacteria. In addition, the cytotoxicity of NiFe2O4@MIL-101(Fe)/GO/TC on HeLa cells was determined by an MTT assay which showed good results. The structure of the prepared nanocarrier was investigated by various spectroscopic techniques such as Fourier-transform infrared spectroscopy (FT-IR), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), Brunauer-Emmett-Teller (BET), and thermal gravimetric analysis (TGA). The results of this study showed that 98% of the TC was loaded on the synthesized nanocomposite. Drug release occurred at pH 7.4 (phosphate buffer saline) and pH 5.0 (acetate buffer) within 3 days, resulting in 77% and 85% release of the drug, respectively.A new Na3Y(VO4)2Eu3+ (NYVOEu3+) phosphor was prepared using the sol-gel method. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to evaluate phase purity and particle size, respectively. The optical properties were investigated by UV-visible absorption, PL, and PLE spectroscopies. The absorption measurements show the formation of the vanadate host by the presence of its characteristic band in the visible region related to VO4 3- groups. The experimental results show that the NYVOEu3+ phosphors exhibit high-brightness and thermally stable emission. Under near-ultraviolet (UV) excitation, both the broadband emission from VO4 3- groups and the sharp peak emissions from Eu3+ ions are observed. The highest luminescence intensity was achieved for an optimal europium concentration of 15 mol%. The study of the chromaticity parameters of these compounds gives a thermally stable hot emission in the red domain, with a color purity of about 85%, which qualifies the NYVOEu3+ compound as a potential phosphor for light-emitting diode (LED) applications. Thermal sensing using NYVOEu3+ phosphors are based on monitoring the luminescence intensity ratio between the NYVO host emission and Eu3+ luminescence lines. Notably, the optical thermometry of NYVOEu3+ was characterized based on the fluorescence intensity ratio of VO4 3- and Eu3+ emissions in the 298-440 K range, with maximum absolute and relative sensitivities of 3.4% K-1 and 0.0032 K-1 respectively and a temperature uncertainty of 0.01. NYVOEu3+ can then be considered as a potential red phosphor for application in ultraviolet-pumped white light-emitting diodes and as a potential optical thermometer. It provides new possibilities for the design of multifunctional materials for red light-emitting diodes and for non-contact thermometry.In this work, we correlate the microstructure and passivation of the Al95-x Ni x Y5 lightweight glassy ribbons (x = 7 and 10) using various techniques. The overdosed Ni (x = 10) can increase the melt viscosity and then deteriorate its glass-forming ability (GFA), ribbon formability, and Y-depleted extra layer formation. Consequently, the overdosed Ni weakens the passivation stability and corrosion resistance of the as-spun ribbon. The key role of the overdosed Ni can form a strong network and crystalline grain boundary in the amorphous matrix, which can transport Y and O to participate in the oxidation. These results can help us explore a valuable method for designing new Al-based metallic glasses.We have succeeded in synthesizing meso-porous α-Ga2O3 which shows significantly high photocatalytic activity for CO2 reduction with water. The sample was synthesized by hydroxidation of liquid Ga metal in water to obtain GaOOH and Ga(OH)3, followed by the calcination of the mixed hydroxides at 773 K for 1 hour which converted them to meso-porous α-Ga2O3. The nano-pores remained as the trace of the evaporation of water produced by the oxidation of the hydroxides during the calcination. The photocatalytic activity of the synthesized meso-porous α-Ga2O3 for CO2 reduction with water was as high as or higher than previous studies using various types of Ga2O3 with and without cocatalysts.Lead (Pb) free metal halide perovskites by atomistic design are of strong interest to photovoltaics and optoelectronics industries because of the pressing need to resolve Pb-related toxicity and instability challenges. In this study, structural, mechanical, electronic, and optical properties of Pb-free RbSnX3 (X = Cl, Br, I) perovskites have been evaluated by using ab initio density functional theory (DFT) calculations. RHPS 4 nmr The computed elastic constants suggest that the Rb-based halide perovskites are mechanically stable and highly ductile, making them suitable as flexible thin films in optoelectronic devices. Besides, the investigated electronic band structures reveal that the RbSnX3 compounds are direct bandgap semiconductors, suitable for photovoltaic and optoelectronic applications. Furthermore, several optical parameters such as dielectric functions, reflectivity, photon absorptions, refractive index, optical conductivity, and loss functions have been investigated and the results predict the excellent optoelectronic efficiency of RbSnX3. Also, the computed mechanical and optical properties of RbSnX3 (X = Cl, Br, I) have been compared with the previously studied CsBX3 (B = Ge, Sn, Pb; X = Cl, Br, I) phases, revealing that the Rb-based perovskites are extremely ductile and possess excellent light absorption and optical conductivity compared to the Cs-based perovskites. Importantly, RbSnI3 shows superior ductility, absorption coefficient, and optical conductivity compared to the CsBX3 (B = Ge, Sn, Pb; X = Cl, Br, I) perovskites. Superior absorption at the ultraviolet region of RbSnI3 holds great promise of this perovskite to be used in next-generation ultraviolet photodetectors.Corrosion behavior of 304 stainless steel in molten NaNO3-NaCl-NaF salt and NaNO3-NaCl-NaF vapor has been studied at 450 °C. The results showed that the samples suffered weight loss, and surface oxides, i.e. Fe2O3 and FeCr2O4 characterized by XRD, were formed after corrosion. The surface oxide layer was about 1.1 μm in thickness after corrosion in molten NaNO3-NaCl-NaF salt, which was relatively homogeneous and dense. Whereas, the distribution of surface oxides was not even, and a shedding phenomenon was observed after corrosion molten NaNO3-NaCl-NaF vapor. This is mainly attributed to the existence of NO2 and NO in the molten NaNO3-NaCl-NaF vapor determined by thermogravimetric infrared spectroscopy, which affected the adherence between oxides and the matrix. Additionally, the corrosion rate of 304 stainless steel in molten NaNO3-NaCl-NaF salt is almost close to that in solar salt, which demonstrates that the synergy influence of Cl- and F- on the rate of 304 stainless steel is not significant. This work not only enriches the database of molten salt corrosion, but provides references for the selection of alloy and molten salt in the CSP.Boosting technological innovation for a sustainable and circular bioeconomy encompasses the use of renewable materials and development of highly effective biotechnological approaches to improve the quality of oilseed crops and facilitate their industrial deployment. The interest in cultivating Crambe as a potential crop is steadily growing due to its low propensity to crossbreeding with other oilseed crops, valuable seed oil composition and a high yield capacity. The main focus is located on Crambe abyssinica as the most adapted into the agriculture and well-studied Crambe species. At the same time, the Crambe genus is one of the most numerous of the Brassicaceae family featuring several underestimated (orphaned) species with useful traits (abiotic stress tolerance, wide range of practical applications). This review features progress in the biotechnological improvement of well-adapted and wild Crambe species starting with aseptic culture establishment and plant propagation in vitro reinforced with the use of genetic engineering and breeding techniques. The aim of the paper is to highlight and review the existing biotechnological methods of both underestimated and well-adapted Crambe species improvment, including the establishment of aseptic culture, in vitro cultivation, plant regeneration and genetic transformation to modify seed oil content and morphological traits of valuable species.The prevention of grain storage pests is a universal concern all over the world. It is in high demand to explore novel, safe and green insecticidal techniques to address such concerns. In this work, both raw and calcined diatomite were used as a natural insecticide to remove common grain storage pests with improved lethal effect on the saw-toothed grain beetle. Interestingly, the raw diatomite showed higher insecticidal efficiency than the calcined diatomite, and its associated insecticidal properties and preparation conditions were also optimized through orthogonal tests. The optimal conditions for processing the raw diatomite insecticide were identified as follows the diatomite dust was 500 mesh (A 3), the temperature was 25 °C (B 1), the relative humidity was 65% (C 2), the diatomite dosage was 20 g m-2 (D 2), the influence factor order was C ≥ D > A > B. The observation of surface morphology indicated that the raw diatomite had a complete, multi hole surface morphology and good adsorption performance, whereas the structure of the calcined diatomite was uncomplete with collapsed pores, resulting in poor adsorption performance. The special pore structure and excellent adsorption capacity of diatomite make the stored grain pests lose water to lethal effect. Acute toxicity and long-term toxicity tests in mice showed that diatomite has no harmful effects on mammals. The findings from our work led to a green and effective approach in producing a highly efficient and safe storage grain insecticide.Multidrug-resistant (MDR) Gram-negative bacteria including Escherichia coli are increasingly resistant to current antibiotics. Among the strategies implemented to eradicate such MDR pathogens, approaches based on two-dimensional (2D) nanomaterials have received considerable attention. In particular, the excellent physicochemical properties of 2D molybdenum disulfide (MoS2) nanosheets, including a high surface area, good conductivity, and good surface retention, are advantageous for their use as bactericidal agents. Herein, we report the fabrication of a MoS2-based nanocomposite conjugated with silver-doped zinc oxide (AZM) as an effective antibacterial agent against E. coli species. The properties of AZM were characterized, and its antibacterial activity against MDR E. coli strains with different resistance types was evaluated. MoS2 was found to activate the antibacterial activity of AZM and provide enhanced selectivity against MDR E. coli strains expressing β-lactamases. We proposed that membrane disruption of bacterial cell walls was the major cell death mechanism for MDR E.
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