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Effect of infection about ejaculate good quality and Genetics fragmentation in subfertile males with Leukocytospermia.
Captan is one of the most widely used organochlorine fungicides, its frequent application contaminates both terrestrial and aquatic ecosystems and negatively affects their key ecological processes. This study demonstrated the toxicity and efficient removal of captan by two different taxonomic species; the green microalga Scenedesmus obliquus and cyanobacterium Nostoc muscorum. After a week of exposure to mild (15 mg/L) and severe (30 mg/L) captan doses, the intracellular captan uptake, degradation and metabolic regulation of captan detoxification were studied. Compared to N. muscorum, S. obliquus accumulated more captan, but efficiently degraded it into two safe eco-friendly by-products; phthalic acid and 1,2,3,6-tetrahydro phthalimide. S. obliquus showed less decrease in cell growth, photosynthesis activity and related parameters including Chla content and activity of PEPC and RuBisCo enzymes. Captan at the severe dose induced oxidative damage particularly in N. muscorum, as expressed by the high levels of H2O2, MDA, NADPH oxidase and protein peroxidation. Both species invested glutathione-s-transferase enzyme in captan detoxification however, induction of antioxidant defence system e.g. ascorbate and glutathione cycle was more pronounced in S. obliquus which could explain its tolerance ability. This study provided a better understanding of the environmental risks of captan and introduced S. obliquus as a promising captan phycoremediator.The detection of mercury, one of the ten most dangerous chemicals, is significant to provide helpful information for assessing mercury toxicity and health risks. However, it is a challenge to explore simple, sensitive, accurate, and cheap Hg2+ detection methods. Noble metal nanomaterials are used for Hg2+ detection by the colorimetric method widely. Still, the pure noble metal materials' detection limit of Hg2+ is high, and sensitivity enhancement usually requires further complex modification. Here, we use a facile one-step route to synthesize ultra-thin two-dimensional palladium nanosheets (PdNS), which have high selectivity and sensitivity for Hg2+ detection by colorimetric method with a low detection limit (0.55 ppb). The detection of Hg2+ by PdNS involves multiple mechanisms, including the formation of amalgam and PdO to improve the peroxidase-mimic activity of PdNS and PdNS motor function to increase its collision probability with the detection reactant. The PdNS can be used to detect Hg2+ in various actual samples. The detection results are highly consistent with the data obtained by the atomic fluorescence spectrometer (AFS). Then, we developed a Hg2+ detection kit, which can realize simple, sensitive, and accurate Hg2+ detection by naked eye or cellphone at a meager cost (0.3 dollars each sample).Highly-efficient separation of adsorbent and pollutant from chemical sludge is urgent for the recycled materials and chemical resources and minimization of sludge production in industry. Herein, an effortless and cost-efficient salt/water system is developed for efficient zwitterionic polymer/dye separation from chemical sludge. To achieve this aim, a novel salt-tolerant zwitterionic polymer (STZP) is synthesized through etherifying 2-chloro-4,6-bis(4-carboxyphenyl amino)-1,3,5-triazine onto corn starch. It is found that "all-surface-area" adsorption of dye can be achieved by in-situ sol-gel transition of STZP. Spent polymer fluid and solid-state dye can be easily regenerated and separated from sewage sludge by a simple salt/water system. At a high NaCl concentration (225 g/L), the separation factor between zwitterionic polymer and dye is up to 50.4, which is 50 times larger than that of salt-free solution. More importantly, the regenerated polymer fluids exhibit an outstanding reusability ability and can maintain over 92.8% decoloration efficiency for dyeing effluent after multiple adsorption-desorption cycles. This study thus provides a technically feasible and economically acceptable strategy for the recycling and reuse of polymer from hazardous textile sludge waste, greatly promising to achieve zero emissions toward conventional adsorption units.Polyvinyl chloride (PVC) is one of the most commonly used plastics. The treatment and recycling of PVC waste is still challenging, due to its non-biodegradability, low thermal stability, high Cl content and low product value. In this study, a one-pot method was developed to upcycle PVC into valuable carbon materials, pipeline-quality pyrolysis gas and chlorides. The well-designed process included dechlorination by Cl-fixative (ZnO or KOH), carbonization of dechlorinated polyenes, and modification of carbon materials in sequence. ZnO and KOH converted 84.48% and 94.15% of total Cl into corresponding chlorides, respectively. CH4 and H2 accounted for 81.87-99.34 vol% of pyrolysis gas with higher heat values of 30.11-32.84 MJ m-3, which can be used as substitute natural gas. As high as 83.13% of the C element was converted into carbon materials. The morphology, structure and property of carbon materials can be modified by different Cl-fixatives. Millimeter-scale carbon spheres with mono-dispersity and porous carbon with a high specific surface area of 1922 m2 g-1 were obtained when ZnO and KOH were added, respectively. Moreover, the reaction mechanisms of PVC with Cl-fixatives were also deciphered through thermogravimetric analysis and thermodynamic simulation.Land-based seawater aquaculture accompanied by high stocking density usually involves producing excess eutrophic nutrients, residual baits, excrement, and antibiotics. Because of limited technology and salinity, proper and efficient treatment of these wastes is still an unsolved issue. In this study, the feasibility of maricultural fish residual bait and excrement-derived biochar as water pollutant remover and saline-alkaline soil amendment were firstly assessed. The biochar was pyrolyzed at 300, 500, 700, 800, 900 ℃ (marked as BC300, BC500, BC700, BC800, BC900) and modified by zirconium or iron (BC700-Zr or BC700-Fe). BC700-Zr had the highest specific surface area. BC700-Zr and BC700-Fe exhibited higher nitrogen removal efficiency. The biochars exhibited nitrogen and phosphate desorption, while we observed no obvious phosphate desorption in BC700-Zr or BC700-Fe. Adsorption kinetics analysis indicated that adsorption processes of nitrate, nitrite and enrofloxacin were consistent with pseudo-second-order model, while ammonium and phosphate adsorption processes fitted pseudo-first-order model better. The biochar showed nitrogen and phosphate nutrients release effects, indicating potential application in saline-alkaline soil improvement. Multi-linear regression analysis indicated that nitrogen release was closely related to biochar nitrogen content, pH and average pore width. Phosphate release was inversely related to pH and positively related to average pore width.Oil refining waste (ORW) contains complex, hazardous, and refractory components, causing more severe long-term environmental pollution than petroleum. Here, ORW was used to simulate the accelerated domestication of bacteria from oily sludges and polymer-flooding wastewater, and the effects of key factors, oxygen and temperature, on the ORW degradation were evaluated. Bacterial communities acclimated respectively in 30/60 °C, aerobic/anaerobic conditions showed differentiated degradation rates of ORW, ranging from 5% to 34%. High-throughput amplicon sequencing and ORW component analysis revealed significant correlation between bacterial diversity/biomass and degradation efficiency/substrate preference. Under mesophilic and oxygen-rich condition, the high biomass and abundant biodiversity with diverse genes and pathways for petroleum hydrocarbons degradation, effectively promoted the rapid and multi-component degradation of ORW. While under harsh conditions, a few dominant genera still contributed to ORW degradation, although the biodiversity was severely restricted. The typical dominant facultative anaerobes Bacillus (up to 99.8% abundance anaerobically) and Geobacillus (up to 99.9% abundance aerobically and anaerobically) showed oxygen-independent sustainable degradation ability and broad-spectrum of temperature adaptability, making them promising and competitive bioremediation candidates for future application. Our findings provide important strategies for practical bioremediation of varied environments polluted by hazardous ORW.Owing to the widespread prevalence and ecotoxicity of bisphenol alternatives such as bisphenol S, bisphenol F, and bisphenol AF, the past decade has witnessed the publication of a remarkable number of studies related to their transformation and remediation in natural waters. However, the reactivity, removal efficiency, transformation products (TPs), and mechanisms of such emerging pollutants by different treatment processes have not been well elucidated. Particularly, the transformation-driven environmental risks have been mostly overlooked. Therefore, we present a review to address these issues from chemical and toxicological viewpoints. Four degradation systems can be largely classified as catalytic persulfate (PS) oxidation, non-catalytic oxidation, photolysis and photocatalysis, and biodegradation. It was found that bisphenol alternatives possess distinct reactivities with different oxidizing species, with the highest performance for hydroxyl radicals. Panobinostat cost All systems exhibit superior elimination efficiency for these compounds. The inadequate mineralization suggests the formation of recalcitrant TPs, from which the overall reaction pathways are proposed. The combined experimental and in silico analysis indicates that many TPs have developmental toxicity, endocrine-disrupting effects, and genotoxicity. Notably, catalytic PS systems and non-catalytic oxidation result in the formation of coupling products as well as halogenated TPs with higher acute and chronic toxicity and lower biodegradability than the parent compounds. In contrast, photolysis and photocatalysis generate hydroxylated and bond-cleavage TPs with less toxicity. Overall, this review highlights the secondary environmental risks from the transformation of bisphenol alternatives by conventional and emerging treatment processes. Finally, future perspectives are recommended to address the knowledge gaps of these contaminants in aquatic ecosystems.Tetramethylammonium hydroxide (TMAH) is a toxic photoresist developer used in the photolithography process in thin-film transistor liquid crystal display (TFT-LCD) production, and it can be removed through anaerobic treatment. TMAH cannot be released into the environment because of its higher toxicity. A tight membrane, such as a forward osmosis (FO) membrane, together with an anaerobic biological process can ensure that no TMAH is released into the environment. Thus, for the first time, an anaerobic osmotic membrane bioreactor (AnOMBR) hybrid system was developed in this study to treat a low-strength TMAH wastewater and to simultaneously investigate its microbial community. Microfiltration extraction was used to mitigate the salinity accumulation, and a periodically physical water cleaning was utilized to mitigate the FO membrane fouling. The diluted draw solute (MgSO4) was reconcentrated and reused by a membrane distillation (MD) process in the AnOMBR to achieve 99.99% TMAH removal in this AnOMBR-MD hybrid system, thereby ensuring that no TMAH is released into the natural environment.
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