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An organized evaluate to compare substance threat forecasts with the zebrafish embryotoxicity examination together with mammalian pre-natal developmental toxic body.
In brief, these in situ formed hydrogels with brilliant structural colors have potential in optical applications, e.g., color displays, crystal immobilization, and biological applications, e.g., 3D cell culture and drug delivery.Thin passivating surface oxide layers on metal alloys form a dissipation horizon between dissimilar phases, hence harbour an inherent free energy and composition gradient. We exploit this gradient to drive order and selective surface separation (speciation), enabling redox-driven enrichment of the core by selective conversion of low standard reduction potential (E°) components into oxides. Coupling this oxide growth to volumetric changes during solidification allows us to create oxide crystallites trapped in a metal ('ship-in-a-bottle') or extrusion of metal fingerlings on the heavily oxidized particle. We confirm the underlying mechanism through high temperature X-ray diffraction and characterization of solidification-trapped particle states. We demonstrate that engineering the passivating surface oxide can lead to purification via selective dealloying with concomitant enrichment of the core, leading to disparate particle morphologies.Nanoscale manipulation of material surfaces can create extraordinary properties, holding great potential for modulating the implant-bio interface for enhanced performance. In this study, a green, simple and biocompatible nanosurfacing approach based on weak alkalinity-activated solid-state dewetting (AAD) was for the first time developed to nano-manipulate the Ti6Al4V surface by atomic self-rearrangement. AAD treatment generated quasi-periodic titanium oxide nanopimples with high surface energy. The nanopimple-like nanostructures enhanced the osteogenic activity of osteoblasts, facilitated M2 polarization of macrophages, and modulated the cross-talk between osteoblasts and macrophages, which collectively led to significant strengthening of in vivo bone-implant interfacial bonding. In addition, the titanium oxide nanopimples strongly adhered to the Ti alloy, showing resistance to tribocorrosion damage. The results suggest strong nano-bio interfacial effects, which was not seen for the control Ti alloy processed through traditional thermal oxidation. Compared to other nanostructuring strategies, the AAD technique shows great potential to integrate high-performance, functionality, practicality and scalability for surface modification of medical implants.Owing to its advantages of freedom to design, improved material utilization, and shortened lead time, additive manufacturing (AM) has the potential to redefine manufacturing after years of evolvement and opens new avenues to produce customized and complex-shaped products. Despite these benefits, AM still suffers problems stemmed from limited material selection, anisotropic material property, low production speed, coarse resolution, etc. In response to these problems, extensive attention has been drawn on integrating AM with fields, which mainly include magnetic field (MF), electric field (EF), and acoustic field (AF). These fields have been proved to be effective in tailoring microstructures, enhancing mechanical properties, focusing and sorting cells, serving as stimuli, etc., thus providing new opportunities to address existing problems and enable new functionalities of AM technologies. This paper presents a review on recent developments and major advances in MF-, EF-, and AF-assisted AM technologies and 4D printing method from aspects of materials, methodologies, and applications. In addition, current challenges and future trends of field-assisted AM technologies and 4D printing method are also outlined and discussed.Self-assembled oxide-metal nanocomposite thin films have aroused great research interest owing to their wide range of functionalities, including metamaterials with plasmonic and hyperbolic optical properties, and ferromagnetic, ferroelectric and multiferroic behaviors. Oxide-metal nanocomposites typically self-assemble as metal particles in an oxide matrix or as a vertically aligned nanocomposite (VAN) with metal nanopillars embedded in an oxide matrix. Among them, the VAN architecture is particularly interesting due to the vertical strain control and highly anisotropic structure, enabling the epitaxial growth of materials with large lattice mismatch. In this review, the driving forces behind the formation of self-assembled oxide-metal VAN structures are discussed. Specifically, an updated in-plane strain compensation model based on the areal strain compensation concept has been proposed in this review, inspired by the prior linear strain compensation model. It provides a guideline for material selection for designing VAN systems, especially those involving complex orientation matching relationships. Based on the model, several case studies are discussed, comparing the microstructure and morphology of different oxide-metal nanocomposites by varying the oxide phase. Specific examples highlighting the coupling between the electrical, magnetic and optical properties are also discussed in the context of oxide-metal nanocomposites. Future research directions and needs are also discussed.Improvements in computing performance have significantly slowed down over the past few years owing to the intrinsic limitations of computing hardware. However, the demand for data computing has increased exponentially. To solve this problem, tremendous attention has been focused on the continuous scaling of Moore's law as well as the advanced non-von Neumann computing architecture. A rich variety of unconventional computing paradigms has been devised with the rapid development of nanoscale devices. Magnetic skyrmions, spin swirling quasiparticles, have been endowed with great expectations for unconventional computing due to their potential as the smallest information carriers by exploiting their physics and dynamics. In this paper, we provide an overview of the recent progress of skyrmion-based unconventional computing from a joint device-application perspective. This paper aims to build up a panoramic picture, analyze the remaining challenges, and most importantly to shed light on the outlook of skyrmion based unconventional computing for interdisciplinary researchers.Beyond current lithium-ion technologies, magnesium-sulfur (Mg-S) batteries represent one of the most attractive battery chemistries that utilize low cost, sustainable, and high capacity materials. In addition to high gravimetric and volumetric energy densities, Mg-S batteries also enable safer operation due to the lower propensity for magnesium dendrite growth compared to lithium. However, the development of practical Mg-S batteries remains challenging. Major problems such as self-discharge, rapid capacity loss, magnesium anode passivation, and low sulfur cathode utilization still plague these batteries, necessitating advanced material design strategies for the cathode, anode, and electrolyte. This review critically appraises the latest research and design principles to address specific issues in state-of-the-art Mg-S batteries. read more In the process, we point out current limitations and open-ended questions, and propose future research directions for practical realization of Mg-S batteries and beyond.Increasing demand for portable and flexible electronic devices requires seamless integration of the energy storage system with other electronic components. This ever-growing area has urged on the rapid development of new electroactive materials that not only possess excellent electrochemical properties but hold capabilities to be fabricated to desired shapes. Ideally, these new materials should have minimal impact on the environment at the end of their life. Nitroxide radical polymers (NRPs) with their remarkable electrochemical and physical properties stand out from diverse organic redox systems and have attracted tremendous attention for their identified applications in plastic energy storage and organic devices. In this review, we present a comprehensive summary of NRPs with respect to the fundamental electrochemical properties, design principles and fabrication methods for different types of energy storage systems and organic electronic devices. While highlighting some exciting progress on charge transfer theory and emerging applications, we end up with a discussion on the challenges and opportunities regarding the future directions of this field.Water scarcity has become an increasingly complex challenge with the growth of the global population, economic expansion, and climate change, highlighting the demand for advanced water treatment technologies that can provide clean water in a scalable, reliable, affordable, and sustainable manner. Recent advancements on 2D nanomaterials (2DM) open a new pathway for addressing the grand challenge of water treatment owing to their unique structures and superior properties. Emerging 2D nanostructures such as graphene, MoS2, MXene, h-BN, g-C3N4, and black phosphorus have demonstrated an unprecedented surface-to-volume ratio, which promises ultralow material use, ultrafast processing time, and ultrahigh treatment efficiency for water cleaning/monitoring. In this review, we provide a state-of-the-art account on engineered 2D nanomaterials and their applications in emerging water technologies, involving separation, adsorption, photocatalysis, and pollutant detection. The fundamental design strategies of 2DM are discussed with emphasis on their physicochemical properties, underlying mechanism and targeted applications in different scenarios. This review concludes with a perspective on the pressing challenges and emerging opportunities in 2DM-enabled wastewater treatment and water-quality monitoring. This review can help to elaborate the structure-processing-property relationship of 2DM, and aims to guide the design of next-generation 2DM systems for the development of selective, multifunctional, programmable, and even intelligent water technologies. The global significance of clean water for future generations sheds new light and much inspiration in this rising field to enhance the efficiency and affordability of water treatment and secure a global water supply in a growing portion of the world.Soft robots that can move like living organisms and adapt to their surroundings are currently in the limelight from fundamental studies to technological applications, due to their advances in material flexibility, human-friendly interaction, and biological adaptation that surpass conventional rigid machines. Light-fueled smart actuators based on responsive soft materials are considered to be one of the most promising candidates to promote the field of untethered soft robotics, thereby attracting considerable attention amongst materials scientists and microroboticists to investigate photomechanics, photoswitch, bioinspired design, and actuation realization. In this review, we discuss the recent state-of-the-art advances in light-driven bimorph soft actuators, with the focus on bilayer strategy, i.e., integration between photoactive and passive layers within a single material system. Bilayer structures can endow soft actuators with unprecedented features such as ultrasensitivity, programmability, superior compatibility, robustness, and sophistication in controllability.
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