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236U/238U atom ratios were detected in the range of (0.627-3.38) × 10-8. A weak correlation between anthropogenic 236U and natural U isotopes were observed. The intermediate correlation between 236U and 137Cs indicated somewhat distinct migration behavior of these two radionuclides in soil after release to the environment. The released amount of 236U from global fallout during the period of atmospheric nuclear weapons testing was roughly estimated to be 1300 ± 448 kg. These results could be used as fingerprint information for anthropogenic 236U migration behavior and tracer application in environment.Arsenic (As) and selenium (Se) pollution caused by coal combustion is receiving increasing concerns. The environmental impacts of As/Se are determined not only by stack emission but also by leaching process from combustion byproducts. For a better control of As/Se emission from As/Se-enriched coal combustion, this study investigated the migration and emission behavior of As/Se in a circulating fluidized bed (CFB) power plant equipped with fabric filter (FF) and wet flue gas desulfurization (WFGD) system. The results demonstrated that arsenic was both enriched in bottom ash (41.4-47.6%) and fly ash (52.4-58.6%), while selenium was mainly captured by fly ash (73.9-83.4%). Limestone injection into furnace promoted As/Se retention in ash residues. Arsenic was mainly converted into arsenate in high-temperature regions and partly trapped in bottom ash as arsenite. In contrast, selenium capture mainly occurred in low-temperature flue gas by the formation of selenite, because of the poor thermal stability of most selenite. Triplet-tank method can totally remove arsenic in WFGD wastewater. And 18.4-58.7% of selenium was removed, resulting from the precipitation of Se4+ anions with highly soluble Se6+ anions remaining in wastewater. The concentrations of As and Se in the stack emission were 0.25-1.02 and 0.96-2.24 μg/m3, receptively. The CFB boiler equipped with FF + WFGD was shown to provide good control of the As/Se emission into the atmosphere. Leaching tests suggested that more attention should be paid to As leachability from fly ash/gypsum, and Se leachability from gypsum/sludge.Oceanic processes such as coastal upwelling and mesoscale eddy, could influence the spatial distribution and environmental behaviors of semi-volatile organic pollutants in the marine environment. Seawater samples were collected from the full-depth water columns from the South China Sea (SCS), and PAH concentrations (∑14PAH) in the continental shelf and the open basin areas were 16-110 and 10-93 ng/L respectively. Results of isomeric ratios and principal component analysis illustrated PAHs' mixed sources (petrogenic and pyrogenic). PAH inventory of the SCS seawater was estimated as 100 ± 58 thousand tons, and the majority of them was stored in the intermediate and deep water masses. Generally, full-depth profiles of dissolved PAHs showed an "enrichment in surface and exhaustion in the deep" pattern, and this might be influenced by the oceanic processes such as coastal upwelling or eddy diffusion. In the cross-shelf area, upwelling could enhance the scavenging efficiency of PAHs on the upper layer, and increase the pollutant concentration in the medium and deep water. While in the open-basin area, PAHs were more likely influenced by the halocline stratification and eddy diffusion, and their vertical fluxes due to eddy diffusion was estimated to be 1.2 × 10-6 g s-1. This study highlighted the influences of oceanic processes in transport PAHs in the marginal sea, further study is needed to investigate their seasonal variations related to the monsoon characteristics.Neurotransmitters are endogenous metabolites that play a crucial role within an organism, at the chemical synapses. There is a growing interest in their analytical determination for understanding the neurotoxic effect of contaminants. Daphnia magna represents an excellent aquatic model for these environmental studies, due to its similarities with vertebrates in several neurotransmitters and related gene pathways and because of its wide application in ecotoxicological studies. Within this study, an accurate and sensible method of analysis of 17 neurotransmitters and related precursors and metabolites was developed. The method was validated in terms of sensitivity, reproducibility, precision, and accuracy, and also matrix effect was evaluated. As an independent probe of method validation and applicability, the method was applied to two different scenarios. First, it was used for the study of neurotransmitter levels in genetically mutated tryptophan hydrolase D. magna clones, confirming the absence of serotonin and its metabolite 5-HIAA. Additionally, the method was applied for determining the effects of chemical compounds known to affect different neurotransmitter systems and to alter Daphnia behavior. Significant changes were observed in 13 of the analyzed neurotransmitters across treatments, which were related to the neurotransmitter systems described as being affected by these neurochemicals. These two studies, which provide results on the ways in which the neurotransmitter systems in D. check details magna are affected, have corroborated the applicability of the presented method, of great importance due to the suitability of this organism for environmental neurotoxicity studies.This work develops a halophilic biocarriers-MBR for saline pharmaceutical wastewater treatment. The system has effectively treated the ampicillin-containing saline wastewater for 32 days, when the ampicillin concentration is lower than 20 mg/L. The system can tolerate the saline organic wastewater with a reasonable biodegradability (removals of COD over 75%) when the ampicillin concentration is 50 mg/L. The system has a bad performance in biodegradation (COD removals around 60-70%) and fouled within 16 days at a high ampicillin concentration of 100 mg/L. At high transmembrane pressures over 30 KPa, some ampicillin molecules may permeate through the membrane causing decreases in the ampicillin removal. The concentrations of protein and carbohydrate in EPS and SMP have increased over time and with increasing the ampicillin concentration. The method of biofouling control in MBR for the ampicillin situations has been proposed based on monitoring the concentrations of EPS and SMP. The drying-assisted monitoring of membrane biofoulants has showed a better efficiency than the monitoring of transmembrane pressure for membrane anti-biofouling in the treatment of pharmaceutical saline wastewaters where a spectroscopic detection can be hardly applied. This work may benefit relative research works for the control of biodegradation performance and membrane biofouling to better treat saline pharmaceutical wastewaters.Malathion is an organophosphorus insecticide and pesticide commonly used in crops and residential applications. The negative effects of Malathion on human health and ecosystems are of great concern. In this work, a mathematical model pivot on Fuzzy Cognitive Map (FCM) is used to analyse the causes and hazardous effects of Malathion to the environmental components (air, water and soil). Based on expert's opinion the possible factors that cause damage to health and ecosystems due to Malathion is identified, which serve as the input to the FCM. The FCM mathematically establishes the causal relation between these factors. The mathematical simulation is done by Python Programming. link2 This approach can be used to study the interdependencies between the adverse effects of any pesticide in human health and environment due to prolonged exposure.In addition to nitrogen, carbonyl compounds such as formaldehyde, acetaldehyde, isobutyraldehyde and crotonaldehyde can be released from slow release fertilizers based on urea-aldehyde by hydrolytic or biotic processes. A possible relevance of such releases in the practical application of corresponding products was investigated in laboratory experiments. In the first part, emissions of organic compounds from the pure products were determined in desiccators under static conditions in dry and water-saturated air as well as during direct contact with water. Significant emissions of isobutyraldehyde were found for products containing isobutylidene diurea. Several formulations emitted acetaldehyde and formaldehyde, especially in the case of higher air humidity and when solved in water. However, crotonaldehyde was not detected in the desiccator air. Other organic components such as herbicides or their degradation products and nitrification inhibitors were released from fertilizers containing these compounds. In further experiments, sticks and granules were applied into potting soil and the release of organic compounds in emission chambers was examined under dynamic conditions. No substances that could be directly attributed to the fertilizers were detected in these experiments. However, relevant emission rates of formaldehyde were observed for the spray fertilizers containing urea-formaldehyde after application to tomato plants. The possible contribution of these emissions to atmospheric formaldehyde concentrations is discussed. Finally, the formaldehyde concentrations in a greenhouse for private use are estimated. It is likely that immediately after spray application of a urea-formaldehyde fertilizer increased formaldehyde concentrations in the breathing air of the greenhouse occur.Microplastic (MP) pollution in soil has been becoming an emerging environmental hot spot, but little is known about the interaction between MPs and chemical contaminants in soil. In this study, batch experiments were performed to study adsorption-desorption behavior and mechanism of triclosan (TCS) on MPs, polyethylene (PE) and polystyrene (PS), and soil particles. PE showed the highest adsorption rate (29.3 mg μg-1 h-1) and equilibrium capacity (1248 μg g-1), while the similar profiles between PS (0.27 mg μg-1 h-1 and 1033 μg g-1, respectively) and soil (0.60 mg μg-1 h-1 and 961 μg g-1, respectively). Two adsorption stages, representing liquid-film and intra-particle diffusion were observed obviously for PE. Adsorption isotherm results revealed that the interaction between MPs and TCS was relatively weak. The sorption potential of soil was lower than that of MPs especially at high concentrations. PE addition induced TCS sorption increase in soil, while PS had no significant (P > 0.05) influence. For MP-soil systems, TCS preferred to adsorb on MPs, which was more pronounced for PE than PS. The desorption rate of TCS was the highest for soil, followed by PE and PS, while equilibrium release amount ranked PE > PS > soil. Moreover, soil solution better facilitated the desorption, with the amount increasing by 38% for PE compared with 0.01 M CaCl2 solution. Therefore, MPs, especially PE with high adsorption and desorption potentials may serve as a source and carrier to TCS, and its amendment can change TCS environmental behavior and further risk in soil.There is limited evidence regarding the relationship between air pollution and pediatric asthma in developing countries. link3 This study aimed to investigate the association between short-term exposure to ambient air pollutants and pediatric asthma emergency department (ED) visits in Shanghai, China. We collected data on six criteria air pollutants (PM2.5, PM10, NO2, SO2, CO, and O3) and daily ED visits for pediatric asthma patients from 66 hospitals in Shanghai from 2016 to 2018. The generalized additive model combined with polynomial distributed lag model was applied to explore the associations. We fitted two-pollutant models and stratified the analyses by sex, age, and season. In total, we identified 108,817 emergency department visits for pediatric asthma. A 10 μg/m3 increase in the concentrations of PM2.5, NO2, SO2, and O3 was significantly associated with increased risks of pediatric asthma ED visits, with relative risk of pediatric asthma of 1.011 [95% confidence interval (CI) 1.002, 1.021], 1.030 (95%CI 1.
Here's my website: https://www.selleckchem.com/HSP-90.html
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