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The reason air expands when heated is because the kinetic energy of the air increases and it's atoms and molecules move around more. this means that each atom will take up more space due to it's movement so the air would expand.
The way the egg is able to stay together and fit through the bottle is because the egg whites are made of water and proteins. Proteins are made of long chains of amino acids, but in an egg the chains are clumped tightly together into individual spheres. ("These are called globular proteins.") When the egg is heated, the proteins and water molecules begin the move faster. As they move and collide with each other, the individual protein chains start to unravel, eventually bonding loosely with other protein chains, forming network of protein with water trapped inside. The consistency has changed from runny egg white to a soft solid.
How to get the egg out again? You need to increase pressure inside the bottle. Turn the bottle upside down and tilt it until the small end of the egg is sitting in the mouth of the bottle. Now put you mouth close to the bottle and blow into it, forcing more air into the bottle will increase the amount of pressure inside. When you take your mouth away the egg should pop out.
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