Notes

Jeffrey LONG - Professor (Full) - PhD - University of Iowa, IA

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<h1 style="clear:both" id="content-section-0">Jeffrey Long - Senior Data Scientist Project Lead - Genentech Can Be Fun For Everyone<br></h1>
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<p class="p__0">Beyond terrestrial separations technologies, we are seeking to enhance this cooperative mechanism for applications as far reaching as air purification in submarines and spacecraft, and are applying essential insights from this work to the design of unique materials and mechanisms for the cooperative adsorption of other crucial, industrially-relevant gas molecules. We are likewise targeting metalorganic frameworks featuring polarizing open metal websites and shape-discriminating pore structures for the boosted binding of H2 and CH4 near ambient temperature levels and the separation of hydrocarbon isomers, respectively. The high-capacity storage of hydrogen and natural gas is specifically relevant for vehicle transportation, as these gases represent promising cleaner options to liquid hydrocarbon fuels, and yet significant advances in adsorbent innovations are required to overcome the pricey constraints currently imposed by low-temperature and high-pressure on-board storage requirements.</p>
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<p class="p__1">In addition to their function as molecular sieves, metalorganic frameworks are guaranteeing as robust, efficient drivers with separated and distinct active sites. We are seeking to use coordinatively-unsaturated framework metal centers as catalytic sites and likewise installing these metal centers post-synthetically via chelating groups constructed into the structure ligands. In https://blogfreely.net/holelathe52/jeffrey-long-studio , we are utilizing this post-synthetic adjustment strategy to reduce or oxidize insulating frameworks and target conductive products with high charge densities for applications varying from battery parts to chemical sensors. Together with their distinct electronic properties, we are discovering unmatched magnetic phenomena in a few of these products, and hence these efforts represent new instructions in fundamental materials science.</p>
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<p class="p__2">These compoundscollectively referred to as single-molecule magnetswere discovered in the early 20th century and are of interest for applications in information storage, spin-based electronics, and quantum computing. Nearly thirty years after their discovery, however, the highest carrying out single-molecule magnets still just display operating temperature levels as high as 60 K, with the vast majority just operating at temperature levels of a few Kas cold as deep area. At higher temperatures, thermal energy triggers random changes of the molecular magnetization that precludes the regulated adjustment of spin that is needed for practical applications. The Long group is employing brand-new style themes and architectures precisely picked to enhance running temperature levels, focusing primarily on the synthesis of multinuclear, radical-bridged particles incorporating the late trivalent lanthanides and low-coordinate, mononuclear complexes of the shift metals.</p>
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