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ALKANES
(due to decreasing enthalpy change)
fluorine: reacts vigorously, even in the dark at room temp
Br and Cl: requires UV light/ heat (initiation), reaction involving Br slower than that involving cl
iodine: no reaction
ALKENES
cycloalkenes with up to 7 carbon atoms can only exist as cis isomer, cycloalkenes with 8 or more C can exist as cis trans
cis isomer higher bp (net dipole moment, trans isomer dh) , trans isomer higher mp (solid--> liqiuid, trans isomer has a higher symmetry, thus it packs better as compared to the U shaped cis isomer, thus dispersion forces hold trans isomers more effectively than cis isomers, merto. )
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